GB1265439A - - Google Patents

Info

Publication number
GB1265439A
GB1265439A GB1265439DA GB1265439A GB 1265439 A GB1265439 A GB 1265439A GB 1265439D A GB1265439D A GB 1265439DA GB 1265439 A GB1265439 A GB 1265439A
Authority
GB
United Kingdom
Prior art keywords
polyacrylonitrile
filaments
filament
methacrylonitrile
crimped
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1265439A publication Critical patent/GB1265439A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/08Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18Homopolymers or copolymers of nitriles
    • C08L33/20Homopolymers or copolymers of acrylonitrile

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Multicomponent Fibers (AREA)

Abstract

1,265,439. Crimped polyacrylonitrile composite filaments. MITSUBISHI RAYON CO. Ltd. 21 April, 1970, No. 19068/70. Heading B5B. [Also in Division D1] Acrylic crimped composite filaments of either the side-by-side, i.e. conjugate type, or the eccentric sheath-core type comprise two components, one being polyacrylonitrile, the other being an acrylonitrile-methacrylonitrile copolymer containing from 5 to 50% (preferably 7 to 30%) by weight of methacrylonitrile and the polyacrylonitrile component occupying the outer portion of each crimp. Either one or both components of the composite filaments may contain from 0À3 to 6% by weight of a monomer unit having a -SO 3 X or -OSO 3 X group, where X is a monovalent alkali metal, -NH 4 or hydrogen. Examples of such monomers are 2-vinyl pyridine, 2-methyl-5-vinyl pyridine, vinyl benzenesulphonic acid, and sodium methallyl sulphonate. 'The filaments may be produced by separately dissolving polyacrylonitrile and acrylonitrile-methacrylonitrile copolymer containing from 5-50% methacrylonitrile in a solvent suitable for dry-spinning, extruding the resulting spinning solutions simultaneously in side-by-side or eccentric sheath-core relationship into an evaporative medium to form composite filament, drawing said filament in a hot water bath, drying the drawn filament and then heating the dried filament in a relaxed state to develop crimps. The filaments may be mechanically crimped before being subjected to the relaxing step.
GB1265439D 1970-04-21 1970-04-21 Expired GB1265439A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1906870 1970-04-21
DE19702019803 DE2019803A1 (en) 1970-04-21 1970-04-23 Acrylic composite fiber and process for making them
FR7018848A FR2087562A5 (en) 1970-04-21 1970-05-22

Publications (1)

Publication Number Publication Date
GB1265439A true GB1265439A (en) 1972-03-01

Family

ID=27182551

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1265439D Expired GB1265439A (en) 1970-04-21 1970-04-21

Country Status (3)

Country Link
DE (1) DE2019803A1 (en)
FR (1) FR2087562A5 (en)
GB (1) GB1265439A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4309475A (en) 1980-02-14 1982-01-05 E. I. Du Pont De Nemours And Company Bicomponent acrylic fiber

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT963572B (en) * 1972-07-31 1974-01-21 Snam Progetti PROCESS OF IRONING THREADS WITH BICOMPOSED ACRYLIC DYES AND THREAD OBTAINED BY THIS PROCEDURE
CN108728973B (en) * 2018-06-21 2021-11-26 福建恒捷实业有限公司 Production method of wool-like polyamide fiber

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4309475A (en) 1980-02-14 1982-01-05 E. I. Du Pont De Nemours And Company Bicomponent acrylic fiber

Also Published As

Publication number Publication date
FR2087562A5 (en) 1971-12-31
DE2019803A1 (en) 1971-12-16

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees