GB1249079A - A process for epoxidizing olefins with organic hydroperoxides - Google Patents

A process for epoxidizing olefins with organic hydroperoxides

Info

Publication number
GB1249079A
GB1249079A GB05373/70D GB1537370D GB1249079A GB 1249079 A GB1249079 A GB 1249079A GB 05373/70 D GB05373/70 D GB 05373/70D GB 1537370 D GB1537370 D GB 1537370D GB 1249079 A GB1249079 A GB 1249079A
Authority
GB
United Kingdom
Prior art keywords
silica
catalysts
molybdenum
didymium
april
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB05373/70D
Inventor
F Wattimena
H P Wulff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1249079A publication Critical patent/GB1249079A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

1,249,079. Epoxidation catalysts. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 1 April, 1970 [2 April, 1969], No. 15373/70. Heading B1E. [Also in Division C2] Catalysts used in the epoxidation of olefinic compounds with organic hydroperoxides comprise titanium in chemical combination with a solid silica and/or an inorganic silicate. In addition the catalyst may contain a promoter e.g. a compound of magnesium, calcium, strontium or barium and also an oxide or hydroxide of boron, tin, miobium, tantalum, chromium, molybdenum, rhenium, uranium, bismuth or rare earth metals (atomic numbers 57-71). Preferably the catalyst has a specific surface area of at least 1m<SP>2</SP>/g. In the examples catalysts are used comprising in addition to the titanium compound the following:-(a) zirconium, (b) niobium, (c) boron, (d) tin, (e) "didymium" (a complex mixture of rare earth metals), (f) molybdenum, (g) molybdenum and didymium and (h) alumina alone or with magnesium or calcium. For comparative purposes examples are given of the use of other catalysts e.g. mixtures of titania and silica or silicates, various other metals are silica and various metal compounds without silica.
GB05373/70D 1969-04-02 1970-04-01 A process for epoxidizing olefins with organic hydroperoxides Expired GB1249079A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US81292069A 1969-04-02 1969-04-02

Publications (1)

Publication Number Publication Date
GB1249079A true GB1249079A (en) 1971-10-06

Family

ID=25210968

Family Applications (1)

Application Number Title Priority Date Filing Date
GB05373/70D Expired GB1249079A (en) 1969-04-02 1970-04-01 A process for epoxidizing olefins with organic hydroperoxides

Country Status (15)

Country Link
JP (1) JPS5030049B1 (en)
AT (1) AT302983B (en)
BE (1) BE748314A (en)
BR (1) BR7017923D0 (en)
CH (1) CH543497A (en)
DE (1) DE2015503C3 (en)
DK (1) DK133746B (en)
ES (1) ES378130A1 (en)
FR (1) FR2042772A5 (en)
GB (1) GB1249079A (en)
IE (1) IE34185B1 (en)
NL (1) NL145233C (en)
NO (1) NO127499B (en)
SE (1) SE375530B (en)
ZA (1) ZA702171B (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0345856A1 (en) 1988-06-08 1989-12-13 Shell Internationale Researchmaatschappij B.V. A process for the preparation of an oxirane compound
US5760253A (en) * 1997-01-29 1998-06-02 Arco Chemical Technology, L.P. Catalytic converter and method for highly exothermic reactions
US5795555A (en) * 1994-11-24 1998-08-18 Alive; Keshavaraja Micro-meso porous amorphous titanium silicates and a process for preparing the same
US5840933A (en) * 1996-10-29 1998-11-24 Arco Chemical Technology, L.P. Catalytic converter system and progress
US5932751A (en) * 1998-06-23 1999-08-03 Arco Chemical Technology, L.P. Epoxidation catalyst and process
WO2001097967A1 (en) * 2000-06-21 2001-12-27 Shell Internationale Research Maatschappij B.V. Catalyst composition, process for its preparation and use thereof
WO2002066433A1 (en) * 2001-02-19 2002-08-29 Lonza Ag Process and catalyst for the preparation of acetylpyridines
US6562987B1 (en) 2002-02-28 2003-05-13 Arco Chemical Technology, L.P. Method for highly exothermic epoxidation reactions
US6605733B2 (en) * 2001-01-15 2003-08-12 Maruzen Petrochemical Co., Ltd. Titanium-containing solid catalyst and process for producing epoxy compound using the same
FR2841797A1 (en) * 2002-07-03 2004-01-09 Centre Nat Rech Scient CATALYSTS BASED ON TUNGSTEN
US7067673B2 (en) 2001-02-19 2006-06-27 Lonza Ag Process and catalyst for the preparation of acetylpyridines
EP1894621A1 (en) * 2006-08-29 2008-03-05 Oxeno Olefinchemie GmbH Catalyst and method for producing iso-olefins
WO2009106237A2 (en) * 2008-02-26 2009-09-03 Bayer Materialscience Ag Catalyst for the synthesis of alkyl carbamates, the method for preparing the same and the use thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3322745A1 (en) * 1983-06-24 1985-01-03 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING OXIRANES
US5723637A (en) * 1995-12-06 1998-03-03 Sumitomo Chemical Company, Limited Process for producing propylene oxide
CN111377951B (en) * 2018-12-28 2022-09-20 万华化学集团股份有限公司 Rare earth metal compound, preparation method, composition and method for catalyzing olefin epoxidation

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1518644A1 (en) * 1965-04-09 1969-04-03 Huels Chemische Werke Ag Process for the catalytic epoxidation of olefinic compounds

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0345856A1 (en) 1988-06-08 1989-12-13 Shell Internationale Researchmaatschappij B.V. A process for the preparation of an oxirane compound
US5795555A (en) * 1994-11-24 1998-08-18 Alive; Keshavaraja Micro-meso porous amorphous titanium silicates and a process for preparing the same
US5840933A (en) * 1996-10-29 1998-11-24 Arco Chemical Technology, L.P. Catalytic converter system and progress
US6153153A (en) * 1996-10-29 2000-11-28 Arco Chemical Technology, L.P. Exothermic reaction system
US5760253A (en) * 1997-01-29 1998-06-02 Arco Chemical Technology, L.P. Catalytic converter and method for highly exothermic reactions
US5932751A (en) * 1998-06-23 1999-08-03 Arco Chemical Technology, L.P. Epoxidation catalyst and process
WO2001097967A1 (en) * 2000-06-21 2001-12-27 Shell Internationale Research Maatschappij B.V. Catalyst composition, process for its preparation and use thereof
US7713906B2 (en) 2000-06-21 2010-05-11 Shell Oil Company Catalyst composition, process for its preparation and use thereof
US6605733B2 (en) * 2001-01-15 2003-08-12 Maruzen Petrochemical Co., Ltd. Titanium-containing solid catalyst and process for producing epoxy compound using the same
US7067673B2 (en) 2001-02-19 2006-06-27 Lonza Ag Process and catalyst for the preparation of acetylpyridines
WO2002066433A1 (en) * 2001-02-19 2002-08-29 Lonza Ag Process and catalyst for the preparation of acetylpyridines
US6562987B1 (en) 2002-02-28 2003-05-13 Arco Chemical Technology, L.P. Method for highly exothermic epoxidation reactions
FR2841797A1 (en) * 2002-07-03 2004-01-09 Centre Nat Rech Scient CATALYSTS BASED ON TUNGSTEN
WO2004004893A3 (en) * 2002-07-03 2004-04-15 Centre Nat Rech Scient Catalysts comprising a tungsten oxide layer on a zirconia and/or titanium oxide support
WO2004004893A2 (en) * 2002-07-03 2004-01-15 Centre National De La Recherche Scientifique (C.N.R.S) Catalysts comprising a tungsten oxide layer on a zirconia and/or titanium oxide support
US7851401B2 (en) 2002-07-03 2010-12-14 Centre National De La Recherche Scientifique (C.N.R.S.) Tungsten catalysts
EP1894621A1 (en) * 2006-08-29 2008-03-05 Oxeno Olefinchemie GmbH Catalyst and method for producing iso-olefins
US7977523B2 (en) 2006-08-29 2011-07-12 Evonik Oxeno Gmbh Catalyst and process for preparing isoolefins
EP2620214A2 (en) * 2006-08-29 2013-07-31 Evonik Oxeno GmbH Method for manufacturing a catalyst, catalyst thereby obtained and method for manufacturing iso-olefines
EP2620214A3 (en) * 2006-08-29 2014-01-01 Evonik Degussa GmbH Method for manufacturing a catalyst, catalyst thereby obtained and method for manufacturing iso-olefines
US8680356B2 (en) 2006-08-29 2014-03-25 Evonik Oxeno Gmbh Catalyst and process for preparing isoolefins
WO2009106237A2 (en) * 2008-02-26 2009-09-03 Bayer Materialscience Ag Catalyst for the synthesis of alkyl carbamates, the method for preparing the same and the use thereof
WO2009106237A3 (en) * 2008-02-26 2010-01-21 Bayer Materialscience Ag Catalyst for the synthesis of alkyl carbamates, the method for preparing the same and the use thereof

Also Published As

Publication number Publication date
FR2042772A5 (en) 1971-02-12
NO127499B (en) 1973-07-02
DE2015503A1 (en) 1970-10-29
JPS5030049B1 (en) 1975-09-29
NL7004582A (en) 1970-10-06
BR7017923D0 (en) 1973-01-11
NL145233C (en) 1980-12-15
SE375530B (en) 1975-04-21
ZA702171B (en) 1971-11-24
DE2015503C3 (en) 1981-04-09
AT302983B (en) 1972-11-10
DK133746B (en) 1976-07-12
BE748314A (en) 1970-10-01
NL145233B (en) 1975-03-17
DE2015503B2 (en) 1980-04-24
DK133746C (en) 1976-11-29
IE34185L (en) 1970-10-02
ES378130A1 (en) 1972-06-01
IE34185B1 (en) 1975-03-05
CH543497A (en) 1973-10-31

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE20 Patent expired after termination of 20 years