GB1331486A - Hydroxyarlypolymethylenesulphonium monomers polymers and surface coatings therefrom - Google Patents

Hydroxyarlypolymethylenesulphonium monomers polymers and surface coatings therefrom

Info

Publication number
GB1331486A
GB1331486A GB4912570A GB4912570A GB1331486A GB 1331486 A GB1331486 A GB 1331486A GB 4912570 A GB4912570 A GB 4912570A GB 4912570 A GB4912570 A GB 4912570A GB 1331486 A GB1331486 A GB 1331486A
Authority
GB
United Kingdom
Prior art keywords
compounds
hydrogen
chlorine
integer
atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4912570A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of GB1331486A publication Critical patent/GB1331486A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/46—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings substituted on the ring sulfur atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/72—Benzo[c]thiophenes; Hydrogenated benzo[c]thiophenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/0204—Polyarylenethioethers
    • C08G75/0245—Block or graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02—Polythioethers
    • C08G75/06—Polythioethers from cyclic thioethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/12—Polythioether-ethers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Polyethers (AREA)
  • Paints Or Removers (AREA)

Abstract

1331486 Cyclic sulphonium compounds DOW CHEMICAL CORP 15 Oct 1970 [15 Oct 1969 (2)] 49125/70 Heading C2C [Also in Divisions B2 and C3] The invention comprises compounds (I) and (II), where R is hydrogen, chlorine or bromine or hydroxy or C 1-4 alkoxy; R<SP>1</SP> is hydrogen, chlorine or bromine or C 1-4 alkyl; a is 1 or 2; each S atom is ortho or para to the phenolic oxygen atom; each of A and B is -CH 2 - or -CHR<SP>1</SP>-; and c is 1 or 2; Z is -CR<SP>11</SP> 2 -, -O-, -S-, -(C m H 2m )O- or -OCO(C n H 2n )COO-, where R<SP>11</SP> is hydrogen or C 1-4 alkyl, m is an integer of 1-6, n is 0 or an integer of 1-6; x+y is 0 or an integer of 1-20 and X- is a non-basic inorganic anion or a compound of Formulµ (V) to (IX). The compounds of the invention are made by reacting an appropriately substituted phenol having an active hydrogen atom ortho or para to the hydroxy group with the appropriate cyclic sulphide in the presence of chlorine or with the appropriate cyclic sulphoxide in the presence of HCl to give the sulphonium chloride or by reqcting an alkylthiophenol with a 1,4- or 1,5-dihaloalkane and if desired converting the sulting salt into another salt. Halogen substituted compounds (I) may be prepared by direct halogenation of the corresponding unsubstituted compounds. The compounds (II) may be prepared by known methods from the compounds (I).
GB4912570A 1969-10-15 1970-10-15 Hydroxyarlypolymethylenesulphonium monomers polymers and surface coatings therefrom Expired GB1331486A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US86676269A 1969-10-15 1969-10-15
US86676369A 1969-10-15 1969-10-15

Publications (1)

Publication Number Publication Date
GB1331486A true GB1331486A (en) 1973-09-26

Family

ID=27127968

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4912570A Expired GB1331486A (en) 1969-10-15 1970-10-15 Hydroxyarlypolymethylenesulphonium monomers polymers and surface coatings therefrom

Country Status (6)

Country Link
JP (5) JPS4935265B1 (en)
BE (1) BE757583A (en)
DE (2) DE2050196C3 (en)
FR (1) FR2065446A5 (en)
GB (1) GB1331486A (en)
NL (1) NL168514C (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3804797A (en) * 1972-09-13 1974-04-16 Dow Chemical Co Coating compositions comprising cyclic sulfonium zwitterions with carboxy containing polymers
WO1993009112A1 (en) * 1991-11-06 1993-05-13 Ciba-Geigy Ag A process for the production of cyclic sulfonium salts
JP6392910B2 (en) 2017-01-13 2018-09-19 ファナック株式会社 Human collaborative robot system with robot safety ensuring function
JP7199291B2 (en) * 2018-04-12 2023-01-05 住友化学株式会社 Salt, acid generator, resist composition and method for producing resist pattern
JP7410726B2 (en) * 2020-01-14 2024-01-10 Ntn株式会社 Robot personal protection device

Also Published As

Publication number Publication date
JPS4925265B1 (en) 1974-06-28
JPS4938118B1 (en) 1974-10-15
JPS4935621B1 (en) 1974-09-25
JPS4935622B1 (en) 1974-09-25
DE2050196B2 (en) 1980-08-07
DE2050196C3 (en) 1981-04-02
DE2050196A1 (en) 1971-04-22
BE757583A (en) 1971-04-15
DE2059761A1 (en) 1971-11-04
FR2065446A5 (en) 1971-07-23
NL168514B (en) 1981-11-16
JPS4935265B1 (en) 1974-09-20
NL168514C (en) 1982-04-16
NL7014702A (en) 1971-04-19

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years