GB1315825A - Spiropyran derivatives - Google Patents

Spiropyran derivatives

Info

Publication number
GB1315825A
GB1315825A GB1315825DA GB1315825A GB 1315825 A GB1315825 A GB 1315825A GB 1315825D A GB1315825D A GB 1315825DA GB 1315825 A GB1315825 A GB 1315825A
Authority
GB
United Kingdom
Prior art keywords
ring
cycloalkyl
pyran
another
different
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Publication of GB1315825A publication Critical patent/GB1315825A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D491/00Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/08Bridged systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D491/00Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/10Spiro-condensed systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

1315825 Spiropyran derivatives MINNESOTA MINING & MFG CO 2 Dec 1970 [10 Dec 1969] 60347/69 Heading C2C [Also in Division C4] Novel spiropyrans having a pyrazoline ring spiro to the pyran ring with the oxygen atom of the pyran ring adjacent the atom which forms the spiro attachment between the pyrazoline and pyran rings, and having one or more rings fused to the pyran ring, and particularly spiropurans, one form of which has the general formula in which R<SP>1</SP> and R<SP>2</SP>, which may be the same as or different from one another, each represents an alkyl, cycloalkyl or aralkyl group, or R<SP>1</SP> and R<SP>2</SP> together complete a cycloalkyl ring, R<SP>3</SP> and R<SP>4</SP>, which may be the same as or different from one another, each represents an alkyl, cycloalkyl or aralkyl group, and R<SP>5</SP> and R<SP>6</SP>, which may be the same as or different from one another, each represents a hydrogen or halogen atom or a nitro, cyano or carboxy group, or R<SP>5</SP> and R<SP>6</SP> together form a fused on aromatic ring are prepared by reacting a quaternary ammonium compound such as one of formula with an aromatic aldehyde such as one of formula The products have photochromic and thermochromic properties undergoing a change of type 5 - Methylthio - 2,3,4,4 - tetramethyl -, 3- methylthio - 4,4,5 - trimethyl -, 2 - ethyl - 5 - ethylthio - 3,4,4 - trimethyl - and 5 - ethylthio - 2,3,4, 4-tetramethyl-pyrazolenium iodides are prepared by quaternization processes.
GB1315825D 1969-12-10 1969-12-10 Spiropyran derivatives Expired GB1315825A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB6034769 1969-12-10

Publications (1)

Publication Number Publication Date
GB1315825A true GB1315825A (en) 1973-05-02

Family

ID=10485462

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1315825D Expired GB1315825A (en) 1969-12-10 1969-12-10 Spiropyran derivatives

Country Status (1)

Country Link
GB (1) GB1315825A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3910949A (en) * 1974-12-09 1975-10-07 American Cyanamid Co Manufacture of 1,2-dimethyl-3,5-diphenylpyrazolium methylsulfate in a single reaction zone
US3925408A (en) * 1974-07-01 1975-12-09 American Cyanamid Co Pyrazolinium compounds as herbicides
US3947583A (en) * 1975-01-13 1976-03-30 American Cyanamid Company Method for controlling fungi utilizing pyrazolinium compounds
US3963742A (en) 1974-07-12 1976-06-15 American Cyanamid Company 1,2-Dialkyl-3,4,5-trisubstituted pyrazolium salts as herbicidal agents
US4041046A (en) 1975-06-06 1977-08-09 American Cyanamid Company 1,2-Dialkyl-3,4,5-trisubstituted pyrazole compounds

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925408A (en) * 1974-07-01 1975-12-09 American Cyanamid Co Pyrazolinium compounds as herbicides
US3963742A (en) 1974-07-12 1976-06-15 American Cyanamid Company 1,2-Dialkyl-3,4,5-trisubstituted pyrazolium salts as herbicidal agents
US3910949A (en) * 1974-12-09 1975-10-07 American Cyanamid Co Manufacture of 1,2-dimethyl-3,5-diphenylpyrazolium methylsulfate in a single reaction zone
US3947583A (en) * 1975-01-13 1976-03-30 American Cyanamid Company Method for controlling fungi utilizing pyrazolinium compounds
US4041046A (en) 1975-06-06 1977-08-09 American Cyanamid Company 1,2-Dialkyl-3,4,5-trisubstituted pyrazole compounds

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee