GB1248988A - Oxo process - Google Patents

Oxo process

Info

Publication number
GB1248988A
GB1248988A GB28789/69A GB2878969A GB1248988A GB 1248988 A GB1248988 A GB 1248988A GB 28789/69 A GB28789/69 A GB 28789/69A GB 2878969 A GB2878969 A GB 2878969A GB 1248988 A GB1248988 A GB 1248988A
Authority
GB
United Kingdom
Prior art keywords
alkyl
aryloxy
alkoxy
aryl
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB28789/69A
Inventor
Malcolm John Lawrenson
Michael Green
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Priority to GB28789/69A priority Critical patent/GB1248988A/en
Priority to NL7007892A priority patent/NL7007892A/xx
Priority to BE751353D priority patent/BE751353A/en
Priority to DE19702026926 priority patent/DE2026926A1/en
Priority to FR7020113A priority patent/FR2049773A5/fr
Publication of GB1248988A publication Critical patent/GB1248988A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,248,988. Oxo process. BP CHEMICALS Ltd. 13 May, 1970 [6 June, 1969], No. 28789/69. Heading C2C. A process for the hydroformylation of olefins to aldehydes comprises reacting an olefin with carbon monoxide and hydrogen at elevated temperature and pressure in the presence of a complex of the form MLL<SP>1</SP>(CO) 3 where M is Ru or Os; L is CO or R<SP>1</SP>R<SP>2</SP>R<SP>3</SP>P or R<SP>6</SP>NC; L<SP>1</SP> is RR<SP>4</SP>R<SP>5</SP>P or R<SP>7</SP>NC; R is an alkyl, alkoxy, aryloxy, or alkaryloxy group, R<SP>1</SP>, R<SP>2</SP>, R<SP>3</SP>, R<SP>4</SP>, R<SP>5</SP>, are alkyl, alkoxy, aryl, aryloxy, alkaryl or alkaryloxy groups and R<SP>6</SP>, R<SP>7</SP> are alkyl, aryl or alkaryl groups or a complex formed from the above by the addition of hydrogen with or without elimination of one of the other ligands. The complexes of formulµ Ru(CO) 3 (Me 2 PhP) 2 ; Ru(CO) 4 (Ph 3 P); Ru(CO) 4 (PhMe 2 P); Ru(CO) 3 - [(MeO) 3 P] 2 ; Ru(CO) 3 [(PhO) 3 P] 2 and Ru(CO) 3 - [EtC(CH 2 O) 3 P] 2 and Ru(CO) 3 (tBuNC) 2 are prepared by reacting cyclooctatetraenetricarbonylruthenium with the appropriate phosphorus compound or isonitrile.
GB28789/69A 1969-06-06 1969-06-06 Oxo process Expired GB1248988A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB28789/69A GB1248988A (en) 1969-06-06 1969-06-06 Oxo process
NL7007892A NL7007892A (en) 1969-06-06 1970-06-01
BE751353D BE751353A (en) 1969-06-06 1970-06-02 OXO PROCESS AND CATALYZERS FOR ITS EXECUTION
DE19702026926 DE2026926A1 (en) 1969-06-06 1970-06-02 Process for the production of aldehydes
FR7020113A FR2049773A5 (en) 1969-06-06 1970-06-02

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB28789/69A GB1248988A (en) 1969-06-06 1969-06-06 Oxo process

Publications (1)

Publication Number Publication Date
GB1248988A true GB1248988A (en) 1971-10-06

Family

ID=10281203

Family Applications (1)

Application Number Title Priority Date Filing Date
GB28789/69A Expired GB1248988A (en) 1969-06-06 1969-06-06 Oxo process

Country Status (5)

Country Link
BE (1) BE751353A (en)
DE (1) DE2026926A1 (en)
FR (1) FR2049773A5 (en)
GB (1) GB1248988A (en)
NL (1) NL7007892A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4506101A (en) * 1981-12-21 1985-03-19 Ashland Oil, Inc. Process for the hydroformylation of olefins to produce linear aldehydes and alcohols
US4451679A (en) * 1982-10-21 1984-05-29 Texaco Inc. Alcohols and aldehydes prepared from olefins and synthesis gas
US4469895A (en) * 1982-10-21 1984-09-04 Texaco Inc. Process for preparing alcohols from olefins and synthesis gas
US4451680A (en) * 1982-10-21 1984-05-29 Texaco Inc. Alcohols prepared from olefins and synthesis gas
US4511740A (en) * 1983-09-01 1985-04-16 Texaco Inc. Process for hydroformylation of terminal olefins to predominantly linear aldehydes

Also Published As

Publication number Publication date
BE751353A (en) 1970-12-02
FR2049773A5 (en) 1971-03-26
DE2026926A1 (en) 1971-03-11
NL7007892A (en) 1970-12-08

Similar Documents

Publication Publication Date Title
Van Leeuwen et al. Rhodium catalyzed hydroformylation
ES449003A1 (en) Catalytic hydroformylation of olefins
GB1451561A (en) Preparation of zerovalent phosphorus arsenic or antimony substituted rhodium compounds and their use in the selective carbonylation of olefins
Nozaki et al. Enantioselective hydroformylation of olefins catalyzed by rhodium (I) complexes of chiral phosphine–phosphite ligands
GB1197847A (en) Hydroformylation Process
CS109185A2 (en) Method of hydroformylation for aldehydes production
ATE40985T1 (en) HYDROFORMYLATION PROCESS.
ATE28183T1 (en) HYDROFORMYLATION PROCESS.
SE8007140L (en) PROCEDURE FOR PREPARING ALDEHYDES
GB1341857A (en) Optically active bidentate compounds containing phosphorus
ATE16475T1 (en) HYDROFORMYLATION PROCESS.
KR860000237A (en) Method of Making Aldehyde
GB1463947A (en) Hydroformylation of olefins
GB1380111A (en) Asymmetric synthesis of alkyl chrysanthemates
GB1248988A (en) Oxo process
ES453073A1 (en) Perfluoroalkylether substituted aryl phosphines and their synthesis
KR830004193A (en) Hydroformylation of Ethylene with Higher Olefin
GB1198815A (en) Catalytic Hydroformylation of Olefins
ES8104982A1 (en) Process for preparing aldehydes
ES425221A1 (en) Process for producing {60 -6-deoxytetracyclines
ES8102842A1 (en) Hydroformylation catalyst system and processes
NL7502872A (en) PROCESS FOR PREPARING MODIFIED BIS (HYDROCARBYL) VINYL PHOSPHONATE POLYMERS.
GB1254222A (en) Oxo process
GB1320036A (en) Production of alcohols and or aldehydes
GB1368434A (en) Hydroformylation of propylene