GB1194600A - Improvements in or relating to Metal Bodies and their Manufacture - Google Patents

Improvements in or relating to Metal Bodies and their Manufacture

Info

Publication number
GB1194600A
GB1194600A GB5018167A GB5018167A GB1194600A GB 1194600 A GB1194600 A GB 1194600A GB 5018167 A GB5018167 A GB 5018167A GB 5018167 A GB5018167 A GB 5018167A GB 1194600 A GB1194600 A GB 1194600A
Authority
GB
United Kingdom
Prior art keywords
total
air
heat treatment
moist hydrogen
oxide layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5018167A
Inventor
Dain Stedman Evans
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co PLC
Original Assignee
General Electric Co PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co PLC filed Critical General Electric Co PLC
Priority to GB5018167A priority Critical patent/GB1194600A/en
Publication of GB1194600A publication Critical patent/GB1194600A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C27/00Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/04Alloys based on tungsten or molybdenum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/045Alloys based on refractory metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18After-treatment
    • C23C4/185Separation of the coating from the substrate
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/02Pretreatment of the material to be coated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

1,194,600. Sintered tungsten or molybdenum base alloys. GENERAL ELECTRIC & ENGLISH ELECTRIC COMPANIES Ltd. Oct.25, 1968 [Nov.3, 1967], No.50181/67. Headings C7A, C7D and C7U. A metal body consisting mainly of W and/or Mo, is composed of, or has at least a surface layer composed of, an alloy comprising:- at least # Al, Be, Ce, Cr, Hf, # 5-20% in total one of # Mg, Th, Ti, U, Zr, # 5-20% in total, at least # Co, Ir, Ni, Os, # 0À01-10% in total, one of #Pd, Pt, Rh, Ru # and at # As, Bi, Ge, P, S, # least # 0À001-10% in total, of # Sb, Se, Si, Sn, Te the balance being W and/or Mo in any relative proportions. The relative proportions of elements from the three groups are so chosen that the body can be made resistant to high temperature oxidation by heating in air or moist hydrogen to form an adherent protective oxide layer. A preferred alloy comprises Cr 5-20%, Pd, 0À5-10% and As 0À01-1%, the balance being W and/or Mo. If the body is to be of one basic composition it may be made by arc melting and casting or preferably by mixing the constituents, some of which may be present as master alloys, in powder form, preferably with a particle size smaller than 5 microns, isostatically pressing (e.g. in glycerol) and then sintering. If the sintering temperature is high enough to form the required oxide layer, it may be performed in air or moist hydrogen. If this is not so the sintered compact must be heat treated in air or moist hydrogen as is the case for the cast bodies. For a body which only has the surface layer of the appropriate composition, a body of a W and/or Mo based alloy, optionally containing Re, Ta, ThO 2 and potassium silicate, is coated with the elements in which it is deficient (e.g. by vapour deposition or electro-plating) and is subjected to a diffusing heat treatment prior to the oxidizing heat treatment in air or moist hydrogen. Some compositions do not require a separate heat treatment as the oxide layer is formed when the article is used.
GB5018167A 1967-11-03 1967-11-03 Improvements in or relating to Metal Bodies and their Manufacture Expired GB1194600A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB5018167A GB1194600A (en) 1967-11-03 1967-11-03 Improvements in or relating to Metal Bodies and their Manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5018167A GB1194600A (en) 1967-11-03 1967-11-03 Improvements in or relating to Metal Bodies and their Manufacture

Publications (1)

Publication Number Publication Date
GB1194600A true GB1194600A (en) 1970-06-10

Family

ID=10454975

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5018167A Expired GB1194600A (en) 1967-11-03 1967-11-03 Improvements in or relating to Metal Bodies and their Manufacture

Country Status (1)

Country Link
GB (1) GB1194600A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0140889A1 (en) * 1983-04-22 1985-05-15 Sri International Process for applying thermal barrier coatings to metals and resulting product
EP0753592A1 (en) * 1995-01-20 1997-01-15 Toho Kinzoku Co., Ltd. Copper-tungsten alloys and process for producing the same
CN109112379A (en) * 2018-09-03 2019-01-01 合肥工业大学 More first light composite materials of a kind of resistance to high temperature oxidation W-Si-Al-Ti-Zr-Y and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0140889A1 (en) * 1983-04-22 1985-05-15 Sri International Process for applying thermal barrier coatings to metals and resulting product
EP0140889A4 (en) * 1983-04-22 1986-02-13 Stanford Res Inst Int Process for applying thermal barrier coatings to metals and resulting product.
EP0753592A1 (en) * 1995-01-20 1997-01-15 Toho Kinzoku Co., Ltd. Copper-tungsten alloys and process for producing the same
EP0753592A4 (en) * 1995-01-20 1997-04-23 Toho Kinzoku Kk Copper-tungsten alloys and process for producing the same
US5889220A (en) * 1995-01-20 1999-03-30 Toho Kinzoku Co, Ltd Copper-tungsten alloys and their manufacturing methods
CN109112379A (en) * 2018-09-03 2019-01-01 合肥工业大学 More first light composite materials of a kind of resistance to high temperature oxidation W-Si-Al-Ti-Zr-Y and preparation method thereof

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee