GB1222006A - A method of preparing mercaptan organotin compounds - Google Patents
A method of preparing mercaptan organotin compoundsInfo
- Publication number
- GB1222006A GB1222006A GB3208968A GB3208968A GB1222006A GB 1222006 A GB1222006 A GB 1222006A GB 3208968 A GB3208968 A GB 3208968A GB 3208968 A GB3208968 A GB 3208968A GB 1222006 A GB1222006 A GB 1222006A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- radical
- tin
- compounds
- organotin compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 title abstract 3
- -1 alkyl radical Chemical group 0.000 abstract 5
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- SVSRQMUJHHQAAX-UHFFFAOYSA-N dibenzyltin Chemical compound C=1C=CC=CC=1C[Sn]CC1=CC=CC=C1 SVSRQMUJHHQAAX-UHFFFAOYSA-N 0.000 abstract 2
- 239000002609 medium Substances 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 150000005840 aryl radicals Chemical class 0.000 abstract 1
- 125000002618 bicyclic heterocycle group Chemical class 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- OVARTBFNCCXQKS-UHFFFAOYSA-N propan-2-one;hydrate Chemical compound O.CC(C)=O OVARTBFNCCXQKS-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/226—Compounds with one or more Sn-S linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,222,006. Mercaptan organotin compounds. INSTYTUT PRZEMYSLU ORGANICZNEGO. 5 July, 1968 [19 July, 1967], No. 32089/68. Heading C2J. Mercaptan organotin compounds of general formulµ (where n = 1, 2 or 3 except in Formula 7 where n = 2 or 3 only; R is an alkyl radical containing 3-20 carbon atoms, an aryl radical or an arylalkyl radical; R<SP>1</SP> is H or R; A is an alkylene or arylene radical; Y is H or an acid residue having 1-20 carbon atoms; R<SP>2</SP> and R<SP>3</SP> are alkyls or alkenyls or R<SP>2</SP> may be H; R<SP>4</SP> is an alkylene, and Z is a residue of bicyclic heterocyclic compounds) are prepared by reacting water insoluble alkyl-tin, arylalkyl-tin or aryl-tin halides with a mercaptan compound in an aqueous medium, a water-alcohol medium or a water-acetone medium. The reaction is preferably effected in the presence of dilute aqueous ammonia, alkali metal, or alkaline metal earth hydroxides or carbonates at 50‹ to 60‹ C. Among examples of compounds prepared by the process are dibenzyltin - bis - isooctylthioglycollate, dibenzyltin - bis - laurylmercaptan, di - tribenzyltin ethylenebisdithiocarbamate, dibutyltin - bis - n - butylthioglycollate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL121792A PL62466B1 (en) | 1967-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1222006A true GB1222006A (en) | 1971-02-10 |
Family
ID=19949703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3208968A Expired GB1222006A (en) | 1967-07-19 | 1968-07-05 | A method of preparing mercaptan organotin compounds |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS5312497B1 (en) |
| AT (1) | AT294850B (en) |
| BE (1) | BE718295A (en) |
| CS (1) | CS153465B2 (en) |
| DE (1) | DE1768838A1 (en) |
| FR (1) | FR1602669A (en) |
| GB (1) | GB1222006A (en) |
| NL (1) | NL6810266A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114605465A (en) * | 2022-04-11 | 2022-06-10 | 云南锡业锡化工材料有限责任公司 | Method for synthesizing dibutyltin dilaurate by solvent method |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3945981A (en) * | 1974-11-08 | 1976-03-23 | Uniroyal, Inc. | Light stable polyurethane elastomer prepared from aliphatic isocyanate using thio tin organic compound containing sulfur attached to tin as heat activated catalyst |
| US4788083A (en) * | 1986-03-27 | 1988-11-29 | Ashland Oil, Inc. | Tin or bismuth complex catalysts and trigger cure of coatings therewith |
-
1968
- 1968-07-05 GB GB3208968A patent/GB1222006A/en not_active Expired
- 1968-07-05 DE DE19681768838 patent/DE1768838A1/en not_active Withdrawn
- 1968-07-15 FR FR1602669D patent/FR1602669A/fr not_active Expired
- 1968-07-18 CS CS526668A patent/CS153465B2/cs unknown
- 1968-07-19 AT AT698768A patent/AT294850B/en not_active IP Right Cessation
- 1968-07-19 NL NL6810266A patent/NL6810266A/xx unknown
- 1968-07-19 BE BE718295D patent/BE718295A/xx unknown
- 1968-07-19 JP JP5060068A patent/JPS5312497B1/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114605465A (en) * | 2022-04-11 | 2022-06-10 | 云南锡业锡化工材料有限责任公司 | Method for synthesizing dibutyltin dilaurate by solvent method |
Also Published As
| Publication number | Publication date |
|---|---|
| CS153465B2 (en) | 1974-02-25 |
| FR1602669A (en) | 1971-01-11 |
| DE1768838A1 (en) | 1972-04-13 |
| BE718295A (en) | 1968-12-31 |
| AT294850B (en) | 1971-12-10 |
| JPS5312497B1 (en) | 1978-05-01 |
| NL6810266A (en) | 1969-01-21 |
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