GB1179222A - Process for the Production of Polyurethanes. - Google Patents

Process for the Production of Polyurethanes.

Info

Publication number
GB1179222A
GB1179222A GB1420868A GB1420868A GB1179222A GB 1179222 A GB1179222 A GB 1179222A GB 1420868 A GB1420868 A GB 1420868A GB 1420868 A GB1420868 A GB 1420868A GB 1179222 A GB1179222 A GB 1179222A
Authority
GB
United Kingdom
Prior art keywords
diisocyanate
polyurethanes
adipic acid
polycarbonate
hexanediol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1420868A
Inventor
Erwin Mueller
Wilhelm Kallert
Joszef Ivanyi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1179222A publication Critical patent/GB1179222A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

1,179,222. Polyurethanes. FARBENFABRIKEN BAYER A.G. 25 March, 1968 [25 March, 1967], No. 14208/68. Heading C3R. Polyurethanes are prepared by reacting a diisocyanate, a compound of M.W. below 800 containing at least two reactive hydrogen atoms and a mixture of a hydroxyl-containing dicarboxylic acid based polyester of M.W. 1000 to 3000 and a hydroxyl-containing hexanediol-1,6- polycarbonate, the proportion of hexanediol-1,6- polycarbonate being 10 to 50% by weight based on the total amount of polyester and polycarbonate. Polyesters based on adipic acid, particularly ethylene glycol-adipic acid, ethylene glycol-butane diol- 1,4-adipic acid and neopentyl glycol-hexanediol-1,6-adipic acid polyesters are preferred. The diisocyanate is preferably 1,5-naphthylene diisocyanate, 4,4<SP>1</SP>-diphenylmethane diisocyanate, m- and p-phenylene diisocyanate, 2,4- and 2,6-toluylene diisocyanates. Suitable chain lengthening agents are glycols when the reaction is carried out in the absence of solvents and diamines, hydrazine or dihydrazides when a solvent is used. Water may also be used as a chain lengthening agent. A prepolymer may first be formed from the diisocyanate and mixture of polyhydroxyl compounds which prepolymer may then be chainlengthened or else the three components may be reacted in one step. Suitable solvents are dimethylformamide, dimethylacetamide and dimethylsulphoxide. The resulting polyurethanes may be cross-linked by reaction with sulphur, peroxides, formaldehyde or diisocyanates. Films and filaments may be produced from the polyurethanes when the latter are produced in solution by chain-lengthening with diamines, hydrazine or dihydrazides.
GB1420868A 1967-03-25 1968-03-25 Process for the Production of Polyurethanes. Expired GB1179222A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0051944 1967-03-25

Publications (1)

Publication Number Publication Date
GB1179222A true GB1179222A (en) 1970-01-28

Family

ID=7105043

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1420868A Expired GB1179222A (en) 1967-03-25 1968-03-25 Process for the Production of Polyurethanes.

Country Status (4)

Country Link
DE (1) DE1694141B2 (en)
FR (1) FR1559394A (en)
GB (1) GB1179222A (en)
SE (1) SE326038B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114149671A (en) * 2021-11-19 2022-03-08 天津金发新材料有限公司 PC/ABS composition and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2910769A1 (en) * 1979-03-19 1980-10-02 Basf Ag METHOD FOR PRODUCING POLYURETHANE ELASTOMERS

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114149671A (en) * 2021-11-19 2022-03-08 天津金发新材料有限公司 PC/ABS composition and preparation method thereof
CN114149671B (en) * 2021-11-19 2023-10-27 天津金发新材料有限公司 PC/ABS composition and preparation method thereof

Also Published As

Publication number Publication date
DE1694141A1 (en) 1971-08-05
FR1559394A (en) 1969-03-07
SE326038B (en) 1970-07-13
DE1694141B2 (en) 1972-07-20

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