GB1175322A - Hydrocarbon Soluble Organosodium Reagents - Google Patents
Hydrocarbon Soluble Organosodium ReagentsInfo
- Publication number
- GB1175322A GB1175322A GB1430368A GB1430368A GB1175322A GB 1175322 A GB1175322 A GB 1175322A GB 1430368 A GB1430368 A GB 1430368A GB 1430368 A GB1430368 A GB 1430368A GB 1175322 A GB1175322 A GB 1175322A
- Authority
- GB
- United Kingdom
- Prior art keywords
- diamine
- organosodium
- hydrocarbon
- tertiary
- complexes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 4
- 229930195733 hydrocarbon Natural products 0.000 title abstract 4
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 4
- 239000003153 chemical reaction reagent Substances 0.000 title 1
- 150000004985 diamines Chemical group 0.000 abstract 4
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 abstract 2
- 229930008564 C01BA04 - Sparteine Natural products 0.000 abstract 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- SLRCCWJSBJZJBV-UHFFFAOYSA-N alpha-isosparteine Natural products C1N2CCCCC2C2CN3CCCCC3C1C2 SLRCCWJSBJZJBV-UHFFFAOYSA-N 0.000 abstract 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 239000002198 insoluble material Substances 0.000 abstract 1
- 238000006263 metalation reaction Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- SLRCCWJSBJZJBV-AJNGGQMLSA-N sparteine Chemical compound C1N2CCCC[C@H]2[C@@H]2CN3CCCC[C@H]3[C@H]1C2 SLRCCWJSBJZJBV-AJNGGQMLSA-N 0.000 abstract 1
- 229960001945 sparteine Drugs 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/04—Sodium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polyamides (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
1,175,322. Hydrocarbon soluble organosodium complexes. BORG-WARNER CORP. 25 March, 1968 [30 March, 1967], No. 14303/68. Heading C2J. [Also in Division C3] An organo-sodium compound RNa, where R is an aliphatic or aromatic radical, is reacted in a hydrocarbon with an open chain or cycloaliphatic tertiary diamine or a tertiary diamine in which the N atom forms part of a heterocyclic ring to yield a homogenous hydrocarbon solution of a chemically active organosodium complex product which is separated from any insoluble material present. Tertiary diamines specified include N,N,N<SP>1</SP>,N<SP>1</SP>-tetramethylethyl. ene diamine, sparteine and triethylene diamine. Preferably R is alkyl or phenyl groups. Complexes of the present invention may be used for the initiation of vinyl monomer anionic polymerization and metalation of polymers as described in Specification 1,172,477.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US62697967A | 1967-03-30 | 1967-03-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1175322A true GB1175322A (en) | 1969-12-23 |
Family
ID=24512660
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1430368A Expired GB1175322A (en) | 1967-03-30 | 1968-03-25 | Hydrocarbon Soluble Organosodium Reagents |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE1768022B1 (en) |
| FR (1) | FR1561591A (en) |
| GB (1) | GB1175322A (en) |
| NL (1) | NL6804487A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4678614A (en) * | 1985-11-27 | 1987-07-07 | Lithium Corporation Of America, Inc. | Hydrocarbon-soluble organometallic complexes of magnesium and alkali metals and method of producing same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3742057A (en) * | 1970-02-27 | 1973-06-26 | Exxon Research Engineering Co | Chelated sodium compounds |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3206519A (en) * | 1963-11-19 | 1965-09-14 | Sun Oil Co | Preparation of alkyl aromatic hydrocarbons |
-
1968
- 1968-03-22 DE DE19681768022 patent/DE1768022B1/en active Pending
- 1968-03-25 GB GB1430368A patent/GB1175322A/en not_active Expired
- 1968-03-29 FR FR1561591D patent/FR1561591A/fr not_active Expired
- 1968-03-29 NL NL6804487A patent/NL6804487A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4678614A (en) * | 1985-11-27 | 1987-07-07 | Lithium Corporation Of America, Inc. | Hydrocarbon-soluble organometallic complexes of magnesium and alkali metals and method of producing same |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1561591A (en) | 1969-03-28 |
| NL6804487A (en) | 1968-10-01 |
| DE1768022B1 (en) | 1972-07-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |