GB1247015A - Improvements relating to catalysts - Google Patents
Improvements relating to catalystsInfo
- Publication number
- GB1247015A GB1247015A GB3896668A GB3896668A GB1247015A GB 1247015 A GB1247015 A GB 1247015A GB 3896668 A GB3896668 A GB 3896668A GB 3896668 A GB3896668 A GB 3896668A GB 1247015 A GB1247015 A GB 1247015A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zeolite
- compound
- water
- precipitated
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
- C10G11/04—Oxides
- C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/08—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Catalysts (AREA)
Abstract
1,247,015. Zeolitic hydrocarbon conversion catalysts. TEXACO DEVELOPMENT CORP. 15 Aug., 1968, No. 38966/68. Heading B1E. [Also in Division C5] A zeolitic catalyst containing a water-insoluble multivalent heavy metal compound dispersed in the unit crystallographic cells of the zeolite is prepared by a process which comprises subjecting an alkali metal or ammonium zeolite having a pore size of from 7 to 13 Angstroms to ion exchange by contact with an aqueous solution of a water-soluble salt having a multivalent heavy metal cation thereby to introduce a multivalent heavy metal ion into a cation position in the zeolite, and thereafter subjecting the multivalent heavy metal cation substituted zeolite to ion exchange by contact with an aqueous solution of a water-soluble compound having a metal-containing anion and a cation selected from alkali metal ions and ammonium ions (including quaternary ammonium ions) thereby to form a precipitated water-insoluble compound of the multivalent heavy metal cation and the metal-containing anion, the molecules of the precipitated compound being dispersed within the unit cells of the zeolite. The zeolite may be faujasite, mordenite, clinoptilolite, zeolite X or zeolite Y. The metal of the multivalent heavy metal cation is a metal selected from Groups I, II, VI, VII and VIII, for example copper, silver, zinc, cadmium, chromium, molybdenum, tungsten, manganese, rhenium, iron, cobalt, nickel, rhodium, palladium, osmium, iridium or palladium. The metal-containing anion may comprise titanium, vanaduim, chromium, molybdenum, tungsten or manganese and may be a vanadate, chromate, molybdate, tungstate or sulphur analogue thereof. The precipitated compound may be a simple salt, for example cobalt tungstate, cobalt thiotungstate, nickel tungstate or nickel thiotungstate; a complex salt, for example silver hydroxylamine tungstate; a compound comprising a dehydrated form of the anion, for example copper metatungstate or zinc paratungstate; or a compound comprising a polymeric form of the anion, for example ferric di-, tri-, tetra- or penta-tungstate. The zeolite containing the precipitated compound may be subjected to -further ion exchange by contact with an aqueous solution of a rare earth metal compound thereby to form a rare earth metalsubstituted zeolite containing molecules of the precipitated compound dispersed within the unit cells of the zeolite; reference also is made to such further ion exchange by contact with an aqueous solution of a water-soluble compound of magnesium, calcium, zinc, manganese, cobalt or nickel. Alternatively and when the water-soluble compound has an alkali metal cation, the zeolite containing the precipitated compound may be subjected to further ion exchange by contact either with acid thereby to form hydrogen zeolite containing molecules of the precipitated compound dispersed with the unit cells of the zeolite or with an ammonium compound thereby to form ammonium zeolite which may be heated to form hydrogen zeolite containing molecules of the precipitated compound dispersed within the unit cells of the zeolite; the hydrogen zeolite so formed may be calcined. The multivalent heavy metal substituted zeolite may be contacted, simultaneously with the aqueous solution of the water-soluble compound, with an aqueous solution of a water-soluble hydroxide or a water-soluble salt of a week acid, for example a carbonate or oxalate, having a cation selected from alkali metal ions and ammonium ions thereby to form a further precipitated compound of the multivalent heavy metal cation and hydroxide ion or the anion of the salt of the week acid, the molecules of the further precipitated compound being dispersed, together with the molecules of the precipitated compound, within the unit cells of the zeolite; the further precipitated compound may be converted by suitable treatment to oxide, sulphide or elemental metal form. In the preparation of the catalyst, water washing may be employed after at least one of the treatment steps. Details are given of the preparation of zeolite Y shaving cobalt tungstate dispersed therein and being essentially in the hydrogen form but apparently also containing some residual cobalt in a lattice position. Reference has been directed by the Comptroller to Specification 1,175,294.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3896668A GB1247015A (en) | 1968-08-15 | 1968-08-15 | Improvements relating to catalysts |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3896668A GB1247015A (en) | 1968-08-15 | 1968-08-15 | Improvements relating to catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1247015A true GB1247015A (en) | 1971-09-22 |
Family
ID=10406793
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3896668A Expired GB1247015A (en) | 1968-08-15 | 1968-08-15 | Improvements relating to catalysts |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1247015A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021074145A1 (en) * | 2019-10-14 | 2021-04-22 | Total Se | Isomorphous substitution of metals on synthesized zeolite framework |
-
1968
- 1968-08-15 GB GB3896668A patent/GB1247015A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021074145A1 (en) * | 2019-10-14 | 2021-04-22 | Total Se | Isomorphous substitution of metals on synthesized zeolite framework |
US11485643B1 (en) * | 2019-10-14 | 2022-11-01 | Totalenergies Onetech | Isomorphous substitution of metals on synthesized zeolite framework |
US20220371904A1 (en) * | 2019-10-14 | 2022-11-24 | Totalenergies Onetech | Isomorphous substitution of metals on synthesized zeolite framework |
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