GB1296351A - - Google Patents

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Publication number
GB1296351A
GB1296351A GB3025568A GB1296351DA GB1296351A GB 1296351 A GB1296351 A GB 1296351A GB 3025568 A GB3025568 A GB 3025568A GB 1296351D A GB1296351D A GB 1296351DA GB 1296351 A GB1296351 A GB 1296351A
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GB
United Kingdom
Prior art keywords
compound
quaternary
alkyl
total number
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3025568A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1296351A publication Critical patent/GB1296351A/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • C08G65/329Polymers modified by chemical after-treatment with organic compounds
    • C08G65/337Polymers modified by chemical after-treatment with organic compounds containing other elements
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32Polymers modified by chemical after-treatment
    • C08G65/329Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33303Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02Polyalkylene oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/48N-containing polycondensation products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/62Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/047Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on cationic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/006Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)

Abstract

1296351 Toilet bars UNILEVER Ltd 24 Sept 1969 [25 June 1968 12 July 1968] 30255/68 and 33361/68 Heading C5D A toilet bar contains at least 15% by wt. of one or more polyethylene oxide quaternary ammonium compounds X of the type described containing a polyethylene oxide group with at least three ethylene oxide units in a chain, which have a K value of from 3 to 0À04 when the compound is detersive and from 30 to 0À67 when the compound is non-detersive, the K value being defined by the expression: where #EO is the total number of ethylene oxide units, #C is the total number of carbon atoms not in ethylene oxide units and #N<SP>+</SP> is the total number of quaternary N atoms per repeating unit of the compound. The compounds X may be (A) of general formula:- R 1 R 2 R 3 N<SP>+</SP>(EO) n X<SP>-</SP> where R 1 is C 8 -C 18 straight chain alkyl or C 8 -C 18 alkyl interrupted by a phenylene group; R 2 is CH 3 or C 6 H 5 CH 2 -; R 3 is methyl or polyethyleneoxide group, n is at least 3 and X- is an anion; (B) of general formula wherein R 2 , R 3 and R 4 may be alkyl, cyclic alkyl, aryl, alkaryl, aralkyl or heterocyclic which may have substituents e.g. halogen, nitro, carbonyl, ester or amide groups, or ethylenic or acetylenic linkages; or R 2 , R 3 and R 4 , together with the quaternary N, may form a heterocyclic group; or the quaternary N may be included in the repeating unit of a polyalkyleneimine compound; Z is 4À5 to 34; X- is a compatible anion e.g. Cl, Br, I, SO4, PO 4 or acetate. The compounds X may be as described and claimed in Specification 1,296,352. The toilet bar. may consist of the compound(s) X alone with or without (1) a hardening agent such as a C 12 -C 22 fatty acid, a polyethylene glycol of mol. wt. 1000-6000, a C 10 -C 18 alkyl succinic acid, a quaternary NH 4 compound and a non-ionic surfactant of formula R-O(EO) n where R is C 12 -C 20 alkyl, n is 20-40; (2) a softening agent such as an amine oxide or a sulphobetaine; or (3) a lather improver such as a C 8 -C 12 soap, a polyethylene glycol of mol. wt. 600-1500 or an ethanolamide. Alternatively, the compound(s) X may be mixed with an anionic, nonionic, ampholytic or quaternary NH 4 surfactant e.g. soap of a mixture of an alkali metal alkane sulphonate and olefin sulphonate.
GB3025568A 1968-06-25 1968-06-25 Expired GB1296351A (en)

Applications Claiming Priority (15)

Application Number Priority Date Filing Date Title
GB3025568 1968-06-25
GB3336168 1968-07-12
SE07100/70A SE349602B (en) 1968-06-25 1970-05-22
NO701970A NO136759C (en) 1968-06-25 1970-05-22 TOILETS} PIECES.
ZA703505A ZA703505B (en) 1968-06-25 1970-05-25 Detergent composition
AU15549/70A AU462276B2 (en) 1968-06-25 1970-05-26 Detergent composition
DE19702029193 DE2029193A1 (en) 1968-06-25 1970-06-13 Toilet detergent bar
DE2038061A DE2038061C2 (en) 1968-06-25 1970-06-13 Quaternary polyethylene oxide ammonium compounds
LU61134 1970-06-15
BE752014 1970-06-15
CH904970A CH548447A (en) 1968-06-25 1970-06-15 TOILET DETERGENT PIECE.
AT541470A AT322707B (en) 1968-06-25 1970-06-16 TOILET DETERGENT PIECE
NL7008839A NL7008839A (en) 1968-06-25 1970-06-17
IT69134/70A IT975524B (en) 1968-06-25 1970-06-19 TOILET SOAP
FR7023854A FR2094622A5 (en) 1968-06-25 1970-06-26

Publications (1)

Publication Number Publication Date
GB1296351A true GB1296351A (en) 1972-11-15

Family

ID=39627832

Family Applications (2)

Application Number Title Priority Date Filing Date
GB30255D Active GB30255A (en) 1968-06-25
GB3025568A Expired GB1296351A (en) 1968-06-25 1968-06-25

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB30255D Active GB30255A (en) 1968-06-25

Country Status (15)

Country Link
US (1) US3838057A (en)
AT (1) AT322707B (en)
AU (1) AU462276B2 (en)
BE (1) BE752014A (en)
CA (1) CA921932A (en)
CH (1) CH548447A (en)
DE (2) DE2029193A1 (en)
FR (1) FR2094622A5 (en)
GB (2) GB1296351A (en)
IT (1) IT975524B (en)
LU (1) LU61134A1 (en)
NL (1) NL7008839A (en)
NO (1) NO136759C (en)
SE (1) SE349602B (en)
ZA (1) ZA703505B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2601014A1 (en) * 1975-01-17 1976-07-22 Exxon Research Engineering Co WETTING AGENTS AND EMULSIFYING AGENTS
EP0022562A2 (en) * 1979-07-14 1981-01-21 Hoechst Aktiengesellschaft Quaternary ammonium compounds, their preparation and their use as fabric softener
EP0623668A2 (en) * 1993-05-04 1994-11-09 DALLI-WERKE WÄSCHE-UND KÖRPERPFLEGE GmbH & Co.KG. Body cleansing agent in coke form
CN114702396A (en) * 2022-05-10 2022-07-05 浙江鹿达科技有限公司 Preparation method of PEG-6 glycerol polyoxyethylene ether quaternary ammonium salt

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4092260A (en) * 1973-11-28 1978-05-30 Lever Bros. Co. Quick lathering toilet bars and method of making same
GR70683B (en) * 1979-02-27 1982-12-20 Procter & Gamble
US4303543A (en) * 1979-02-27 1981-12-01 The Procter & Gamble Company Method for cleansing and conditioning the skin
US4285826A (en) * 1980-04-14 1981-08-25 Armour-Dial, Inc. Toilet soap bars imparting improved moisturing and skin feel characteristics
US4551506A (en) * 1982-12-23 1985-11-05 The Procter & Gamble Company Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4659802A (en) * 1982-12-23 1987-04-21 The Procter & Gamble Company Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions
US4676921A (en) * 1982-12-23 1987-06-30 The Procter & Gamble Company Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties
US4664848A (en) * 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
US4661288A (en) * 1982-12-23 1987-04-28 The Procter & Gamble Company Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions
US4548744A (en) * 1983-07-22 1985-10-22 Connor Daniel S Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions
US4885102A (en) * 1987-07-17 1989-12-05 Kao Corporation Cloth-softening liquid composition containing quaternary ammonium compound and a polyether derivative or cationic surfactant polymer
GB8727659D0 (en) * 1987-11-26 1987-12-31 Unilever Plc Machine dishwashing compositions
JPH0756112B2 (en) * 1988-02-17 1995-06-14 花王株式会社 Concentrated softening agent for clothing
US5160450A (en) * 1990-12-05 1992-11-03 Lion Corporation Surface-active agents having two hydrophobic chains and two hydrophilic groups
PE6995A1 (en) * 1994-05-25 1995-03-20 Procter & Gamble COMPOSITION INCLUDING A PROPOXYLATED POLYKYLENE OAMINE POLYKYLENE OAMINE POLYMER AS DIRT SEPARATION AGENT
JP5558126B2 (en) * 2010-01-28 2014-07-23 広栄化学工業株式会社 (2- (2-hydroxyethoxy) ethyl) trialkylammonium salt
JP6250640B2 (en) * 2012-05-11 2017-12-20 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Ethoxylated polyethyleneimine and method of using the same
US9068147B2 (en) 2012-05-11 2015-06-30 Basf Se Quaternized polyethylenimines with a high quaternization degree
PL2989192T3 (en) * 2013-04-23 2019-01-31 Basf Se Formulations, use of same as or for manufacture of dish-washing agents and their manufacture
EP3039109B1 (en) 2013-08-26 2017-09-13 The Procter and Gamble Company Compositions comprising alkoxylated polyamines having low melting points
CN106929179A (en) * 2017-02-24 2017-07-07 江苏斯德瑞克化工有限公司 Asymmetric polyethers Gemini surface active agent and preparation method thereof
CN110305076A (en) * 2019-07-05 2019-10-08 广州市沙索化工科技有限公司 A kind of preparation method of novel Biester quarternary ammoniumsalt

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE639249A (en) * 1962-10-27
GB1084134A (en) * 1964-07-14 1967-09-20 Mafchon Products Ltd Novel quaternary ammonium salts, their preparation and use as surface-active agents

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2601014A1 (en) * 1975-01-17 1976-07-22 Exxon Research Engineering Co WETTING AGENTS AND EMULSIFYING AGENTS
US4239634A (en) 1975-01-17 1980-12-16 Exxon Research & Engineering Co. Lubricating oil containing a surface active agent
EP0022562A2 (en) * 1979-07-14 1981-01-21 Hoechst Aktiengesellschaft Quaternary ammonium compounds, their preparation and their use as fabric softener
EP0022562B1 (en) * 1979-07-14 1985-06-19 Hoechst Aktiengesellschaft Quaternary ammonium compounds, their preparation and their use as fabric softener
EP0623668A2 (en) * 1993-05-04 1994-11-09 DALLI-WERKE WÄSCHE-UND KÖRPERPFLEGE GmbH & Co.KG. Body cleansing agent in coke form
EP0623668A3 (en) * 1993-05-04 1996-04-10 Dalli Werke Waesche Und Koeper Body cleansing agent in coke form.
CN114702396A (en) * 2022-05-10 2022-07-05 浙江鹿达科技有限公司 Preparation method of PEG-6 glycerol polyoxyethylene ether quaternary ammonium salt

Also Published As

Publication number Publication date
AT322707B (en) 1975-06-10
LU61134A1 (en) 1971-07-02
ZA703505B (en) 1972-01-26
AU462276B2 (en) 1975-06-05
NL7008839A (en) 1971-12-21
BE752014A (en) 1970-12-15
NO136759C (en) 1977-11-02
SE349602B (en) 1972-10-02
NO136759B (en) 1977-07-25
US3838057A (en) 1974-09-24
DE2029193A1 (en) 1971-12-23
CA921932A (en) 1973-02-27
FR2094622A5 (en) 1972-02-04
DE2038061C2 (en) 1982-11-18
DE2038061A1 (en) 1971-12-23
GB30255A (en)
AU1554970A (en) 1971-12-02
CH548447A (en) 1974-04-30
IT975524B (en) 1974-08-10

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee