GB1182651A - Polymerisation Catalysts and Polymers prepared therewith - Google Patents

Polymerisation Catalysts and Polymers prepared therewith

Info

Publication number
GB1182651A
GB1182651A GB05492/67A GB1549267A GB1182651A GB 1182651 A GB1182651 A GB 1182651A GB 05492/67 A GB05492/67 A GB 05492/67A GB 1549267 A GB1549267 A GB 1549267A GB 1182651 A GB1182651 A GB 1182651A
Authority
GB
United Kingdom
Prior art keywords
metal
groups
compounds
atom
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB05492/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1182651A publication Critical patent/GB1182651A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/13—Organo-metallic compounds

Abstract

1,182,651. Polymerisation catalysts. MONSANTO CO. 4 April, 1967 [4 April, 1966; 6 March, 1967 (4)], No. 15492/67. Heading B1E. [Also in Divisions C2, C3 and C7] A polymerisation catalyst is prepared by forming a mixture of (1) a compound having the general formula Xn MCR<SP>1</SP>R<SP>2</SP>-(-M X( n-1 ) CR<SP>1</SP>R<SP>2</SP>) p MX n in which each of R<SP>1</SP> and R<SP>2</SP> is a hydrogen atom or a hydrocarbon group or R<SP>1</SP> and R<SP>2</SP> taken together with the carbon atom to which they are attached form a vinylidene group in which one or both of the hydrogen atoms may be replaced by hydrocarbon groups, M is boron or a metal from Group II, IIIA or IVA of the Periodic Table according to Deming, each X is a halogen atom, n is an integer which is one less than the valency of M and p is zero or an integer, and (2) a compound of a transition metal from Groups IB, IIIB to VIIB or VIII, or a complex containing such a compound R<SP>1</SP> and R<SP>2</SP> preferably have not more than 8 carbon atoms. Metal compounds (2) are preferably used in the highest oxidation state of the metal. Preferred salts under (2) are the halides; mixed halides and cyclopentadienyl compounds are also very suitable. An especially preferred class of titanium compounds are (R<SP>4</SP>Z) m TiX<SP>1</SP>( 4-m ) in which R<SP>4</SP> is a hydrogen atom or a hydrocarbon group m is an integer from 1 to 4, Z is an oxygen, sulphur, selenium or tellurium atom or an -NR<SP>4</SP>- group. Another useful class of compounds under (2) are (R<SP>4</SP>) 3 QTiX 4 <SP>1</SP> in which Q is a N, P, As, Sb or Bi atom or a monoxide or monosulphide of P, As or Sb. Acetyl acetonate compounds of V, Mn, Fe, Co, Ni, Cr, Ti, Zr, or Mo are also useful. The catalyst may be prepared by electrolysing a compound CR<SP>1</SP>R<SP>2</SP>X 2 using (a) an anode formed from boron or a metal from Groups II, IIIA or IVA and (b) an anode formed from a transition metal from Groups defined above or an anode of an alloy of an element under (a) with a transition metal under (b). The electrolyte is preferably X n MOR<SP>3</SP> where R<SP>3</SP> is a hydrogen atom or an organic group and it is preferably carried out in the presence of an inert gas or ethylene. The catalyst may also be prepared by heating under substantially anhydrous conditions a halide CR<SP>1</SP>R<SP>2</SP>X 3 with an alloy of (1) boron or a metal from Groups II, IIIA or IVA with (2) a transition metal from Groups IB, IIIB to VIIB or VIII.
GB05492/67A 1966-04-04 1967-04-04 Polymerisation Catalysts and Polymers prepared therewith Expired GB1182651A (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US53966266A 1966-04-04 1966-04-04
US62103567A 1967-03-06 1967-03-06
US62066967A 1967-03-06 1967-03-06
US62103667A 1967-03-06 1967-03-06
US62067067A 1967-03-06 1967-03-06

Publications (1)

Publication Number Publication Date
GB1182651A true GB1182651A (en) 1970-03-04

Family

ID=27541865

Family Applications (1)

Application Number Title Priority Date Filing Date
GB05492/67A Expired GB1182651A (en) 1966-04-04 1967-04-04 Polymerisation Catalysts and Polymers prepared therewith

Country Status (4)

Country Link
BE (1) BE696593A (en)
DE (1) DE1745099A1 (en)
GB (1) GB1182651A (en)
NL (1) NL6704784A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2578754A1 (en) * 1985-03-13 1986-09-19 Charbonnages Ste Chimique ELECTROCHEMICAL CATALYTIC SYSTEM, PROCESS FOR PREPARING THE SAME AND APPLICATION THEREOF TO THE MANUFACTURE OF ALDEHYDES
US4831090A (en) * 1986-10-15 1989-05-16 Basf Aktiengesellschaft Preparation of homopolymers of ethene and copolymers of ethene with higher α-monoolefins using a Ziegler catalyst system
WO1989012649A2 (en) * 1988-06-23 1989-12-28 Norsolor Process for preparing a catalyst for the polymerization of olefins
FR2633298A1 (en) * 1988-06-23 1989-12-29 Norsolor Sa CATALYTIC COMPONENT FOR OLEFIN POLYMERIZATION AND PROCESS FOR PREPARING THE SAME
CN112934251A (en) * 2019-12-11 2021-06-11 中国科学院大连化学物理研究所 Bifunctional catalyst for catalyzing n-heptane hydroisomerization and preparation method thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2578754A1 (en) * 1985-03-13 1986-09-19 Charbonnages Ste Chimique ELECTROCHEMICAL CATALYTIC SYSTEM, PROCESS FOR PREPARING THE SAME AND APPLICATION THEREOF TO THE MANUFACTURE OF ALDEHYDES
WO1986005415A1 (en) * 1985-03-13 1986-09-25 Societe Chimique Des Charbonnages S.A. Electrochemical catalytic system, preparation method thereof and its application to the production of aldehydes
EP0196253A1 (en) * 1985-03-13 1986-10-01 Exxon Chemical Patents Inc. Catalytic system, its preparation method and its use in the production of aldehydes
US4923840A (en) * 1985-03-13 1990-05-08 Exxon Chemical Company Electrochemical catalytic system, the process for preparation thereof and its application to the production of aldehydes
US4831090A (en) * 1986-10-15 1989-05-16 Basf Aktiengesellschaft Preparation of homopolymers of ethene and copolymers of ethene with higher α-monoolefins using a Ziegler catalyst system
FR2633299A1 (en) * 1988-06-23 1989-12-29 Norsolor Sa CATALYST FOR THE POLYMERIZATION OF OLEFINS, AND PROCESS FOR PREPARING THE SAME
FR2633298A1 (en) * 1988-06-23 1989-12-29 Norsolor Sa CATALYTIC COMPONENT FOR OLEFIN POLYMERIZATION AND PROCESS FOR PREPARING THE SAME
EP0351265A1 (en) * 1988-06-23 1990-01-17 Ecp Enichem Polymeres France Catalyst component for olefine polymerization, and process for preparing the same
EP0351266A1 (en) * 1988-06-23 1990-01-17 Ecp-Enichem Polymeres France S.A. Process for preparing an olefin polymerization catalyst
WO1989012649A3 (en) * 1988-06-23 1990-01-25 Norsolor Sa Process for preparing a catalyst for the polymerization of olefins
WO1989012649A2 (en) * 1988-06-23 1989-12-28 Norsolor Process for preparing a catalyst for the polymerization of olefins
CN112934251A (en) * 2019-12-11 2021-06-11 中国科学院大连化学物理研究所 Bifunctional catalyst for catalyzing n-heptane hydroisomerization and preparation method thereof
CN112934251B (en) * 2019-12-11 2023-06-06 中国科学院大连化学物理研究所 Double-function catalyst for catalyzing hydroisomerization of n-heptane and preparation method thereof

Also Published As

Publication number Publication date
DE1745099A1 (en) 1970-05-14
BE696593A (en) 1967-10-04
NL6704784A (en) 1967-10-05

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees