GB1263652A - Phosphoric-(phosphonic)- and thionophosphoric-(phosphonic)-acid esters,-ester amides and -diamides - Google Patents
Phosphoric-(phosphonic)- and thionophosphoric-(phosphonic)-acid esters,-ester amides and -diamidesInfo
- Publication number
- GB1263652A GB1263652A GB26028/70A GB2602870A GB1263652A GB 1263652 A GB1263652 A GB 1263652A GB 26028/70 A GB26028/70 A GB 26028/70A GB 2602870 A GB2602870 A GB 2602870A GB 1263652 A GB1263652 A GB 1263652A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- phosphonic
- formula
- hydroxy
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002253 acid Substances 0.000 title abstract 3
- 150000002148 esters Chemical class 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- XQEKXIYVPKTHAB-UHFFFAOYSA-N 2-oxo-6-propan-2-yl-1h-pyridine-3-carbonitrile Chemical compound CC(C)C1=CC=C(C#N)C(=O)N1 XQEKXIYVPKTHAB-UHFFFAOYSA-N 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 239000011591 potassium Substances 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 159000000000 sodium salts Chemical class 0.000 abstract 2
- DYUMBFTYRJMAFK-UHFFFAOYSA-N 3-cyano-2-pyridone Chemical class OC1=NC=CC=C1C#N DYUMBFTYRJMAFK-UHFFFAOYSA-N 0.000 abstract 1
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Chemical group 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 125000004663 dialkyl amino group Chemical group 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000000417 fungicide Substances 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical group 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 150000003222 pyridines Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Pyridine Compounds (AREA)
Abstract
1,263,652. Pyridine derivatives of phosphorus acids; sodium salt of 2-hydroxy-3-cyan-6-isopropyl pyridine. FARBENFABRIKEN BAYER A.G. 29 May, 1970 [30 May, 1969], No. 26028/70. Headings C2C and C2P. The invention comprises compounds of the Formula I where R 2 is aryl or C 1-6 alkyl, R 3 is hydrogen or methyl, R is C 1-6 alkyl, R 1 is C 1-6 alkyl or alkoxy, monoalkylamino or dialkylamino, or, if R 2 is aryl or C 2-6 alkyl, R 1 may be aryl, X is oxygen or sulphur and Y is oxygen, -NR 4 - or -NH-, where R 4 is alkyl. The compounds of Formula I may be prepared by reacting an appropriate 2 - hydroxy - 3 - cyano - pyridine derivative, or a sodium, potassium or ammonium salt thereof, with a halide of the Formula III or by reacting an appropriate 2-halogeno-3- cyanopyridine derivative with an acid or salt or the Formula V where M is hydrogen, sodium, potassium or ammonium. The compounds of Formula I may be used as insecticides, acaricides or fungicides, either alone or as the active ingredient in a composition comprising a solid or liquid diluent or carrier. The sodium salt of 2-hydroxy-3-cyan-6-isopropylpyridine is prepared by reacting 2- hydroxy - 3 - cyan - 6 - isopropylpyridine with sodium methylate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19691927643 DE1927643A1 (en) | 1969-05-30 | 1969-05-30 | Phosphorus (phosphonic) or thionophosphorus (phosphonic) acid esters, ester amides or diamides, processes for their preparation and their use as insecticides, acaricides and fungicides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1263652A true GB1263652A (en) | 1972-02-16 |
Family
ID=5735668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB26028/70A Expired GB1263652A (en) | 1969-05-30 | 1970-05-29 | Phosphoric-(phosphonic)- and thionophosphoric-(phosphonic)-acid esters,-ester amides and -diamides |
Country Status (15)
| Country | Link |
|---|---|
| JP (2) | JPS4817277B1 (en) |
| AT (1) | AT297027B (en) |
| BE (1) | BE751171A (en) |
| CH (1) | CH498157A (en) |
| CS (1) | CS161749B2 (en) |
| DE (1) | DE1927643A1 (en) |
| DK (1) | DK128121B (en) |
| ES (1) | ES380220A1 (en) |
| FR (1) | FR2043833A1 (en) |
| GB (1) | GB1263652A (en) |
| IL (1) | IL34448A (en) |
| NL (1) | NL7007733A (en) |
| PL (1) | PL69776B1 (en) |
| RO (1) | RO58847A (en) |
| SU (1) | SU460631A3 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3445465A1 (en) * | 1984-12-13 | 1986-06-19 | Bayer Ag, 5090 Leverkusen | PYRIMIDINYL THIONOPHOSPHORIC ACID ESTER |
-
1969
- 1969-05-30 DE DE19691927643 patent/DE1927643A1/en active Pending
-
1970
- 1970-05-01 CH CH660070A patent/CH498157A/en not_active IP Right Cessation
- 1970-05-04 IL IL34448A patent/IL34448A/en unknown
- 1970-05-14 RO RO63358A patent/RO58847A/ro unknown
- 1970-05-28 JP JP45045254A patent/JPS4817277B1/ja active Pending
- 1970-05-28 JP JP45045255A patent/JPS526342B1/ja active Pending
- 1970-05-28 NL NL7007733A patent/NL7007733A/xx unknown
- 1970-05-29 CS CS3788A patent/CS161749B2/cs unknown
- 1970-05-29 FR FR7019721A patent/FR2043833A1/fr not_active Withdrawn
- 1970-05-29 DK DK278870AA patent/DK128121B/en unknown
- 1970-05-29 SU SU1443808A patent/SU460631A3/en active
- 1970-05-29 AT AT481470A patent/AT297027B/en not_active IP Right Cessation
- 1970-05-29 PL PL1970140959A patent/PL69776B1/pl unknown
- 1970-05-29 GB GB26028/70A patent/GB1263652A/en not_active Expired
- 1970-05-29 BE BE751171D patent/BE751171A/en unknown
- 1970-05-30 ES ES380220A patent/ES380220A1/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IL34448A (en) | 1973-01-30 |
| SU460631A3 (en) | 1975-02-15 |
| JPS526342B1 (en) | 1977-02-21 |
| PL69776B1 (en) | 1973-08-31 |
| BE751171A (en) | 1970-11-30 |
| ES380220A1 (en) | 1972-08-16 |
| AT297027B (en) | 1972-03-10 |
| DE1927643A1 (en) | 1970-12-03 |
| CH498157A (en) | 1970-10-31 |
| RO58847A (en) | 1976-03-15 |
| NL7007733A (en) | 1970-12-02 |
| JPS4817277B1 (en) | 1973-05-28 |
| IL34448A0 (en) | 1970-07-19 |
| FR2043833A1 (en) | 1971-02-19 |
| CS161749B2 (en) | 1975-06-10 |
| DK128121B (en) | 1974-03-04 |
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