GB1202058A - Manufacture of polyethylene terephthalate - Google Patents

Manufacture of polyethylene terephthalate

Info

Publication number
GB1202058A
GB1202058A GB3857367A GB3857367A GB1202058A GB 1202058 A GB1202058 A GB 1202058A GB 3857367 A GB3857367 A GB 3857367A GB 3857367 A GB3857367 A GB 3857367A GB 1202058 A GB1202058 A GB 1202058A
Authority
GB
United Kingdom
Prior art keywords
polyethylene terephthalate
prepolymer
aug
solid phase
trihydric alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3857367A
Inventor
Kenneth Thomas Barkey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1202058A publication Critical patent/GB1202058A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/80Solid-state polycondensation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/20Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/85Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof

Abstract

1,202,058. Polyethylene terephthalate. EASTMAN KODAK CO. 22 Aug., 1967 [22 Aug., 1966], No. 38573/67. Heading C3R. Polyethylene terephthalate is made by reacting ethylene glycol and a dialkyl terephthalate in the presence of an ester interchange catalyst and a polycondensation catalyst until a prepolymer having an intrinsic viscosity of 0À1 to 0À45 is obtained, solidifying and comminuting the prepolymer and carrying out solid phase polymerization, 0À05 to 2% by weight of an epoxy compound containing two or more epoxy groups or a trihydric alcohol, neither having a boiling point greater than 200‹ C., being added to the mixture at any stage before the solid phase polycondensation. The additive is preferably epoxidized soybean oil, the reaction products of epichlorohydrin with a bisphenol, a diol or a triol (e.g. glycerol) or a trihydric alcohol. The catalysts may be organic or inorganic compounds of titanium, zinc, antimony and manganese.
GB3857367A 1966-08-22 1967-08-22 Manufacture of polyethylene terephthalate Expired GB1202058A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US57388866A 1966-08-22 1966-08-22

Publications (1)

Publication Number Publication Date
GB1202058A true GB1202058A (en) 1970-08-12

Family

ID=24293792

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3857367A Expired GB1202058A (en) 1966-08-22 1967-08-22 Manufacture of polyethylene terephthalate

Country Status (2)

Country Link
BE (1) BE702600A (en)
GB (1) GB1202058A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2398073A (en) * 2003-02-03 2004-08-11 Johnson Matthey Plc Polyester manufacturing process
CN112409583A (en) * 2020-11-11 2021-02-26 大连理工大学 Preparation method of animal/vegetable oil bio-based polymer based on mechanochemical method
CN115151594A (en) * 2020-02-26 2022-10-04 东洋纺株式会社 Polyester resin with little foreign matter and coating composition or adhesive composition using same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2398073A (en) * 2003-02-03 2004-08-11 Johnson Matthey Plc Polyester manufacturing process
CN115151594A (en) * 2020-02-26 2022-10-04 东洋纺株式会社 Polyester resin with little foreign matter and coating composition or adhesive composition using same
CN112409583A (en) * 2020-11-11 2021-02-26 大连理工大学 Preparation method of animal/vegetable oil bio-based polymer based on mechanochemical method

Also Published As

Publication number Publication date
BE702600A (en) 1968-01-15

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees