GB1347367A - Aqueous dispersions of film-forming macromolecules - Google Patents

Aqueous dispersions of film-forming macromolecules

Info

Publication number
GB1347367A
GB1347367A GB3521871A GB3521871A GB1347367A GB 1347367 A GB1347367 A GB 1347367A GB 3521871 A GB3521871 A GB 3521871A GB 3521871 A GB3521871 A GB 3521871A GB 1347367 A GB1347367 A GB 1347367A
Authority
GB
United Kingdom
Prior art keywords
monomer
grafted
vinyl acetate
heated
hydroperoxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3521871A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lubrizol Corp
Original Assignee
Lubrizol Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lubrizol Corp filed Critical Lubrizol Corp
Publication of GB1347367A publication Critical patent/GB1347367A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/20—Carboxylic acid amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/003—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/28—Non-macromolecular organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/54—Inorganic substances

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

1347367 Graft polymer dispersions LUBRIZOL CORP 27 July 1971 [10 Aug 1970] 35218/71 Heading C3G In an aqueous dispersion of film-forming macromolecules, at least a portion of said macromolecules has grafted thereon one or more amide units derived from a monomer of formula wherein R 1 , R 2 , R 3 , R 4 and R 5 are each independently selected from hydrogen, hydrocarbon radicals and substituted hydrocarbon radicals; R 6 is selected from hydrogen halo and C 1 to C 10 - alkyl radicals and Z is The dispersion may be prepared by mixing a polymer, preferably a polymer of vinyl acetate, an alkyl acrylate or an alkyl methacrylate, with a monomer of the said formula and carrying out the polymerization in an aqueous medium. Alternatively the polymerization is carried out in bulk or in an organic solvent and the graft polymer produced is dispersed in an aqueous medium. In the examples, (a) polyvinyl acetate latex is heated in the presence of t-butyl hydroperoxide before or while being contacted with (i) diacetone acrylamide or (ii) hydroxy methylated diacetone acrylamide, the resulting graft polymer being blended with additional polyvinyl acetate latex; (b) vinyl acetate/nbutyl acrylate copolymer latex is heated in an aqueous medium containing said hydroperoxide and then grafted with monomer (ii), or is heated in a similar aqueous medium containing monomer (i); (c) vinylacetate/di-n-butyl maleate copolymer latex is heated with said peroxide and then grafted with monomer (ii); (d) a vinyl acetate (vinyl ester of C 9 -C 11 -alkanoic carboxylic acids copolymer latex is heated with monomer (i) and said hydroperoxide; (e) vinyl acetate/ethylene copolymer latex is heated with said hydroperoxide while being contacted with monomer (i) or prior to being contacted with monomer (ii); (f) ethyl acrylate (methyl methacrylate copolymer latex as in (e); and (g) butadiene-styrene copolymer latex is grafted with monomer (i) using said hydroperoxide as initiator. The graft polymers are incorporated in compositions comprising (1) polyvinyl acetate grafted with monomer (ii) or vinyl acetate/nbutyl acrylate copolymer grafted with monomer (ii), and a pigment slip containing red iron oxide, talc and barytes; (2) vinyl acetate polymer grafted with monomer (i), ammonium caseinate, rosin ester resin, phenol-formaldehyde resin and styrenated phenol; (3) butadiene-styrene copolymer grafted with monomer (i), ammonium caseinate, phenolformaldehyde resin, styrenated phenol, sulphur, zinc oxide and zinc N,N- dibutyldithiocarbamate; (4) vinyl acetate polymer grafted with monomer (i), tetrasodium pyrophosphate, cornstarch, clay, styrenated phenol and optionally, titanium dioxide.
GB3521871A 1970-08-10 1971-07-27 Aqueous dispersions of film-forming macromolecules Expired GB1347367A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US6267770A 1970-08-10 1970-08-10

Publications (1)

Publication Number Publication Date
GB1347367A true GB1347367A (en) 1974-02-27

Family

ID=22044098

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3521871A Expired GB1347367A (en) 1970-08-10 1971-07-27 Aqueous dispersions of film-forming macromolecules

Country Status (6)

Country Link
JP (1) JPS5339454B1 (en)
AU (1) AU462143B2 (en)
CA (1) CA932887A (en)
DE (1) DE2139856A1 (en)
FR (1) FR2105854A5 (en)
GB (1) GB1347367A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2620738C2 (en) * 1976-05-11 1983-04-28 Wacker-Chemie GmbH, 8000 München Process for the production of aqueous copolymer dispersions and their use in admixture with acidic, water-soluble hardening additives for adhesives
JPS5882603U (en) * 1981-11-30 1983-06-04 藤井　恒雄 pituchi caliper

Also Published As

Publication number Publication date
AU462143B2 (en) 1975-06-19
JPS5339454B1 (en) 1978-10-21
FR2105854A5 (en) 1972-04-28
DE2139856A1 (en) 1972-02-17
CA932887A (en) 1973-08-28
AU3219671A (en) 1973-02-15

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees