GB1316194A - Photonitrosation of normal paraffins - Google Patents
Photonitrosation of normal paraffinsInfo
- Publication number
- GB1316194A GB1316194A GB1316194DA GB1316194A GB 1316194 A GB1316194 A GB 1316194A GB 1316194D A GB1316194D A GB 1316194DA GB 1316194 A GB1316194 A GB 1316194A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxime
- light
- reaction
- vessel
- normal paraffin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002923 oximes Chemical class 0.000 abstract 8
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 239000012188 paraffin wax Substances 0.000 abstract 3
- 239000000047 product Substances 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- -1 nitrosyl halides Chemical class 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000005540 biological transmission Effects 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- OMBRFUXPXNIUCZ-UHFFFAOYSA-N dioxidonitrogen(1+) Chemical compound O=[N+]=O OMBRFUXPXNIUCZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002272 engine oil additive Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- VQTGUFBGYOIUFS-UHFFFAOYSA-N nitrosylsulfuric acid Chemical compound OS(=O)(=O)ON=O VQTGUFBGYOIUFS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 239000003380 propellant Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 238000000638 solvent extraction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1316194 Oximes TEXACO DEVELOPMENT CORP 8 March 1971 6263/71 Heading C2C [Also in Division C5] Normal paraffin oximes are obtained by (a) photochemically reacting in a light-transmittable vessel, at 32-110‹ F., a C 10-13 normal paraffin with a gaseous nitrosating agent whose partial pressure in the vessel is 125-625 mm. Hg., under the influence of light excluding wavelengths below 200 millimicrons; (b) separating unreacted normal paraffin from the reaction product by solvent extraction; and (c) neutralizing the separated reaction product with a base to form a two-phase system containing the oxime in one phase and neutralization products of the base in the other, and separating the phase containing the oxime Suitable nitrosating agents are nitrosyl halides, nitrosyl sulphuric acid, nitric oxide and chlorine, and nitrogen peroxide and chlorine; diluents such as hydrogen chloride and nitrogen may be used. The light for the reaction may be obtained by filtering through suitable glasses, solutions or plastics, or by the use of fluorescent materials. Preferably 85-98% H 2 SO 4 or H 3 PO 4 is allowed to flow at least intermittently over the reaction surface of the reaction vessel, to prevent formation of deposits which will inhibit the transmission of light. With nitrosyl halides as nitrosating agents the initial products are the oxime hydrohalides, which are neutralized to liberate the free oxime; or if, e.g. H 2 SO 4 is used the oxime hydrohalides form complexes with the acid. The oxime products are useful as engine oil additives, anti-icing agents, fuels, rocket propellants and pesticides.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB626371 | 1971-03-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1316194A true GB1316194A (en) | 1973-05-09 |
Family
ID=9811346
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1316194D Expired GB1316194A (en) | 1971-03-08 | 1971-03-08 | Photonitrosation of normal paraffins |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE764853A (en) |
| DE (1) | DE2115049A1 (en) |
| FR (1) | FR2083242A5 (en) |
| GB (1) | GB1316194A (en) |
| NL (1) | NL7103546A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU708998B2 (en) * | 1994-06-10 | 1999-08-19 | Johnson & Johnson Vision Products, Inc. | Low oxygen molding of soft contact lenses |
-
1971
- 1971-03-08 GB GB1316194D patent/GB1316194A/en not_active Expired
- 1971-03-17 NL NL7103546A patent/NL7103546A/xx unknown
- 1971-03-24 FR FR7110331A patent/FR2083242A5/fr not_active Expired
- 1971-03-25 BE BE764853A patent/BE764853A/en unknown
- 1971-03-27 DE DE19712115049 patent/DE2115049A1/de active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU708998B2 (en) * | 1994-06-10 | 1999-08-19 | Johnson & Johnson Vision Products, Inc. | Low oxygen molding of soft contact lenses |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2115049A1 (en) | 1972-10-05 |
| FR2083242A5 (en) | 1971-12-10 |
| BE764853A (en) | 1971-09-27 |
| NL7103546A (en) | 1972-09-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |