GB1271061A - Self skinned polymer foams - Google Patents
Self skinned polymer foamsInfo
- Publication number
- GB1271061A GB1271061A GB46370A GB46370A GB1271061A GB 1271061 A GB1271061 A GB 1271061A GB 46370 A GB46370 A GB 46370A GB 46370 A GB46370 A GB 46370A GB 1271061 A GB1271061 A GB 1271061A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalysts
- preferred
- foam
- foams
- tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/161—Catalysts containing two or more components to be covered by at least two of the groups C08G18/166, C08G18/18 or C08G18/22
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/34—Chemical features in the manufacture of articles consisting of a foamed macromolecular core and a macromolecular surface layer having a higher density than the core
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
1,271,061. Self-skinned polymer foams. UPJOHN CO. 5 Jan., 1970 [10 Feb., 1969], No. 463/70. Headings C3C and C3R. Cellular polymer articles having an integrally formed non-cellular skin are formed by moulding a polymer foam forming reaction mixture in a closed mould, of a volume less than that which would be occupied by the resultant foam if the said mixture were allowed to rise freely, a catalyst system being chosen such that the interval between cream time and final rise time of the foam is not more than 33 seconds. Suitable foams may be composed of polyurethanes, polyureas, polyimides, polyamides, polyoxazolidinones and polyisocyanurates. Catalysts capable of providing suitable time intervals may be chosen by trial and error from conventional catalysts, or the required effect may be obtained by using excess quantities of conventional catalysts. Thus, polyurethane catalysts may be employed in amounts varying from 0À1 to 2À0% by weight of the total reactants. Preferred polyurethane catalysts are tertiary amines such as triethylene diamine and dimethylethanolamine, and organic derivatives of tin such as stannous octoate, dibutyl tin dilaurate and dibutyl tin diacetate. Mixtures of such tin and tertiary amine catalysts are particularly preferred. Preferred polyisocyanurate catalysts are tertiary amines such as N,N<SP>1</SP>,N<SP>11</SP>-tris (dialkylaminoalkyl) hexahydrotriazines, N.N-dialkylethanolamines and triethylene diamine in admixture with monomeric homocyclic polyepoxides such as novolac resin glycidyl ethers and glycidyl ethers of non-fused polynuclear phenols. In a preferred aspect of the invention the components of the foam forming reaction mixture are cooled to a temperature of between 0‹ C. to 15‹ C. before being brought together. Examples describe the preparation of integrally skinned rigid foams composed of polyurethanes and polyisocyanurates. Uses.-Upholstery, automobile bodies and padding, furniture construction, walls, partitions and table tops.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79810369A | 1969-02-10 | 1969-02-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1271061A true GB1271061A (en) | 1972-04-19 |
Family
ID=25172555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB46370A Expired GB1271061A (en) | 1969-02-10 | 1970-01-05 | Self skinned polymer foams |
Country Status (4)
| Country | Link |
|---|---|
| AT (1) | AT309830B (en) |
| DE (1) | DE2001913B2 (en) |
| FR (1) | FR2030395B1 (en) |
| GB (1) | GB1271061A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718462A (en) * | 2020-04-15 | 2020-09-29 | 黎明化工研究设计院有限责任公司 | Self-skinning polyurethane foam rapid demoulding composition for automobile steering wheel and preparation method thereof |
| CN114716638A (en) * | 2022-04-14 | 2022-07-08 | 佳化化学科技发展（上海）有限公司 | Polyurethane self-skinning foam and preparation method and application thereof |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1071942B (en) * | 1954-02-09 | 1959-12-24 | Farbenfabriken Bayer Aktiengesellschaft, Leverkusen-Bayerwerk | Process for the production of foam bodies based on polyurethane and surrounded by cover layers |
| DE1181897B (en) * | 1957-03-22 | 1964-11-19 | Dow Chemical Co | Injection molding process for the production of foam structures from expandable cores of thermoplastic resinous material |
| GB914448A (en) * | 1961-01-13 | 1963-01-02 | Bruce Gardner Hood | Improvements relating to the moulding of plastic foam |
| US3178490A (en) * | 1961-10-06 | 1965-04-13 | Thiokol Chemical Corp | Process for producing a foamed plastic article having a dense skin |
| GB1146661A (en) * | 1965-04-29 | 1969-03-26 | Ici Ltd | Foamed polymers |
| FR1499903A (en) * | 1966-03-02 | 1967-11-03 | Kuhlmann Ets | Polyurethane-polyurea composition resulting in a single stage in a cellular product and a compact elastomer |
| FR1525413A (en) * | 1966-04-22 | 1968-05-17 | Ici Ltd | Process for manufacturing rigid polymer foams containing a cyclic structure of the isocyanurate type |
| CH502399A (en) * | 1967-03-24 | 1971-01-31 | Mobay Chemical Corp | Process for the production of a foam containing isocyanurate groups, means for carrying out the process and foam obtained in this way |
-
1970
- 1970-01-05 GB GB46370A patent/GB1271061A/en not_active Expired
- 1970-01-16 DE DE19702001913 patent/DE2001913B2/en not_active Ceased
- 1970-02-09 AT AT115170A patent/AT309830B/en not_active IP Right Cessation
- 1970-02-09 FR FR7004460A patent/FR2030395B1/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111718462A (en) * | 2020-04-15 | 2020-09-29 | 黎明化工研究设计院有限责任公司 | Self-skinning polyurethane foam rapid demoulding composition for automobile steering wheel and preparation method thereof |
| CN114716638A (en) * | 2022-04-14 | 2022-07-08 | 佳化化学科技发展（上海）有限公司 | Polyurethane self-skinning foam and preparation method and application thereof |
| CN114716638B (en) * | 2022-04-14 | 2023-12-01 | 佳化化学科技发展（上海）有限公司 | Polyurethane self-skinning foam and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2001913B2 (en) | 1981-06-25 |
| FR2030395A1 (en) | 1970-11-13 |
| AT309830B (en) | 1973-09-10 |
| FR2030395B1 (en) | 1974-06-14 |
| DE2001913A1 (en) | 1970-09-10 |
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