GB1278421A - The sulphonation of unsaturated carboxylic acids - Google Patents
The sulphonation of unsaturated carboxylic acidsInfo
- Publication number
- GB1278421A GB1278421A GB3270469A GB3270469A GB1278421A GB 1278421 A GB1278421 A GB 1278421A GB 3270469 A GB3270469 A GB 3270469A GB 3270469 A GB3270469 A GB 3270469A GB 1278421 A GB1278421 A GB 1278421A
- Authority
- GB
- United Kingdom
- Prior art keywords
- styrene
- june
- maintained
- sulphonation
- carboxylic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/02—Sulfonic acids having sulfo groups bound to acyclic carbon atoms
- C07C309/20—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic unsaturated carbon skeleton
- C07C309/22—Sulfonic acids having sulfo groups bound to acyclic carbon atoms of an acyclic unsaturated carbon skeleton containing carboxyl groups bound to the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D327/00—Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1278421 Polymerizing styrene LANKRO CHEMICALS Ltd A T PUGH and A G CHESWORTH 23 June 1970 [27 June 1969] 32704/69 Heading C3P [Also in Division C2] 257 g. of water, 30 g. of a sulphonated oleic acid, 1À5 g. sodium bicarbonate and 1À5 g. potassium persulphate were stirred until clear in a suitable vessel equipped with condenser, dropping funnel and thermometer. 22À5 g. of stabilized styrene were added and the mixture heated to 75‹ C. 202À5 g. of styrene was then added dropwise over a period of one hour, the temperature being maintained at 75‹ C. To complete the reaction, the mixture was heated to 82‹ C. for 25 minutes. The resulting product was a fine stable emulsion of low viscosity, which was maintained on storage.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3270469A GB1278421A (en) | 1969-06-27 | 1969-06-27 | The sulphonation of unsaturated carboxylic acids |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3270469A GB1278421A (en) | 1969-06-27 | 1969-06-27 | The sulphonation of unsaturated carboxylic acids |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1278421A true GB1278421A (en) | 1972-06-21 |
Family
ID=10342776
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3270469A Expired GB1278421A (en) | 1969-06-27 | 1969-06-27 | The sulphonation of unsaturated carboxylic acids |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1278421A (en) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4450011A (en) * | 1982-09-20 | 1984-05-22 | Westvaco Corporation | Cationic bituminous emulsions |
US4478642A (en) * | 1983-06-20 | 1984-10-23 | Westvaco Corporation | Amphoterics as emulsifiers for bituminous emulsions |
US4494992A (en) * | 1983-06-20 | 1985-01-22 | Westvaco Corporation | Amphoterics as emulsifiers for bituminous emulsions |
DE3537190A1 (en) * | 1984-10-20 | 1986-04-24 | Lion Corp., Tokio/Tokyo | METHOD FOR PRODUCING A MIXTURE FROM SATURED AND UNSATURATED FATTY ACID ESTERSULFONATES |
EP0355613A2 (en) * | 1988-08-19 | 1990-02-28 | Henkel Kommanditgesellschaft auf Aktien | Use of mixtures containing (A) alkali, ammonium and/or amine salts of sulfonated, unsaturated fatty acids, and (B) alkoxylated alkyl alcohols, as wetting agents |
EP0371369A1 (en) * | 1988-11-28 | 1990-06-06 | Henkel Kommanditgesellschaft auf Aktien | Liquid, concentrated anionic tensides and process for their preparation |
WO1991001972A1 (en) * | 1989-08-09 | 1991-02-21 | Henkel Kommanditgesellschaft Auf Aktien | Process for preparing light-coloured oleic acid sulfonates |
US5329030A (en) * | 1990-11-12 | 1994-07-12 | Henkel Kommanditgesellschaft Auf Aktien | Process for the production of concentrated aqueous dispersions of α-sulfofatty acide mono- and/or disalt |
US5429684A (en) * | 1990-12-10 | 1995-07-04 | Henkel Kommanditgesellschaft Auf Aktien | Water-based carpet cleaning composition and method |
US5523016A (en) * | 1991-05-29 | 1996-06-04 | Henkel Kommanditgesellschaft Auf Aktien | Liquid pourable and pumpable surfactant preparation |
US5591377A (en) * | 1991-10-15 | 1997-01-07 | Henkel Kommanditgesellschaft Auf Aktien | Viscous water-based surfactant preparation |
US5596032A (en) * | 1994-05-27 | 1997-01-21 | Westvaco Corporation | Slow-setting bituminous emulsions |
US5696074A (en) * | 1993-06-18 | 1997-12-09 | Henkel Kommanditgesellschaft Auf Aktien | Liquid crystalline, aqueous surfactant preparations |
US7666828B2 (en) | 2008-01-22 | 2010-02-23 | Stepan Company | Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them |
US7884064B2 (en) | 2009-01-21 | 2011-02-08 | Stepan Company | Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids |
US8119588B2 (en) | 2009-01-21 | 2012-02-21 | Stepan Company | Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof |
US8124577B2 (en) | 2009-01-21 | 2012-02-28 | Stepan Company | Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof |
WO2012061101A1 (en) | 2010-10-25 | 2012-05-10 | Stepan Company | Sulfonates from natural oil metathesis |
-
1969
- 1969-06-27 GB GB3270469A patent/GB1278421A/en not_active Expired
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4450011A (en) * | 1982-09-20 | 1984-05-22 | Westvaco Corporation | Cationic bituminous emulsions |
US4478642A (en) * | 1983-06-20 | 1984-10-23 | Westvaco Corporation | Amphoterics as emulsifiers for bituminous emulsions |
US4494992A (en) * | 1983-06-20 | 1985-01-22 | Westvaco Corporation | Amphoterics as emulsifiers for bituminous emulsions |
DE3537190A1 (en) * | 1984-10-20 | 1986-04-24 | Lion Corp., Tokio/Tokyo | METHOD FOR PRODUCING A MIXTURE FROM SATURED AND UNSATURATED FATTY ACID ESTERSULFONATES |
DE3537190C2 (en) * | 1984-10-20 | 1988-06-23 | Lion Corp., Tokio/Tokyo, Jp | |
EP0355613A2 (en) * | 1988-08-19 | 1990-02-28 | Henkel Kommanditgesellschaft auf Aktien | Use of mixtures containing (A) alkali, ammonium and/or amine salts of sulfonated, unsaturated fatty acids, and (B) alkoxylated alkyl alcohols, as wetting agents |
EP0355613A3 (en) * | 1988-08-19 | 1990-03-28 | Henkel Kommanditgesellschaft Auf Aktien | Use of mixtures containing (a) alkali, ammonium and/or amine salts of sulfonated, unsaturated fatty acids, and (b) alkoxylated alkyl alcohols and/or sulfosuccinic-acid esters, as wetting agents |
US5002683A (en) * | 1988-08-19 | 1991-03-26 | Henkel Kommanditgesellschaft Auf Aktien | Use of mixtures containing (A) alkali, ammonium and/or amine salts of sulfonated unsaturated fatty acids and (B) alkoxylated alkyl and/or alkenyl alcohols and/or sulfosuccinic acid esters as wetting agents |
EP0371369A1 (en) * | 1988-11-28 | 1990-06-06 | Henkel Kommanditgesellschaft auf Aktien | Liquid, concentrated anionic tensides and process for their preparation |
WO1990006300A1 (en) * | 1988-11-28 | 1990-06-14 | Henkel Kommanditgesellschaft Auf Aktien | Concentrated, free-flowing anionic surface-active agents and process for the production thereof |
WO1991001972A1 (en) * | 1989-08-09 | 1991-02-21 | Henkel Kommanditgesellschaft Auf Aktien | Process for preparing light-coloured oleic acid sulfonates |
US5294726A (en) * | 1989-08-09 | 1994-03-15 | Henkel Kommanditgesellschaft Auf Aktien | Process for the preparation of light-colored oleic acid sulfonates |
US5329030A (en) * | 1990-11-12 | 1994-07-12 | Henkel Kommanditgesellschaft Auf Aktien | Process for the production of concentrated aqueous dispersions of α-sulfofatty acide mono- and/or disalt |
US5429684A (en) * | 1990-12-10 | 1995-07-04 | Henkel Kommanditgesellschaft Auf Aktien | Water-based carpet cleaning composition and method |
US5523016A (en) * | 1991-05-29 | 1996-06-04 | Henkel Kommanditgesellschaft Auf Aktien | Liquid pourable and pumpable surfactant preparation |
US5591377A (en) * | 1991-10-15 | 1997-01-07 | Henkel Kommanditgesellschaft Auf Aktien | Viscous water-based surfactant preparation |
US5696074A (en) * | 1993-06-18 | 1997-12-09 | Henkel Kommanditgesellschaft Auf Aktien | Liquid crystalline, aqueous surfactant preparations |
US5596032A (en) * | 1994-05-27 | 1997-01-21 | Westvaco Corporation | Slow-setting bituminous emulsions |
US8129328B2 (en) | 2008-01-22 | 2012-03-06 | Stepan Company | Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them |
US7666828B2 (en) | 2008-01-22 | 2010-02-23 | Stepan Company | Sulfonated estolides and other derivatives of fatty acids, methods of making them, and compositions and processes employing them |
US8338358B2 (en) | 2008-01-22 | 2012-12-25 | Stepan Company | Compositions comprising sulfonated estolides and alkyl ester sulfonates, methods of making them, and compositions and processes employing them |
US7884064B2 (en) | 2009-01-21 | 2011-02-08 | Stepan Company | Light duty liquid detergent compositions of sulfonated estolides and other derivatives of fatty acids |
US8119588B2 (en) | 2009-01-21 | 2012-02-21 | Stepan Company | Hard surface cleaner compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof |
US8124577B2 (en) | 2009-01-21 | 2012-02-28 | Stepan Company | Personal care compositions of sulfonated estolides and other derivatives of fatty acids and uses thereof |
WO2012061101A1 (en) | 2010-10-25 | 2012-05-10 | Stepan Company | Sulfonates from natural oil metathesis |
EP2633018A4 (en) * | 2010-10-25 | 2015-09-09 | Stepan Co | Sulfonates from natural oil metathesis |
US9598359B2 (en) | 2010-10-25 | 2017-03-21 | Stepan Company | Sulfonates from natural oil metathesis |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |