GB1240580A - Hydrogenolysis of esters and lactones - Google Patents

Hydrogenolysis of esters and lactones

Info

Publication number
GB1240580A
GB1240580A GB63055/69A GB6305569A GB1240580A GB 1240580 A GB1240580 A GB 1240580A GB 63055/69 A GB63055/69 A GB 63055/69A GB 6305569 A GB6305569 A GB 6305569A GB 1240580 A GB1240580 A GB 1240580A
Authority
GB
United Kingdom
Prior art keywords
alumina
acid
sulphide
styrene
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB63055/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of GB1240580A publication Critical patent/GB1240580A/en
Priority to US00235090A priority Critical patent/US3849457A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/213—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by splitting of esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins
    • C07C2531/10—Ion-exchange resins sulfonated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Abstract

1,240,580. Hydrogenolysis catalysts. MOBIL OIL CORP. 29 Dec., 1969 [27 Jan., 1969], No. 63055/69. Heading B1E. [Also in Divisions C2 and C5] Hydrogenolysis catalysts comprise (i) a hydrogenation component which is a metal of Groups I B, II B, III B, IV B, V B, VI B, VII B or VIII of the Periodic Table and (ii) a solid acid-acting component. Esters, including lactones, hydrogenolysed to carboxylic acids without reducing the carbonyl group of the ester. The preferred metal is from Groups VIII e.g. palladium, nickel and platinum, and the acid-acting solid may be a cation exchange resin, a crystalline aluminosilicate, alumina, silica-alumina, thoria, vanadia, zirania, titania, zinc oxide, chromia; chromia-alumina, silicamagnesia, molybdena-alumina, halogenated alumina, germania, ceria, molybdena, phosphorus pentoxide, molybdenium sulphide, tungsten sulphide, iron sulphide, nickel sulphide and mixtures thereof. The cation exchange resin may be a phenolic type, a copolymer of styrene and a divinylaromatic, polystyrene, polyacrylic, chlorinated styrene-divinylbenzene with functional groups such as sulphonic, phenolsulphonic, and phosphonic acids, the crystalline alumino silicates may be of the molecular sieve or zeolitic type. The twocomponent catalyst may be a physical mixture or a chemically bonded as molecular dispersion. The acid component may be treated e.g. with carbon tetrachloride, boron fluoride and halogen acids to increase the acid activity. Examples describe the use of nickel and activated clay, or sulphonated styrene-divinylbenzene resin, or zeolites, and palladium with sulphonated polystyrene resin, polyphosphonic acid, sulphonated styrene-divinylbenzene resin, and alumina as catalysts for the production of esters.
GB63055/69A 1969-01-27 1969-12-29 Hydrogenolysis of esters and lactones Expired GB1240580A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US00235090A US3849457A (en) 1969-01-27 1972-03-15 Preparation of carboxylic acids by hydrogenolysis of esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US79434269A 1969-01-27 1969-01-27

Publications (1)

Publication Number Publication Date
GB1240580A true GB1240580A (en) 1971-07-28

Family

ID=25162377

Family Applications (1)

Application Number Title Priority Date Filing Date
GB63055/69A Expired GB1240580A (en) 1969-01-27 1969-12-29 Hydrogenolysis of esters and lactones

Country Status (5)

Country Link
JP (1) JPS5233081B1 (en)
DE (1) DE2003522A1 (en)
FR (1) FR2029502A1 (en)
GB (1) GB1240580A (en)
NL (1) NL7000607A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010142350A1 (en) * 2009-06-12 2010-12-16 Aggregate Energy, Llc. Catalyst comprising a metal and a supplemental component and process for hydrogenating oxygen containing organic products
WO2011015643A1 (en) 2009-08-07 2011-02-10 Shell Internationale Research Maatschappij B.V. Process for hydrogenation
US20110112326A1 (en) * 2009-08-07 2011-05-12 Jean-Paul Lange Process for hydrogenation
US8003818B2 (en) 2004-12-23 2011-08-23 Shell Oil Company Process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group
US8580978B2 (en) 2009-08-07 2013-11-12 Shell Oil Company Process for preparing a hydroxyacid or hydroxyester
CN103717565A (en) * 2011-06-21 2014-04-09 赢创德固赛有限公司 Method for the production of 2-ethylheptanoic acid

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53132521A (en) * 1977-04-26 1978-11-18 Soda Aromatic Process for preparing omegaahydroxy fatty acid
DE4141762A1 (en) * 1991-12-18 1993-06-24 Basf Ag METHOD FOR THE CONTINUOUS PRODUCTION OF CYCLOHEXES FROM CYCLOHEXYL ESTERS
US5693601A (en) * 1993-07-23 1997-12-02 The Procter & Gamble Company Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants
WO2017002849A1 (en) 2015-06-30 2017-01-05 武田薬品工業株式会社 Method for producing pyrrole compound

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8003818B2 (en) 2004-12-23 2011-08-23 Shell Oil Company Process for the hydrogenation of a lactone or of a carboxylic acid or an ester having a gamma-carbonyl group
WO2010142350A1 (en) * 2009-06-12 2010-12-16 Aggregate Energy, Llc. Catalyst comprising a metal and a supplemental component and process for hydrogenating oxygen containing organic products
US8389781B2 (en) 2009-06-12 2013-03-05 Aggregate Energy, Llc Catalyst with supplement component for hydroprocessing of bio-feedstock
WO2011015643A1 (en) 2009-08-07 2011-02-10 Shell Internationale Research Maatschappij B.V. Process for hydrogenation
US20110112326A1 (en) * 2009-08-07 2011-05-12 Jean-Paul Lange Process for hydrogenation
US8580978B2 (en) 2009-08-07 2013-11-12 Shell Oil Company Process for preparing a hydroxyacid or hydroxyester
CN103717565A (en) * 2011-06-21 2014-04-09 赢创德固赛有限公司 Method for the production of 2-ethylheptanoic acid

Also Published As

Publication number Publication date
NL7000607A (en) 1970-07-29
JPS5233081B1 (en) 1977-08-26
DE2003522A1 (en) 1970-07-30
FR2029502A1 (en) 1970-10-23

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