GB1233106A - - Google Patents
Info
- Publication number
- GB1233106A GB1233106A GB1233106DA GB1233106A GB 1233106 A GB1233106 A GB 1233106A GB 1233106D A GB1233106D A GB 1233106DA GB 1233106 A GB1233106 A GB 1233106A
- Authority
- GB
- United Kingdom
- Prior art keywords
- propylene
- copolymer
- working
- zone
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
Abstract
1,233,106. Preparation and mechanical working of propylene-ethylene block copolymers. PHILLIPS PETROLEUM CO. 27 Sept., 1968 [29 Sept., 1967], No. 46125/68. Heading C3P. A continuous process for the production of a block copolymer comprises (a) polymerizing propylene in bulk in the presence of a catalyst in a first zone, (b) feeding the partially polymerized mixture to a second zone, (c) adding ethylene to the mixture in the second zone, and optionally further propylene, and continuing the polymerization, (d) recovering the solid copolymer, and (e) mechanically working the copolymer at a work input of at least 0À25 horse-power per hour per pound of copolymer. The product is essentially propylene-b-[ethylene-copropylene]. The polymerization is suitably carried out using a Ziegler catalyst and hydrogen. Mechanical working may be achieved by conventional Banbury mixers or extruders. A polyethylene may be included prior to or during the working. The polymer may be recovered by treatment with a diketone, e.g. acetylacetone, -propylene oxide mixture, washing, and drying, prior to mechanical working. In the examples the catalyst employed is (C 2 H 5 ) 2 AlCl-TiCl 3 obtained by reducing TiCl 4 with Al. A flow diagram of a suitable continuous operation is included.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US67162667A | 1967-09-29 | 1967-09-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1233106A true GB1233106A (en) | 1971-05-26 |
Family
ID=24695271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1233106D Expired GB1233106A (en) | 1967-09-29 | 1968-09-27 |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE721579A (en) |
| DK (1) | DK118625B (en) |
| FR (1) | FR1604260A (en) |
| GB (1) | GB1233106A (en) |
| NL (1) | NL6813875A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7834108B2 (en) | 2007-12-11 | 2010-11-16 | Sumitomo Chemical Company, Limited | Powder transfer device and polyolefin production process |
| US7993591B2 (en) | 2007-12-11 | 2011-08-09 | Sumitomo Chemical Company, Limited | Spouted bed device and polyolefin production process using the same |
| US7993593B2 (en) | 2007-12-11 | 2011-08-09 | Sumitomo Chemical Company, Limited | Olefin polymerization reactor, polyolefin production system, and polyolefin production process |
| US8030420B2 (en) | 2007-12-11 | 2011-10-04 | Sumitomo Chemical Company, Limited | Olefin polymerization reaction unit and polyolefin production process |
| US8084555B2 (en) | 2007-12-11 | 2011-12-27 | Sumitomo Chemical Company, Limited | Spouted bed device, polyolefin production system with spouted bed device, and polyolefin production process |
| US8163246B2 (en) | 2009-06-08 | 2012-04-24 | Sumitomo Chemical Company, Limited | Spouted-fluidized bed-type olefin polymerization reactor |
| US10537871B2 (en) | 2016-08-03 | 2020-01-21 | Sumitomo Chemical Company, Limited | System for producing polyolefin, method of producing polyolefin, and method of producing heterophasic propylene polymer material |
-
1968
- 1968-09-27 NL NL6813875A patent/NL6813875A/xx unknown
- 1968-09-27 DK DK470068A patent/DK118625B/en unknown
- 1968-09-27 GB GB1233106D patent/GB1233106A/en not_active Expired
- 1968-09-27 FR FR1604260D patent/FR1604260A/fr not_active Expired
- 1968-09-27 BE BE721579D patent/BE721579A/xx unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7834108B2 (en) | 2007-12-11 | 2010-11-16 | Sumitomo Chemical Company, Limited | Powder transfer device and polyolefin production process |
| US7993591B2 (en) | 2007-12-11 | 2011-08-09 | Sumitomo Chemical Company, Limited | Spouted bed device and polyolefin production process using the same |
| US7993593B2 (en) | 2007-12-11 | 2011-08-09 | Sumitomo Chemical Company, Limited | Olefin polymerization reactor, polyolefin production system, and polyolefin production process |
| US8030420B2 (en) | 2007-12-11 | 2011-10-04 | Sumitomo Chemical Company, Limited | Olefin polymerization reaction unit and polyolefin production process |
| US8084555B2 (en) | 2007-12-11 | 2011-12-27 | Sumitomo Chemical Company, Limited | Spouted bed device, polyolefin production system with spouted bed device, and polyolefin production process |
| US8313704B2 (en) | 2007-12-11 | 2012-11-20 | Sumitomo Chemical Company, Limited | Spouted bed device, polyolefin production system with spouted bed device, and polyolefin production process |
| US8163246B2 (en) | 2009-06-08 | 2012-04-24 | Sumitomo Chemical Company, Limited | Spouted-fluidized bed-type olefin polymerization reactor |
| US10537871B2 (en) | 2016-08-03 | 2020-01-21 | Sumitomo Chemical Company, Limited | System for producing polyolefin, method of producing polyolefin, and method of producing heterophasic propylene polymer material |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1604260A (en) | 1971-10-11 |
| BE721579A (en) | 1969-03-27 |
| DK118625B (en) | 1970-09-14 |
| NL6813875A (en) | 1969-04-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |