GB1227562A - - Google Patents

Info

Publication number
GB1227562A
GB1227562A GB1227562DA GB1227562A GB 1227562 A GB1227562 A GB 1227562A GB 1227562D A GB1227562D A GB 1227562DA GB 1227562 A GB1227562 A GB 1227562A
Authority
GB
United Kingdom
Prior art keywords
carbon atoms
metal
saturated
optionally
sio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of GB1227562A publication Critical patent/GB1227562A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2291Olefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/827Iridium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/842Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03Multinuclear procatalyst, i.e. containing two or more metals, being different or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,227,562. Olefine reaction catalysts. PHILLIPS PETROLEUM CO. 2 May, 1968 [3 May, 1967; 8 Jan., 1968; 28 March, 1968], No. 20827/68. Heading B1E. [Also in Divisions C3 and C5] A catalyst composition for the olefine reaction is formed by admixture of (a) a complex of [(L) a (Y) b M c Z d ] x wherein M is Fe, Ru, OS, CO, Rh or Ir; Z is halogen, CN, SCN OCN or S n Cl 3 or an organic acid radical of up to 30 carbon atoms; (Y) is NO or (#-CHR<SP>4</SP>- CR<SP>4</SP>-CH 2 -); (L) is R 3 )Q, R 2 Q-QR 2 , R 2 NR', CO, R 2 N-R<SP>2</SP>-NR 2 , optionally R<SP>5</SP> substituted pyridine or 2, 2'bipyridines, optionally R substituted #-cyclopentadienyls, R<SP>3</SP>S, R-S-R, R<SP>5</SP>(CN) y , R<SP>5</SP>(COO-) y , 1-5-cyclooctadiene, dicyclopentadiene or norbornadiene a is 0 at 1-6, b is 1 or 2, y is 1 or 2, c is 1, 2 or 3, d is 1 - 6, x is indicative of polymeric state of complex; the sum of a+b+c+d is not greater than the number required for a metal to achieve the closed shell electronic configuration of the next highest At.No inert gas; when M is Ru or Os b is 0, 1 or 2; when M is Fe (Y) is NO only and b is 2; Q is P, As or Sb; R is alkoxy or halo optionally substituted aromatic or saturated aliphatic of up to 20 carbon atoms; R<SP>1</SP> is H or R; R<SP>2</SP> is divalent R; R<SP>3</SP> is divalent saturated or ethylenically unsaturated aliphatic from 4 to 10 carbon atoms; R<SP>4</SP> is H or Me; R<SP>5</SP> is an aromatic, saturated or ethylenically unsaturated aliphatic of up to 30 carbon atoms; and (b) an Al compound selected from (i) one or more ReAlX f (ii) AlX 3 and (iii) a mixture of (i) or (ii) with R<SP>1</SP> g M<SP>1</SP>X h , where R<SP>1</SP> is H or R, M<SP>1</SP> is a metal of group IA, IIA, IIB or IIIA, e is 1-3, A is 0-2 and e+f is 3, g is 1-3, h is 0-2 and g+h equals the valency of M<SP>1</SP>. Many examples of metal starting compounds, complexing agents, complexes and Al compounds given. The catalysts may be used in the vapour phase supported on a carrier such as Al 2 O 3 , SiO 2 , SiO 2 -Al 2 O 3 , TiO 2 , B 2 O 3 zeolites, ion exchange resins or polymers.
GB1227562D 1967-05-03 1968-05-02 Expired GB1227562A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US63568867A 1967-05-03 1967-05-03
US69610968A 1968-01-08 1968-01-08
US71702568A 1968-03-28 1968-03-28

Publications (1)

Publication Number Publication Date
GB1227562A true GB1227562A (en) 1971-04-07

Family

ID=27417570

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1227562D Expired GB1227562A (en) 1967-05-03 1968-05-02

Country Status (5)

Country Link
BE (1) BE714624A (en)
DE (1) DE1767373B2 (en)
FR (1) FR1575779A (en)
GB (1) GB1227562A (en)
NL (2) NL6806210A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000153B (en) * 1977-06-16 1982-11-24 Brintzinger H Cyclopentadienyl-metal compounds and processes for their preparation
US5324799A (en) * 1990-03-06 1994-06-28 Akihiro Yano Polyethylene and process of production thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2564748B1 (en) * 1984-05-24 1986-09-26 Charbonnages Ste Chimique CARBON MONOXIDE HYDROCONDENSATION CATALYST, PROCESS FOR THE PREPARATION THEREOF, AND APPLICATION THEREOF TO MANUFACTURE HYDROCARBONS AND OXYGENIC ALIPHATIC COMPOUNDS
DE3583554D1 (en) * 1984-05-04 1991-08-29 Atochem HYDROCONVERSION PROCESS OF CARBON MONOXIDE.
KR910018412A (en) * 1990-04-16 1991-11-30 야마구찌 도시아끼 Method for producing polyolefin

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000153B (en) * 1977-06-16 1982-11-24 Brintzinger H Cyclopentadienyl-metal compounds and processes for their preparation
US5324799A (en) * 1990-03-06 1994-06-28 Akihiro Yano Polyethylene and process of production thereof

Also Published As

Publication number Publication date
DE1767373A1 (en) 1972-08-31
NL135027C (en)
DE1767373B2 (en) 1974-06-20
DE1767373C3 (en) 1975-03-06
NL6806210A (en) 1968-11-04
BE714624A (en) 1968-11-04
FR1575779A (en) 1969-07-25

Similar Documents

Publication Publication Date Title
GB1227382A (en)
Stoufer et al. UNUSUAL MAGNETIC PROPERTIES OF SOME SIX-COÖRDINATE COBALT (II) COMPLEXES1—ELECTRONIC ISOMERS
GB1088558A (en) Novel film-forming solution
ES305897A1 (en) A procedure for preparing conjugated diamond polymers. (Machine-translation by Google Translate, not legally binding)
Eisch et al. The Novel Synthesis of Aluminoles by the Metalative Cyclization of Unsaturated Organoaluminum Compounds
GB1228142A (en)
Espenson et al. Oxidation of Tantalum Cluster Ions1
GB1227562A (en)
GB1227563A (en)
GB1353540A (en) Organo-metallic compounds
Manuel et al. Chemistry of the Metal Carbonyls. VI. The Nature of Cycloöctatriene-Iron Carbonyl Complexes1, 2
Andrews et al. Thioxanthate complexes. Carbon disulfide eliminations to form bridged mercaptide dimers of nickel (II) and palladium (II)
Schnoes et al. Interconversion of the Aspidospermine Skeleton to the Refractine Type
ES354909A1 (en) Catalyst for hydrocarbon conversion
Rose et al. Reaction of Free Carbon Atoms with Cyclopentadiene
GB1232831A (en)
ES324563A1 (en) A procedure for the preparation of 4-methylpenten-1. (Machine-translation by Google Translate, not legally binding)
Adams et al. Cluster condensations. The dimerization of [Os3 (CO) 9 (μ3-CO)(μ) 3-S)]
Mednikov et al. Synthesis of large palladium clusters. The preparation of Pd 38 (CO) 28 (PR 3) 12 (R= Et, Bu n) and Pd 34 (CO) 24 (PEt 3) 12
GB997151A (en) Polymerization process
GB1109855A (en) Dihydrocarbon tin compounds
Hoigné et al. ON A POSSIBLE TRACK REACTION IN THE RADIOLYSIS OF TOLUENE1
GB1184831A (en) Improvements in or relating to Catalyst Compositions suitable for the Polymerization of Ethylenically Unsaturated Monomers
JPS5625122A (en) Preparation of ethanol
GB1027959A (en) Process for the polymerization of diolefins

Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee