GB1340891A - Catalytic oxidation of alkanes to aldehydes acids anhydrides and alkenes - Google Patents

Catalytic oxidation of alkanes to aldehydes acids anhydrides and alkenes

Info

Publication number
GB1340891A
GB1340891A GB53266A GB1340891DA GB1340891A GB 1340891 A GB1340891 A GB 1340891A GB 53266 A GB53266 A GB 53266A GB 1340891D A GB1340891D A GB 1340891DA GB 1340891 A GB1340891 A GB 1340891A
Authority
GB
United Kingdom
Prior art keywords
alkanes
alkane
nov
july
iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB53266A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Power Gas Corp Ltd
Original Assignee
Imperial Chemical Industries Ltd
Power Gas Corp Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd, Power Gas Corp Ltd filed Critical Imperial Chemical Industries Ltd
Publication of GB1340891A publication Critical patent/GB1340891A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/12—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L17/00—Joints with packing adapted to sealing by fluid pressure
    • F16L17/02—Joints with packing adapted to sealing by fluid pressure with sealing rings arranged between outer surface of pipe and inner surface of sleeve or socket
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L21/00—Joints with sleeve or socket
    • F16L21/02—Joints with sleeve or socket with elastic sealing rings between pipe and sleeve or between pipe and socket, e.g. with rolling or other prefabricated profiled rings
    • F16L21/022—Joints with sleeve or socket with elastic sealing rings between pipe and sleeve or between pipe and socket, e.g. with rolling or other prefabricated profiled rings used with sleeves or nipples for pipes of the same diameter, or with reduction pieces
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

1340891 Oxidative dehydrogenation of alkanes POWER-GAS Ltd and IMPERIAL CHEMICAL INDUSTRIES Ltd 25 Nov 1970 [25 Nov 1969 24 March 1970 16 July 1970 22 July 1970 22 Oct 1970] 53266/70 14072/70 34508/70 35500/70 and 50131/70 Divided out of 1336135 Heading C5E [Also in Divisions B1 and C2] Alkanes of 3-20 carbon atoms are oxidized to produce an unsaturated hydrocarbon by passing a feed gas, consisting essentially of the alkane in vapour phase and molecular oxygen or air, in the absence of other reactants, at an elevated temperature over a solid alkane oxidation catalyst including oxygen and either at least two metals other than iron or at least one metal other than iron and phosphorus, into a conventional static, moving or fluidized bed, at a pressure not greater than substantially two atmospheres wherein the partial pressure of the alkane in the feed gas is in excess of 0À20 atmosphere absolute. Processes specified and/or exemplified include the oxidation of propane to propylene, of isobutane to isobutylene, of n-butane to butene and/or butadiene, and of isopentane to isopentene and/or isoprene.
GB53266A 1970-03-24 1970-11-25 Catalytic oxidation of alkanes to aldehydes acids anhydrides and alkenes Expired GB1340891A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB1407270 1970-03-24
GB3450870 1970-07-16
GB3550070 1970-07-22
GB5013170 1970-10-22
GB5326670 1970-11-25

Publications (1)

Publication Number Publication Date
GB1340891A true GB1340891A (en) 1973-12-19

Family

ID=27516133

Family Applications (1)

Application Number Title Priority Date Filing Date
GB53266A Expired GB1340891A (en) 1970-03-24 1970-11-25 Catalytic oxidation of alkanes to aldehydes acids anhydrides and alkenes

Country Status (1)

Country Link
GB (1) GB1340891A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0010902A1 (en) * 1978-10-30 1980-05-14 Rohm And Haas Company Process for the production of (meth)acrylic acid by the catalytic vapour phase oxidation of isobutane or propane
US4413147A (en) * 1982-04-14 1983-11-01 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
US4532365A (en) * 1982-09-20 1985-07-30 The Halcon Sd Group, Inc. Conversion of alkanes to unsaturated aldehydes
US4535188A (en) * 1982-04-14 1985-08-13 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
USRE32082E (en) * 1982-04-14 1986-02-11 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
WO1999020590A1 (en) * 1997-10-21 1999-04-29 Basf Aktiengesellschaft Method of heterogeneous catalyzed vapor-phase oxidation of propane to acrolein and/or acrylic acid

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0010902A1 (en) * 1978-10-30 1980-05-14 Rohm And Haas Company Process for the production of (meth)acrylic acid by the catalytic vapour phase oxidation of isobutane or propane
US4413147A (en) * 1982-04-14 1983-11-01 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
US4535188A (en) * 1982-04-14 1985-08-13 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
USRE32082E (en) * 1982-04-14 1986-02-11 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
US4532365A (en) * 1982-09-20 1985-07-30 The Halcon Sd Group, Inc. Conversion of alkanes to unsaturated aldehydes
WO1999020590A1 (en) * 1997-10-21 1999-04-29 Basf Aktiengesellschaft Method of heterogeneous catalyzed vapor-phase oxidation of propane to acrolein and/or acrylic acid
US6541664B1 (en) 1997-10-21 2003-04-01 Basf Aktiengesellschaft Method of heterogeneous catalyzed vapor-phase oxidation of propane to acrolein and/or acrylic acid

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PS Patent sealed
PE20 Patent expired after termination of 20 years