GB1273770A - Dithiolanyl- or dithianyl-phosphoric or -thiophosphoric acid esters and processes for their preparation - Google Patents

Dithiolanyl- or dithianyl-phosphoric or -thiophosphoric acid esters and processes for their preparation

Info

Publication number
GB1273770A
GB1273770A GB38631/69A GB3863169A GB1273770A GB 1273770 A GB1273770 A GB 1273770A GB 38631/69 A GB38631/69 A GB 38631/69A GB 3863169 A GB3863169 A GB 3863169A GB 1273770 A GB1273770 A GB 1273770A
Authority
GB
United Kingdom
Prior art keywords
reacting
formula
compound
prepared
sulphur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB38631/69A
Inventor
Klaus Stoelzer
Ingeborg Hammann
Guenter Unterstenhoefer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19681793232 external-priority patent/DE1793232C3/en
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1273770A publication Critical patent/GB1273770A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D339/00—Heterocyclic compounds containing rings having two sulfur atoms as the only ring hetero atoms
    • C07D339/02—Five-membered rings
    • C07D339/06—Five-membered rings having the hetero atoms in positions 1 and 3, e.g. cyclic dithiocarbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D339/00—Heterocyclic compounds containing rings having two sulfur atoms as the only ring hetero atoms
    • C07D339/08—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
    • C07F9/655345—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms the sulfur atom being part of a five-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms
    • C07F9/655363—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having sulfur atoms, with or without selenium or tellurium atoms, as the only ring hetero atoms the sulfur atom being part of a six-membered ring

Abstract

1,273,770. Heterocyclic phosphoric and thiophosphoric acid derivatives. FARBENFABBIKEN BAYER A.G. 1 Aug., 1969 [20 Aug., 1968], No. 38631/69. Headings C2C and C2P. Novel compounds of the formula where R and R<SP>1</SP> are C 1-6 alkyl, X and Y are oxygen or sulphur, and n is 1 or 2, are prepared (a) by reacting a compound of formula with (RO)(R<SP>1</SP>O)P(Y)(SH) in the presence of an acid-binding agent or in the form of an alkali metal, alkaline earth metal or ammonium salt, or (b) by reacting a hydroxy compound of formula with a halide of formula (RO)(R<SP>1</SP>O)P(Y)(Hal) in the presence of a hydrogen halide acceptor or (c) reacting the hydroxy compound of (b) with a halide of formula (RO)(R<SP>1</SP>O)PHal in the presence of a halogen hydride acceptor and oxidizing the product or treating it with elemental sulphur or a sulphur-yielding agent. The hydroxymethyl starting materials are prepared by reacting 2,3-di-mercaptopropanol-(1) with an alkali metal methylate and treating the resulting mercaptide with a dihalo-methane or -ethane, or by reacting the dimercaptol with paraformaldehyde in dichloromethane or ethane in the presence of p-toluene sulphonic acid, or in the presence of HCl gas to yield the corresponding chloromethyl compound. The chloro compound is also prepared by reacting the hydroxymethyl compound with e.g. thionyl chloride. The compounds of Formula I may be used, with or without solvents and diluents as insecticides and acaricides.
GB38631/69A 1968-08-20 1969-08-01 Dithiolanyl- or dithianyl-phosphoric or -thiophosphoric acid esters and processes for their preparation Expired GB1273770A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19681793232 DE1793232C3 (en) 1968-08-20 Dithiolanyl or. Dithianyl phosphorus or thiophosphoric acid esters, process for their preparation and agents containing them

Publications (1)

Publication Number Publication Date
GB1273770A true GB1273770A (en) 1972-05-10

Family

ID=5707626

Family Applications (1)

Application Number Title Priority Date Filing Date
GB38631/69A Expired GB1273770A (en) 1968-08-20 1969-08-01 Dithiolanyl- or dithianyl-phosphoric or -thiophosphoric acid esters and processes for their preparation

Country Status (7)

Country Link
BE (1) BE737721A (en)
CH (1) CH525243A (en)
ES (1) ES370641A1 (en)
FR (1) FR2016018A1 (en)
GB (1) GB1273770A (en)
IL (1) IL32635A (en)
NL (1) NL6912607A (en)

Also Published As

Publication number Publication date
BE737721A (en) 1970-02-20
FR2016018A1 (en) 1970-04-30
CH525243A (en) 1972-07-15
DE1793232A1 (en) 1971-07-08
ES370641A1 (en) 1971-05-01
IL32635A (en) 1972-07-26
DE1793232B2 (en) 1976-04-01
IL32635A0 (en) 1969-09-25
NL6912607A (en) 1970-02-24

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee