GB1310464A - Coating by vacuum vapour deposition of synthetic plastics and resinous materials - Google Patents
Coating by vacuum vapour deposition of synthetic plastics and resinous materialsInfo
- Publication number
- GB1310464A GB1310464A GB1942471A GB1942471A GB1310464A GB 1310464 A GB1310464 A GB 1310464A GB 1942471 A GB1942471 A GB 1942471A GB 1942471 A GB1942471 A GB 1942471A GB 1310464 A GB1310464 A GB 1310464A
- Authority
- GB
- United Kingdom
- Prior art keywords
- substrate
- vapour
- oxide
- coating
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011248 coating agent Substances 0.000 title abstract 3
- 238000000576 coating method Methods 0.000 title abstract 3
- 230000008021 deposition Effects 0.000 title abstract 2
- 239000004033 plastic Substances 0.000 title abstract 2
- 229920003023 plastic Polymers 0.000 title abstract 2
- 239000012260 resinous material Substances 0.000 title abstract 2
- 239000000758 substrate Substances 0.000 abstract 4
- -1 B 2 O 3 Inorganic materials 0.000 abstract 2
- 229910004298 SiO 2 Inorganic materials 0.000 abstract 2
- 239000010410 layer Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052776 Thorium Inorganic materials 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 238000010894 electron beam technology Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 150000002222 fluorine compounds Chemical class 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011229 interlayer Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052746 lanthanum Inorganic materials 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract 1
- 239000004417 polycarbonate Substances 0.000 abstract 1
- 229920000515 polycarbonate Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000013047 polymeric layer Substances 0.000 abstract 1
- 239000004926 polymethyl methacrylate Substances 0.000 abstract 1
- 150000003346 selenoethers Chemical class 0.000 abstract 1
- 150000004760 silicates Chemical class 0.000 abstract 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229920002545 silicone oil Polymers 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 150000004772 tellurides Chemical class 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 238000001771 vacuum deposition Methods 0.000 abstract 1
- 239000012855 volatile organic compound Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/10—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment
- B29C59/12—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment in an environment other than air
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
Abstract
1310464 Two-stage vacuum coating process CARL-ZEISS-STIFTUNG [trading as JENAER GLASWERK SCHOTT & GEN] 8 June 1971 [13 June 1970] 19424/71 Heading C7F In a process for applying, by vacuum vapour deposition, an inorganic coating (A) having an E-modulus greater than 3 x 10<SP>5</SP> Kp/cm<SP>2</SP> to a substrate (B) of synthetic plastics or resinous material, there is deposited an intermediate layer (C) on substrate (B), (C) being a polymeric layer produced by means of a glow discharge in the vapour of a volatile organic substance or mixture of such. (B) may be polymethylmethacrylate or polycarbonate, and (A) is preferably a glass consisting of SiO 2 , B 2 O 3 , Al 2 O 3 and Na 2 O, but may be SiO 2 , CeO 2 , Sn oxide, In oxide, Pb oxide, sulphides, selenides and tellurides of Zn and Cd, fluorides of Mg, Li, Th, Pb, Ba, La or Ce, silicates and borates of alkaline earths or Fe, Cu, or Cr. Layer (C), preferably 30 to 400‹ thick, is made by glow discharging vapour of an aliphatic such as acetylene or an aromatic, e.g. xylene, or preferably, a Si-containing compound such as a volatile ester of silicic acid, e.g. a methyl or ethyl silicate, or volatile silicone oil. The volatile organic compound is put in 4, valve 5 closed, and the chamber pumped down via main pump 8, which is then replaced by auxiliary pump 10 whilst valve 5 is opened and a glow discharge established in the resulting organic vapour between substrate 11 and glass-backed Al plate 3, to produce the polymer inter-layer. Substrate 11 is then moved adjacent source 6 of coating material (A) which is evaporated by electron-beam heating.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702029307 DE2029307C3 (en) | 1970-06-13 | 1970-06-13 | Process for improving the adhesion of glass layers vapor-deposited on molded polymer bodies in a high vacuum |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1310464A true GB1310464A (en) | 1973-03-21 |
Family
ID=5773923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1942471A Expired GB1310464A (en) | 1970-06-13 | 1971-06-08 | Coating by vacuum vapour deposition of synthetic plastics and resinous materials |
Country Status (4)
| Country | Link |
|---|---|
| CH (1) | CH518799A (en) |
| DE (1) | DE2029307C3 (en) |
| FR (1) | FR2095239B1 (en) |
| GB (1) | GB1310464A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0110258A1 (en) * | 1982-11-25 | 1984-06-13 | Shin-Etsu Chemical Co., Ltd. | A method for the preparation of a polyvinyl chloride resin shaped article with metallized surface |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB933549A (en) * | 1958-12-02 | 1963-08-08 | Radiation Res Corp | Dielectric coated electrodes |
| US3690932A (en) * | 1968-11-20 | 1972-09-12 | Jenaer Glaswerk Schott & Gen | Method for producing mixed layers from inorganic and organic substances on a substrate |
-
1970
- 1970-06-13 DE DE19702029307 patent/DE2029307C3/en not_active Expired
-
1971
- 1971-06-08 GB GB1942471A patent/GB1310464A/en not_active Expired
- 1971-06-08 CH CH832271A patent/CH518799A/en not_active IP Right Cessation
- 1971-06-11 FR FR7121395A patent/FR2095239B1/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0110258A1 (en) * | 1982-11-25 | 1984-06-13 | Shin-Etsu Chemical Co., Ltd. | A method for the preparation of a polyvinyl chloride resin shaped article with metallized surface |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2095239B1 (en) | 1975-07-11 |
| DE2029307A1 (en) | 1971-12-23 |
| DE2029307B2 (en) | 1974-06-06 |
| DE2029307C3 (en) | 1975-01-30 |
| CH518799A (en) | 1972-02-15 |
| FR2095239A1 (en) | 1972-02-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |