GB1302441A - - Google Patents

Info

Publication number
GB1302441A
GB1302441A GB1259670A GB1259670A GB1302441A GB 1302441 A GB1302441 A GB 1302441A GB 1259670 A GB1259670 A GB 1259670A GB 1259670 A GB1259670 A GB 1259670A GB 1302441 A GB1302441 A GB 1302441A
Authority
GB
United Kingdom
Prior art keywords
hydrogen peroxide
alcohol
allyl
ene
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1259670A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority claimed from US00185369A external-priority patent/US3806467A/en
Publication of GB1302441A publication Critical patent/GB1302441A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D303/46—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by amide or nitrile radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/48—Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

1302441 Epoxide compounds SUMITOMO CHEMICAL CO Ltd 16 March 1970 [14 March 1969 4 Sept 1969 6 Oct 1969] 12596/70 Heading C2C [Also in Division B1] Epoxides are produced by reacting an olefin, an ethylenically unsaturated alcohol or an ethylenically unsaturated or carboxylic acid with hydrogen peroxide in the presence of a catalyst comprising-(a) an organo-tin compound containing a hydroxyl group or a group hydrolysable to a hydroxyl group in the presence of water or hydrogen peroxide and (b) at least one compound containing at least one of Mo, W, V, Se or B. Specified reactants are propylene, normal but-1-ene or but-2-ene, iso-butene, 1,3- butadiene, allyl alcohol, methyl allyl-alcohol, allyl chloride, iso-octane, styrene, alpha-methyl styrene, soybean oil, oleic acid, cyclohexene, 4- cyanocyclohexene, cyclooctadiene and cyclododecatriene. Reaction conditions specified are - 20‹ to + 150‹ C., 1 to 100 atmos. pressure, a reaction time of 1 minute to 100 hours and a mole ratio of olefin to hydrogen peroxide of 1: 30 to 30 1.
GB1259670A 1969-03-14 1970-03-16 Expired GB1302441A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP1975269 1969-03-14
JP7045769 1969-09-04
JP8014769 1969-10-06
US1833570A 1970-03-10 1970-03-10
US00185369A US3806467A (en) 1969-03-14 1971-09-30 Organic tin compound containing catalyst system useful for producing epoxy compounds

Publications (1)

Publication Number Publication Date
GB1302441A true GB1302441A (en) 1973-01-10

Family

ID=27520167

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1259670A Expired GB1302441A (en) 1969-03-14 1970-03-16

Country Status (4)

Country Link
DE (1) DE2012049A1 (en)
FR (1) FR2038948A5 (en)
GB (1) GB1302441A (en)
NL (1) NL149801C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4410715A (en) 1982-07-14 1983-10-18 Exxon Research & Engineering Co. Process for the epoxidation of olefins using a group V metal co-catalyst I and a phenolic hydrocarbon co-catalyst II
EP0950659A2 (en) * 1998-04-14 1999-10-20 Ube Industries, Ltd. Proces for producing 1,2-Epoxy-5, 9-Cyclododecadiene

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE863237A (en) * 1977-02-01 1978-07-24 Ugine Kuhlmann CATALYTIC EPOXIDATION PROCESS OF OLEFINS

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4410715A (en) 1982-07-14 1983-10-18 Exxon Research & Engineering Co. Process for the epoxidation of olefins using a group V metal co-catalyst I and a phenolic hydrocarbon co-catalyst II
EP0950659A2 (en) * 1998-04-14 1999-10-20 Ube Industries, Ltd. Proces for producing 1,2-Epoxy-5, 9-Cyclododecadiene
EP0950659A3 (en) * 1998-04-14 2001-07-18 Ube Industries, Ltd. Process for producing 1,2-Epoxy-5,9-Cyclododecadiene

Also Published As

Publication number Publication date
NL7003607A (en) 1970-09-16
DE2012049A1 (en) 1970-10-01
NL149801C (en) 1976-11-15
FR2038948A5 (en) 1971-01-08

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee