GB1184020A - Salts of Polyvalent Metals and Alkylsalicylic Acids - Google Patents

Salts of Polyvalent Metals and Alkylsalicylic Acids

Info

Publication number
GB1184020A
GB1184020A GB60355/68A GB6035568A GB1184020A GB 1184020 A GB1184020 A GB 1184020A GB 60355/68 A GB60355/68 A GB 60355/68A GB 6035568 A GB6035568 A GB 6035568A GB 1184020 A GB1184020 A GB 1184020A
Authority
GB
United Kingdom
Prior art keywords
salts
alkyl
acids
polyvalent metals
alkyl group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB60355/68A
Inventor
Aart Strang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB60355/68A priority Critical patent/GB1184020A/en
Priority to US885982A priority patent/US3704315A/en
Priority to BE743261D priority patent/BE743261A/xx
Priority to SE17379/69A priority patent/SE359537B/xx
Priority to FR6943706A priority patent/FR2026542A1/fr
Priority to NLAANVRAGE6918900,A priority patent/NL169730C/en
Priority to DE1963320A priority patent/DE1963320C3/en
Publication of GB1184020A publication Critical patent/GB1184020A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
    • C07C37/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon unsaturated bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/01—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups
    • C07C65/03—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring
    • C07C65/05—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring o-Hydroxy carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/189—Carboxylic acids; metal salts thereof having at least one carboxyl group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/146—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
    • C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Lubricants (AREA)

Abstract

1,184,020. Alkyl salicylic acid salts. SHELL INTERNATIONALE RESEARCH MAAT. SCHAPPIJ N.V. 19 Dec., 1968, No. 60355/68. Heading C2C. [Also in Division C5] The invention comprises salts of polyvalent metals and alkylsalicylic acids, which contain at least one alkyl group with more than 12 carbon atoms and of which more than 60% m. consists of acids containing an alkyl group in paraposition relative to the hydroxyl group, while at least part of the latter alkyl groups is attached with a quaternary carbon atom to the benzene nucleus. Calcium salts are exemplified. The compounds are prepared by alkylation of phenol, which may be carried out in two stages with different alkylating agents, conversion of the alkylphenols to alkyl-salicylic acids followed by salt formation.
GB60355/68A 1968-12-19 1968-12-19 Salts of Polyvalent Metals and Alkylsalicylic Acids Expired GB1184020A (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
GB60355/68A GB1184020A (en) 1968-12-19 1968-12-19 Salts of Polyvalent Metals and Alkylsalicylic Acids
US885982A US3704315A (en) 1968-12-19 1969-12-17 Dialkylsalicylic acids and alkaline earth metal salts thereof
BE743261D BE743261A (en) 1968-12-19 1969-12-17
SE17379/69A SE359537B (en) 1968-12-19 1969-12-17
FR6943706A FR2026542A1 (en) 1968-12-19 1969-12-17
NLAANVRAGE6918900,A NL169730C (en) 1968-12-19 1969-12-17 PROCESS FOR PREPARING SALTS OF MULTI-VALUED METALS AND ALKYL SALICYLIC ACIDS AND OF LUBRICATING OILS CONTAINING THEM.
DE1963320A DE1963320C3 (en) 1968-12-19 1969-12-17 Mixtures of alkyl-substituted salicylic acids in the form of their salts with alkaline earth metals, processes for their production and their use as additives in lubricants and in fuels

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB60355/68A GB1184020A (en) 1968-12-19 1968-12-19 Salts of Polyvalent Metals and Alkylsalicylic Acids

Publications (1)

Publication Number Publication Date
GB1184020A true GB1184020A (en) 1970-03-11

Family

ID=10485478

Family Applications (1)

Application Number Title Priority Date Filing Date
GB60355/68A Expired GB1184020A (en) 1968-12-19 1968-12-19 Salts of Polyvalent Metals and Alkylsalicylic Acids

Country Status (7)

Country Link
US (1) US3704315A (en)
BE (1) BE743261A (en)
DE (1) DE1963320C3 (en)
FR (1) FR2026542A1 (en)
GB (1) GB1184020A (en)
NL (1) NL169730C (en)
SE (1) SE359537B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0192323A1 (en) * 1985-01-18 1986-08-27 Nippon Oil Co. Ltd. Gasoline compositions for automotive vehicles
EP0283294A1 (en) * 1987-03-19 1988-09-21 Exxon Chemical Patents Inc. Improved fuel oil compositions
EP0675191A2 (en) * 1994-03-30 1995-10-04 Cosmo Research Institute Petroleum additive and process for producing alkaline earth metal salt of an aromatic hydroxy-carboxylic acid
WO2004013265A1 (en) * 2002-08-05 2004-02-12 Nippon Oil Corporation Lubricating oil composition
WO2004013264A1 (en) * 2002-08-05 2004-02-12 Nippon Oil Corporation Lubricating oil composition
WO2004013263A1 (en) * 2002-08-05 2004-02-12 Nippon Oil Corporation Lubricating oil composition
WO2004055140A1 (en) * 2002-12-17 2004-07-01 Nippon Oil Corporation Lubricating oil additive and lubricating oil composition
US7563752B2 (en) 2002-08-05 2009-07-21 Nippon Oil Corporation Lubricating oil compositions
US7625847B2 (en) 2002-08-05 2009-12-01 Nippon Oil Corporation Lubricating oil compositions

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4627928A (en) * 1976-08-26 1986-12-09 The Lubrizol Corporation Basic non-carbonated magnesium compositions and fuel, lubricant and additive concentrate compositions containing same
FR2391186A1 (en) * 1977-05-16 1978-12-15 Lubrizol Corp Non-carbonated overbased magnesium salts prepn. - from hydrocarbyl-substd. hydroxylic aromatic carboxylic acid, useful as additives for lubricants and fuels
US4499295A (en) * 1983-05-09 1985-02-12 G. D. Searle & Co. Protease inhibitors
US4749505A (en) * 1985-07-08 1988-06-07 Exxon Chemical Patents Inc. Olefin polymer viscosity index improver additive useful in oil compositions
CA1262721A (en) 1985-07-11 1989-11-07 Jacob Emert Oil soluble dispersant additives useful in oleaginous compositions
GB8531626D0 (en) * 1985-12-23 1986-02-05 Shell Int Research Grease composition
GB8613815D0 (en) * 1986-06-06 1986-07-09 Shell Int Research Basic salt
JP2592456B2 (en) * 1987-06-12 1997-03-19 大洋化工株式会社 Lubricant composition and method for producing the same
GB8714922D0 (en) * 1987-06-25 1987-07-29 Shell Int Research Lubricating oil composition
GB8722323D0 (en) * 1987-09-22 1987-10-28 Shell Int Research Lubricating oil composition
DE4020047C1 (en) * 1990-04-05 1991-10-31 Mekuwa Metall- Und Kunststoff-Fertigungs-Gesellschaft Mbh, 6082 Moerfelden-Walldorf, De
JP3107173B2 (en) * 1991-12-27 2000-11-06 株式会社三光開発科学研究所 Process for producing nuclear-substituted salicylic acid metal salt
US5672572A (en) * 1993-05-27 1997-09-30 Arai; Katsuya Lubricating oil composition
US6306802B1 (en) 1994-09-30 2001-10-23 Exxon Chemical Patents Inc. Mixed antioxidant composition
US5688751A (en) * 1996-08-14 1997-11-18 The Lubrizol Corporation Salicylate salts as lubricant additives for two-cycle engines
JPH1161165A (en) * 1997-06-12 1999-03-05 Tonen Corp Friction reducing agent comprising metallic salicylate and lubricating oil composition containing the same
JP5156157B2 (en) * 1998-04-27 2013-03-06 インフィニューム ホールディングス ベスローテン フェンノートシャップ Lubricating oil composition
EP1344812A1 (en) * 2002-03-13 2003-09-17 Infineum International Limited Overbased metallic salt diesel fuel additive compositions for improvement of particulate traps
EP1344811A1 (en) * 2002-03-13 2003-09-17 Infineum International Limited Iron salt diesel fuel additive composition for improvement of particulate traps
US7045654B2 (en) * 2002-10-31 2006-05-16 Crompton Corporation Method for the alkylation of salicylic acid
US20090029888A1 (en) * 2005-07-12 2009-01-29 Ramanathan Ravichandran Amine tungstates and lubricant compositions
CA2614504A1 (en) * 2005-07-12 2007-01-18 King Industries, Inc. Amine tungstates and lubricant compositions

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0192323A1 (en) * 1985-01-18 1986-08-27 Nippon Oil Co. Ltd. Gasoline compositions for automotive vehicles
EP0283294A1 (en) * 1987-03-19 1988-09-21 Exxon Chemical Patents Inc. Improved fuel oil compositions
WO1988007071A1 (en) * 1987-03-19 1988-09-22 Exxon Chemical Limited Improved fuel oil compositions
EP0675191A2 (en) * 1994-03-30 1995-10-04 Cosmo Research Institute Petroleum additive and process for producing alkaline earth metal salt of an aromatic hydroxy-carboxylic acid
EP0675191A3 (en) * 1994-03-30 1995-12-13 Cosmo Sogo Kenkyusho Kk Petroleum additive and process for producing alkaline earth metal salt of an aromatic hydroxy-carboxylic acid.
US7563751B2 (en) 2002-08-05 2009-07-21 Nippon Oil Corporation Lubricating oil composition
WO2004013264A1 (en) * 2002-08-05 2004-02-12 Nippon Oil Corporation Lubricating oil composition
WO2004013263A1 (en) * 2002-08-05 2004-02-12 Nippon Oil Corporation Lubricating oil composition
CN100462424C (en) * 2002-08-05 2009-02-18 新日本石油株式会社 Lubricating oil compositions
CN100500818C (en) * 2002-08-05 2009-06-17 新日本石油株式会社 Lubricating oil compositions
US7563752B2 (en) 2002-08-05 2009-07-21 Nippon Oil Corporation Lubricating oil compositions
WO2004013265A1 (en) * 2002-08-05 2004-02-12 Nippon Oil Corporation Lubricating oil composition
US7625847B2 (en) 2002-08-05 2009-12-01 Nippon Oil Corporation Lubricating oil compositions
US8765649B2 (en) 2002-08-05 2014-07-01 Nippon Oil Corporation Lubricating oil composition
WO2004055140A1 (en) * 2002-12-17 2004-07-01 Nippon Oil Corporation Lubricating oil additive and lubricating oil composition
US7629302B2 (en) 2002-12-17 2009-12-08 Nippon Oil Corporation Lubricating oil additive and lubricating oil composition

Also Published As

Publication number Publication date
NL6918900A (en) 1970-06-23
NL169730B (en) 1982-03-16
DE1963320A1 (en) 1970-07-09
NL169730C (en) 1982-08-16
FR2026542A1 (en) 1970-09-18
SE359537B (en) 1973-09-03
BE743261A (en) 1970-06-17
DE1963320B2 (en) 1981-08-13
US3704315A (en) 1972-11-28
DE1963320C3 (en) 1982-05-06

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee