GB1286457A - Subbing layers in film recording materials - Google Patents
Subbing layers in film recording materialsInfo
- Publication number
- GB1286457A GB1286457A GB58350/68A GB5835068A GB1286457A GB 1286457 A GB1286457 A GB 1286457A GB 58350/68 A GB58350/68 A GB 58350/68A GB 5835068 A GB5835068 A GB 5835068A GB 1286457 A GB1286457 A GB 1286457A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- layer
- coated
- hydrophilic layer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229920000728 polyester Polymers 0.000 abstract 2
- 229920006267 polyester film Polymers 0.000 abstract 2
- -1 polyethylene terephthalate Polymers 0.000 abstract 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract 2
- 239000000243 solution Substances 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 abstract 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- 108010010803 Gelatin Proteins 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- QMJDEXCUIQJLGO-UHFFFAOYSA-N [4-(methylamino)phenyl] hydrogen sulfate Chemical compound CNC1=CC=C(OS(O)(=O)=O)C=C1 QMJDEXCUIQJLGO-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000003926 acrylamides Chemical class 0.000 abstract 1
- 125000005396 acrylic acid ester group Chemical group 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000006258 conductive agent Substances 0.000 abstract 1
- 239000012954 diazonium Substances 0.000 abstract 1
- 150000001989 diazonium salts Chemical class 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- RMGVZKRVHHSUIM-UHFFFAOYSA-L dithionate(2-) Chemical compound [O-]S(=O)(=O)S([O-])(=O)=O RMGVZKRVHHSUIM-UHFFFAOYSA-L 0.000 abstract 1
- 235000019256 formaldehyde Nutrition 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 239000008273 gelatin Substances 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- 235000011852 gelatine desserts Nutrition 0.000 abstract 1
- 238000007654 immersion Methods 0.000 abstract 1
- 150000002688 maleic acid derivatives Chemical class 0.000 abstract 1
- 239000006224 matting agent Substances 0.000 abstract 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 abstract 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 abstract 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 229910001961 silver nitrate Inorganic materials 0.000 abstract 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 abstract 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 1
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
- 239000012463 white pigment Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 235000014692 zinc oxide Nutrition 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/12—Printing plates or foils; Materials therefor non-metallic other than stone, e.g. printing plates or foils comprising inorganic materials in an organic matrix
- B41N1/14—Lithographic printing foils
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/705—Compositions containing chalcogenides, metals or alloys thereof, as photosensitive substances, e.g. photodope systems
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
- G03C1/915—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means using mechanical or physical means therefor, e.g. corona
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/91—Photosensitive materials characterised by the base or auxiliary layers characterised by subbing layers or subbing means
- G03C1/93—Macromolecular substances therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/42—Structural details
- G03C8/52—Bases or auxiliary layers; Substances therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/10—Bases for charge-receiving or other layers
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Metallurgy (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Photoreceptors In Electrophotography (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Abstract
1286457 Coating AGFA-GEVAERT 24 Oct 1969 [9 Dec 1968] 58350/68 Heading B2E [Also in Divisions H1 and G2] In a process for the preparation of a recording material comprising a polyester support, e.g. polyethylene terephthalate, a layer of a copolymer comprising at least one of the chlorine - containing monomers vinylidene chloride and vinyl chloride on the polyester support and a photosensitive hydrophilic layer on the copolymer layer, the adhesion of the hydrophilic layer to the copolymer layer is improved by exposing the surface of the copolymer layer to a high voltage electric corona discharge before the application thereto of the hydrophilic layer. The copolymer may comprise 45-99.5% by weight of vinyl chloride or vinylidene chloride, 0.5-10% by weight of an ethylenically unsaturated hydrophilic monomer, e.g. acrylic, methacrylic or itaconic acid or N-vinylpyrrolidone, and up to 54.5% by weight of at least one other copolymerisable ethylenically unsaturated monomer, e.g. acrylamides, methacrylamides, acrylicacid esters, methacrylic acid esters, maleic acid esters, N-alkylmaleimides or butadiene. A polyester film coated with the copolymer may be passed between an earthed roller and a corona electrode, the copolymer layer facing the corona electrode, and an AC high voltage applied to the corona electrode to produce a high frequency corona discharge, a frequency range of 10-100Kc and current intensities of 0.5Î10<SP>-5</SP>-1.5Î10<SP>15</SP> A/cm being preferred. The copolymer may be applied as a solution or aqueous dispersion which may contain a wetting or dispersing agent by immersion, spray, brush, roller, doctor blade, air brush or wiping techniques to a thickness of 0.3-3ju. The film may be coated on at least one side and stretched in one or both directions prior to and after application of the copolymer. The hydrophilic layer which may be transferred by stripping from a temporary support may also contain a semi-conductive substance, electro conductive agent, matting agent or opaque white pigment in a binding agent, pigment in a photo - hardenable or photosolubilizable binder, light sensitive silver halide, diazonium salt or diazosulphonate, dissolved dye, colour coupler or development nuclei. In the examples polyester films coated with the copolymer and subjected to a corona discharge are coated with an aqueous composition comprising zinc oxide or titanium dioxide, sodium hexametaphosphate, gelatin, formaldehyde and ethylene chlorohydrin, dried, exposed image - wise through a transparent original, dipped in an aqueous solution of silver nitrate, an aqueous solution of p-monomethylaminophenol sulphate and an acid solution containing sodium thiosulphate pentahydrate and potassium metabisulphate, rinsed and dried.
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB58350/68A GB1286457A (en) | 1968-12-09 | 1968-12-09 | Subbing layers in film recording materials |
| SU1370156A SU398059A3 (en) | 1968-12-09 | 1969-10-22 | |
| CA065783A CA935019A (en) | 1968-12-09 | 1969-10-24 | Subbing layers in film recording materials |
| JP9461269A JPS542090B1 (en) | 1968-12-09 | 1969-11-25 | |
| ES373975A ES373975A1 (en) | 1968-12-09 | 1969-11-27 | Process of improving adherence of hydrophilic layer to hydrophobic film support |
| FR6941319A FR2025649A1 (en) | 1968-12-09 | 1969-11-28 | |
| DE19691961374 DE1961374A1 (en) | 1968-12-09 | 1969-12-06 | Film materials with improved adhesive layers |
| SE16892/69A SE354528B (en) | 1968-12-09 | 1969-12-08 | |
| BE742769D BE742769A (en) | 1968-12-09 | 1969-12-08 | |
| US00245619A US3712812A (en) | 1968-12-09 | 1972-04-19 | Process of improving adherence of hydrophilic layer to hydrophobic film support |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB58350/68A GB1286457A (en) | 1968-12-09 | 1968-12-09 | Subbing layers in film recording materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1286457A true GB1286457A (en) | 1972-08-23 |
Family
ID=10481385
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB58350/68A Expired GB1286457A (en) | 1968-12-09 | 1968-12-09 | Subbing layers in film recording materials |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3712812A (en) |
| JP (1) | JPS542090B1 (en) |
| BE (1) | BE742769A (en) |
| CA (1) | CA935019A (en) |
| DE (1) | DE1961374A1 (en) |
| ES (1) | ES373975A1 (en) |
| FR (1) | FR2025649A1 (en) |
| GB (1) | GB1286457A (en) |
| SE (1) | SE354528B (en) |
| SU (1) | SU398059A3 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4252885A (en) | 1977-03-25 | 1981-02-24 | Bexford Limited | Polyester coated films using an aqueous polyester dispersion and photographic layer |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3864128A (en) * | 1967-09-28 | 1975-02-04 | Agfa Gevaert | Electrophotographic sheet material employing a hydrophobic film support and hydrophilic layer |
| JPS5318551B2 (en) * | 1971-11-17 | 1978-06-15 | ||
| CA977596A (en) * | 1971-12-28 | 1975-11-11 | Yoshio Tsuji | Imaged sheet or film and method and apparatus for preparing same |
| JPS5135147B2 (en) * | 1972-11-06 | 1976-09-30 | ||
| GB1463727A (en) * | 1974-07-04 | 1977-02-09 | Ciba Geigy Ag | Subbing of polyester film material |
| US4220471A (en) * | 1977-10-13 | 1980-09-02 | Mitsubishi Paper Mills, Ltd. | Photographic polypropylene coated paper support with corona discharge treatment and polymeric subbing layer |
| US4311774A (en) * | 1980-03-19 | 1982-01-19 | Polaroid Corporation | Irradiation treatment of polymeric photographic film supports |
| DE3263357D1 (en) * | 1981-05-18 | 1985-06-05 | Agfa Gevaert Nv | Surface-treated vinyl chloride polymer material including an adhering hydrophilic layer |
| US5240809A (en) * | 1992-04-20 | 1993-08-31 | Minnesota Mining And Manufacturing Company | Imageable articles having dye selective interlayers |
| US5691123A (en) * | 1995-06-30 | 1997-11-25 | Eastman Kodak Company | Method to selectively remove lubricant from one side of lubricant-coated support |
-
1968
- 1968-12-09 GB GB58350/68A patent/GB1286457A/en not_active Expired
-
1969
- 1969-10-22 SU SU1370156A patent/SU398059A3/ru active
- 1969-10-24 CA CA065783A patent/CA935019A/en not_active Expired
- 1969-11-25 JP JP9461269A patent/JPS542090B1/ja active Pending
- 1969-11-27 ES ES373975A patent/ES373975A1/en not_active Expired
- 1969-11-28 FR FR6941319A patent/FR2025649A1/fr not_active Withdrawn
- 1969-12-06 DE DE19691961374 patent/DE1961374A1/en active Pending
- 1969-12-08 SE SE16892/69A patent/SE354528B/xx unknown
- 1969-12-08 BE BE742769D patent/BE742769A/xx unknown
-
1972
- 1972-04-19 US US00245619A patent/US3712812A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4252885A (en) | 1977-03-25 | 1981-02-24 | Bexford Limited | Polyester coated films using an aqueous polyester dispersion and photographic layer |
| US4304851A (en) | 1977-03-25 | 1981-12-08 | Bexford Limited | Polyester sublime layers for photographic layers with polyester bases |
Also Published As
| Publication number | Publication date |
|---|---|
| SU398059A3 (en) | 1973-09-17 |
| BE742769A (en) | 1970-06-08 |
| CA935019A (en) | 1973-10-09 |
| FR2025649A1 (en) | 1970-09-11 |
| JPS542090B1 (en) | 1979-02-02 |
| US3712812A (en) | 1973-01-23 |
| SE354528B (en) | 1973-03-12 |
| ES373975A1 (en) | 1972-03-16 |
| DE1961374A1 (en) | 1970-07-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 435 | Patent endorsed 'licences of right' on the date specified (sect. 35/1949) | ||
| PCNP | Patent ceased through non-payment of renewal fee |