GB1261672A - Synthetic resin dispersions - Google Patents

Synthetic resin dispersions

Info

Publication number
GB1261672A
GB1261672A GB9917/70A GB991770A GB1261672A GB 1261672 A GB1261672 A GB 1261672A GB 9917/70 A GB9917/70 A GB 9917/70A GB 991770 A GB991770 A GB 991770A GB 1261672 A GB1261672 A GB 1261672A
Authority
GB
United Kingdom
Prior art keywords
synthetic resin
emulsifying agent
butyl acrylate
monomer composition
aqueous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9917/70A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Roehm GmbH Darmstadt
Original Assignee
Roehm GmbH Darmstadt
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm GmbH Darmstadt filed Critical Roehm GmbH Darmstadt
Publication of GB1261672A publication Critical patent/GB1261672A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paper (AREA)
  • Paints Or Removers (AREA)

Abstract

1,261,672. Acrylic polymers. ROHM G.m.b.H. 2 March, 1970 [1 March, 1969], No. 9917/70. Heading C3P. Aqueous dispersions of acrylic resins are produced by polymerizing or copolymerizing a monomer composition comprising (a) at least one ester of acrylic and/or methacrylic acid; optionally (b) styrene or a homologue thereof; and, optionally (c) one or more other copolymerizable monomers; the combined amount of component (a), and (when present) component (b) in the monomer composition being at least 50% by weight; the said monomer composition being in the form of an aqueous emulsion thereof containing an anionic emulsifying agent; the aqueous emulsion being produced by adding the monomer composition, preferably in the form of an aqueous emulsion additive with the anionic emulsifying agent and part of the water of the final aqueous emulsion, to an appropriate amount of water, if desired, containing an amount of the anionic emulsifying agent, to produce the desired emulsion; the said emulsifying agent being present in the water at the start of the polymerization or copolymerization reaction in a concentration within the range of from 0À3-3À0 times the critical micelle formation concentration (C.M.C.) based on the aqueous phase of the emulsion, the concentration of said emulsifying agent being such that the aqueous dispersion of the synthetic resin obtained has an average particle size and particle size distribution such that upon diluting the dispersion to 10% solids content and centrifuging the diluted dispersion at 10,000 g for 15 minutes at 20‹C. with a maximum free sedimentation path of 43 mm., a sediment amounting to 10 to 80% by weight of the synthetic resin is obtained; and the amount of monomer composition used being selected whereby the aqueous dispersion of the synthetic resin obtained contains at least 55% by weight of the synthetic resin. In the examples, using ammonium persulphate with sodium lauryl sulphate or ethoxylated, sulphated and neutralized alkyl phenol, there are polymerized (1) n-butyl acrylate / acrylonitrile / N-methylol methacrylamide; (2) n-butyl acrylate/methyl methacrylate / N-methylol methacrylamide / methacrylamide/glycol dimethacrylate; (3) n-butyl acrylate/methyl methacrylate; (4) styrene/n-butyl acrylate/methacrylic acid; (5) ethyl acrylate/ methyl methacrylate; (6) methyl methacrylate/ butyl acrylate/acrylic acid.
GB9917/70A 1969-03-01 1970-03-02 Synthetic resin dispersions Expired GB1261672A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1910488A DE1910488C3 (en) 1969-03-01 1969-03-01 Process for the production of at least 55 percent acrylate dispersions

Publications (1)

Publication Number Publication Date
GB1261672A true GB1261672A (en) 1972-01-26

Family

ID=5726819

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9917/70A Expired GB1261672A (en) 1969-03-01 1970-03-02 Synthetic resin dispersions

Country Status (4)

Country Link
DE (1) DE1910488C3 (en)
FR (1) FR2031312A5 (en)
GB (1) GB1261672A (en)
NL (1) NL161170C (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5842608A (en) * 1981-08-29 1983-03-12 レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Plastic dispersion comprising acryl monomer majorly as plastic component and manufacture
US4395515A (en) 1981-01-22 1983-07-26 Rohm Gmbh Resin dispersions having high pigment binding capacity
US4525418A (en) * 1981-12-01 1985-06-25 Rohm Gmbh Two-layered packaging material for foodstuffs one layer of which comprises a polymer blend
US7037975B2 (en) 1999-03-18 2006-05-02 Wacker Chemie Ag Process for producing high-solids aqueous polymer dispersions
CN114621384A (en) * 2021-04-15 2022-06-14 江苏长海复合材料股份有限公司 Emulsion capable of reducing slurry bonding speed and preparation method thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2535372C3 (en) * 1975-08-08 1986-07-10 Hoechst Ag, 6230 Frankfurt Process for the production of aqueous plastic dispersions
DE3129262A1 (en) * 1981-07-24 1983-02-10 Röhm GmbH, 6100 Darmstadt "AGENT FOR COATING PLASTIC OBJECTS WITH ANTISTATIC AND ANTI-FOG EFFECT AND THEIR APPLICATION"
DE3130924A1 (en) * 1981-08-05 1983-02-17 Röhm GmbH, 6100 Darmstadt SURFACE-BASED SYSTEMS FOR FIXING SUBSTRATES CONTAINING NUCLEOPHILE GROUPS
DE3704563A1 (en) * 1987-02-13 1988-08-25 Roehm Gmbh Welded casing of acrylic resin-coated, textile sheet-like material for direct casing of foodstuffs, and process for the production thereof
WO1996010587A1 (en) * 1994-09-30 1996-04-11 Nippon Zeon Co., Ltd. Copolymer latex and process for producing the same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3126360A (en) * 1959-09-23 1964-03-24 Polycondensation catalysts for im-

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4395515A (en) 1981-01-22 1983-07-26 Rohm Gmbh Resin dispersions having high pigment binding capacity
JPS5842608A (en) * 1981-08-29 1983-03-12 レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Plastic dispersion comprising acryl monomer majorly as plastic component and manufacture
JPH0337562B2 (en) * 1981-08-29 1991-06-06 Roehm Gmbh
US4525418A (en) * 1981-12-01 1985-06-25 Rohm Gmbh Two-layered packaging material for foodstuffs one layer of which comprises a polymer blend
US7037975B2 (en) 1999-03-18 2006-05-02 Wacker Chemie Ag Process for producing high-solids aqueous polymer dispersions
CN114621384A (en) * 2021-04-15 2022-06-14 江苏长海复合材料股份有限公司 Emulsion capable of reducing slurry bonding speed and preparation method thereof

Also Published As

Publication number Publication date
NL161170C (en) 1982-12-16
NL161170B (en) 1979-08-15
FR2031312A5 (en) 1970-11-13
NL7001940A (en) 1970-09-03
DE1910488C3 (en) 1986-03-27
DE1910488B2 (en) 1974-02-21
DE1910488A1 (en) 1970-09-03

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