GB1227562A - - Google Patents

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Publication number
GB1227562A
GB1227562A GB1227562DA GB1227562A GB 1227562 A GB1227562 A GB 1227562A GB 1227562D A GB1227562D A GB 1227562DA GB 1227562 A GB1227562 A GB 1227562A
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GB
United Kingdom
Prior art keywords
carbon atoms
metal
saturated
optionally
sio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
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Publication of GB1227562A publication Critical patent/GB1227562A/en
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,227,562. Olefine reaction catalysts. PHILLIPS PETROLEUM CO. 2 May, 1968 [3 May, 1967; 8 Jan., 1968; 28 March, 1968], No. 20827/68. Heading B1E. [Also in Divisions C3 and C5] A catalyst composition for the olefine reaction is formed by admixture of (a) a complex of [(L) a (Y) b M c Z d ] x wherein M is Fe, Ru, OS, CO, Rh or Ir; Z is halogen, CN, SCN OCN or S n Cl 3 or an organic acid radical of up to 30 carbon atoms; (Y) is NO or (#-CHR<SP>4</SP>- CR<SP>4</SP>-CH 2 -); (L) is R 3 )Q, R 2 Q-QR 2 , R 2 NR', CO, R 2 N-R<SP>2</SP>-NR 2 , optionally R<SP>5</SP> substituted pyridine or 2, 2'bipyridines, optionally R substituted #-cyclopentadienyls, R<SP>3</SP>S, R-S-R, R<SP>5</SP>(CN) y , R<SP>5</SP>(COO-) y , 1-5-cyclooctadiene, dicyclopentadiene or norbornadiene a is 0 at 1-6, b is 1 or 2, y is 1 or 2, c is 1, 2 or 3, d is 1 - 6, x is indicative of polymeric state of complex; the sum of a+b+c+d is not greater than the number required for a metal to achieve the closed shell electronic configuration of the next highest At.No inert gas; when M is Ru or Os b is 0, 1 or 2; when M is Fe (Y) is NO only and b is 2; Q is P, As or Sb; R is alkoxy or halo optionally substituted aromatic or saturated aliphatic of up to 20 carbon atoms; R<SP>1</SP> is H or R; R<SP>2</SP> is divalent R; R<SP>3</SP> is divalent saturated or ethylenically unsaturated aliphatic from 4 to 10 carbon atoms; R<SP>4</SP> is H or Me; R<SP>5</SP> is an aromatic, saturated or ethylenically unsaturated aliphatic of up to 30 carbon atoms; and (b) an Al compound selected from (i) one or more ReAlX f (ii) AlX 3 and (iii) a mixture of (i) or (ii) with R<SP>1</SP> g M<SP>1</SP>X h , where R<SP>1</SP> is H or R, M<SP>1</SP> is a metal of group IA, IIA, IIB or IIIA, e is 1-3, A is 0-2 and e+f is 3, g is 1-3, h is 0-2 and g+h equals the valency of M<SP>1</SP>. Many examples of metal starting compounds, complexing agents, complexes and Al compounds given. The catalysts may be used in the vapour phase supported on a carrier such as Al 2 O 3 , SiO 2 , SiO 2 -Al 2 O 3 , TiO 2 , B 2 O 3 zeolites, ion exchange resins or polymers.
GB1227562D 1967-05-03 1968-05-02 Expired GB1227562A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US63568867A 1967-05-03 1967-05-03
US69610968A 1968-01-08 1968-01-08
US71702568A 1968-03-28 1968-03-28

Publications (1)

Publication Number Publication Date
GB1227562A true GB1227562A (en) 1971-04-07

Family

ID=27417570

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1227562D Expired GB1227562A (en) 1967-05-03 1968-05-02

Country Status (5)

Country Link
BE (1) BE714624A (en)
DE (1) DE1767373B2 (en)
FR (1) FR1575779A (en)
GB (1) GB1227562A (en)
NL (2) NL6806210A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000153B (en) * 1977-06-16 1982-11-24 Brintzinger H Cyclopentadienyl-metal compounds and processes for their preparation
US5324799A (en) * 1990-03-06 1994-06-28 Akihiro Yano Polyethylene and process of production thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2564748B1 (en) * 1984-05-24 1986-09-26 Charbonnages Ste Chimique CARBON MONOXIDE HYDROCONDENSATION CATALYST, PROCESS FOR THE PREPARATION THEREOF, AND APPLICATION THEREOF TO MANUFACTURE HYDROCARBONS AND OXYGENIC ALIPHATIC COMPOUNDS
DE3583554D1 (en) * 1984-05-04 1991-08-29 Atochem HYDROCONVERSION PROCESS OF CARBON MONOXIDE.
KR910018412A (en) * 1990-04-16 1991-11-30 야마구찌 도시아끼 Method for producing polyolefin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000153B (en) * 1977-06-16 1982-11-24 Brintzinger H Cyclopentadienyl-metal compounds and processes for their preparation
US5324799A (en) * 1990-03-06 1994-06-28 Akihiro Yano Polyethylene and process of production thereof

Also Published As

Publication number Publication date
DE1767373A1 (en) 1972-08-31
NL135027C (en)
DE1767373B2 (en) 1974-06-20
DE1767373C3 (en) 1975-03-06
NL6806210A (en) 1968-11-04
BE714624A (en) 1968-11-04
FR1575779A (en) 1969-07-25

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PCNP Patent ceased through non-payment of renewal fee