GB1282658A - Stabilisation of organic products with phenol ethers and phenol esters - Google Patents

Stabilisation of organic products with phenol ethers and phenol esters

Info

Publication number
GB1282658A
GB1282658A GB07378/70A GB1737870A GB1282658A GB 1282658 A GB1282658 A GB 1282658A GB 07378/70 A GB07378/70 A GB 07378/70A GB 1737870 A GB1737870 A GB 1737870A GB 1282658 A GB1282658 A GB 1282658A
Authority
GB
United Kingdom
Prior art keywords
alkyl
bis
butylphenyl
methoxy
alkoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB07378/70A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Merck Patent GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Merck Patent GmbH filed Critical Merck Patent GmbH
Publication of GB1282658A publication Critical patent/GB1282658A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/375—Thiols containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00—Preserving by using additives, e.g. anti-oxidants
    • C11B5/0021—Preserving by using additives, e.g. anti-oxidants containing oxygen
    • C11B5/0035—Phenols; Their halogenated and aminated derivates, their salts, their esters with carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088—Neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089—Overbased salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/17—Electric or magnetic purposes for electric contacts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1282658 Stabilizing polymers MERCK PATENT GmbH 13 April 1970 [23 July 1969] 17378/70 Heading C3P [Also in Division C5] Polymers are stabilized against thermal and/or oxidative degradation by incorporating therein a compound of formula in which R 1 is C 1-18 alkyl or C 2-18 alkanoyl; R 2 is H or C 1-9 alkyl, alkoxy or alkanoyl, optionally substituted with Ar; R 3 and R 5 are H or C 1-6 alkyl; R 4 is H, Ar, Ar-oxy, Ar-thio or C 1-18 alkyl, alkoxy, alkanoyloxy or carbalkoxy optionally substituted with one or more Ar; R 6 is H, C 1-6 alkyl, alkoxy or alkanoyloxy, or a cyclopentyl or cyclohexyl group which may be substituted with a C 1-3 alkyl group; and Ar is phenyl which may be substituted with C 1-18 alkyl, alkoxy, alkanoyloxy or carbalkoxy, or a cyclopentyl or cyclohexyl group which may be C 1-3 alkyl substituted; provided that no aromatic ring bears more than one t-butyl group, and that R 1 is not alkyl if R 2 -R 6 are H or if R 4 is unsubstituted benzyl, or if R 4 is alkoxy and R 2 , R 3 , R 5 and R 6 are H. The polymer may be a polyethylene, polypropylene, polystyrene, polyvinyl chloride, polyester, polyether, polyacetal, polyamide or copolymer of butadiene with styrene, acrylonitrile or isobutylene, natural rubber, polybutadiene or polyisoprene. Many suitable stabilizers are listed and examples describe the stabilizing of polyethylene with 4 - nonylanisole, 4 - t - butylphenyl - n - butylether, 2- (or 3-) t - butyl-4- n - butoxyanisole, 2- (or 3-) t - butyl - 4 - trimethylacetoxyanisole, 4,4<SP>1</SP> - dimethoxybiphenyl, 4,4<SP>1 </SP>- diacetoxybiphenyl, bis - (2- methoxy- 4 - ethyl - 6 - t - butylphenyl) methane, bis - (2 - acetoxy - 4 - ethyl - 6 - t - butylphenyl) methane, bis - (2 - methoxy - 3 - (2 - methylcyclohexyl) - 5 - methylphenyl) methane, 2,2- bis - (4 - n - butoxyphenyl) propane, 1,1-bis- (2 - methyl - 4 - acetoxy - 5 - t - butylphenyl) butane, 1,1 - bis - (2 - methyl - 4 - methoxy-5-tbutylphenyl) butane, 1,1,3 - tris - (2 - methyl-4- methoxy - 5 - t - butylphenyl) butane and bis- (2 - methyl - 4 - methoxy - 5 - t - butylphenyl) sulphide.
GB07378/70A 1969-07-23 1970-04-13 Stabilisation of organic products with phenol ethers and phenol esters Expired GB1282658A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19691937384 DE1937384A1 (en) 1969-07-23 1969-07-23 Stabilizers

Publications (1)

Publication Number Publication Date
GB1282658A true GB1282658A (en) 1972-07-19

Family

ID=5740630

Family Applications (1)

Application Number Title Priority Date Filing Date
GB07378/70A Expired GB1282658A (en) 1969-07-23 1970-04-13 Stabilisation of organic products with phenol ethers and phenol esters

Country Status (6)

Country Link
BE (1) BE753701A (en)
DE (1) DE1937384A1 (en)
FR (1) FR2054267A5 (en)
GB (1) GB1282658A (en)
NL (1) NL7006925A (en)
RO (1) RO58336A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008002598A2 (en) * 2006-06-27 2008-01-03 Exxonmobil Research And Engineering Company Synthetic phenolic ether lubricant base stocks and lubricating oils comprising such base stocks mixed with co-base stocks and/or additives
EP3012314A1 (en) * 2014-10-23 2016-04-27 SK Innovation Co., Ltd. Lubricant base oil and method for preparing the same
AU2017209362B2 (en) * 2016-01-20 2021-01-28 Biomedical Analysis Center, Academy Of Military Medical Sciences Hydroquinone compound, preparation method therefor, and application in tumour resistance or immunomodulation

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57145803A (en) * 1981-03-05 1982-09-09 Sunstar Inc External decoloring agent for skin
ATE34994T1 (en) * 1983-10-04 1988-06-15 Milliken Res Corp POLYOLEFINE COMPOSITIONS.
US6103927A (en) * 1996-04-16 2000-08-15 Shell Oil Company Process for the carbonylation of ethylenically unsaturated compounds

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008002598A2 (en) * 2006-06-27 2008-01-03 Exxonmobil Research And Engineering Company Synthetic phenolic ether lubricant base stocks and lubricating oils comprising such base stocks mixed with co-base stocks and/or additives
WO2008002598A3 (en) * 2006-06-27 2008-05-15 Exxonmobil Res & Eng Co Synthetic phenolic ether lubricant base stocks and lubricating oils comprising such base stocks mixed with co-base stocks and/or additives
US7879778B2 (en) 2006-06-27 2011-02-01 Exxonmobil Research And Engineering Company Synthetic phenolic ether lubricant base stocks and lubricating oils comprising such base stocks mixed with co-base stocks and/or additives
EP3012314A1 (en) * 2014-10-23 2016-04-27 SK Innovation Co., Ltd. Lubricant base oil and method for preparing the same
US10125334B2 (en) 2014-10-23 2018-11-13 Sk Innovation Co., Ltd. Lubricant base oil and method for preparing the same
US10696914B2 (en) 2014-10-23 2020-06-30 Sk Innovation Co., Ltd. Lubricant base oil and method for preparing the same
AU2017209362B2 (en) * 2016-01-20 2021-01-28 Biomedical Analysis Center, Academy Of Military Medical Sciences Hydroquinone compound, preparation method therefor, and application in tumour resistance or immunomodulation

Also Published As

Publication number Publication date
DE1937384A1 (en) 1971-02-11
FR2054267A5 (en) 1971-04-16
RO58336A (en) 1975-09-15
BE753701A (en) 1971-01-20
NL7006925A (en) 1971-01-26

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Legal Events

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PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees