GB1172239A - Improvements in or relating to Organotin Compounds - Google Patents
Improvements in or relating to Organotin CompoundsInfo
- Publication number
- GB1172239A GB1172239A GB57681/66A GB5768166A GB1172239A GB 1172239 A GB1172239 A GB 1172239A GB 57681/66 A GB57681/66 A GB 57681/66A GB 5768166 A GB5768166 A GB 5768166A GB 1172239 A GB1172239 A GB 1172239A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetoxime
- reaction
- organotin compounds
- sodium salt
- tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 abstract 6
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 abstract 3
- 159000000000 sodium salts Chemical class 0.000 abstract 3
- LUZSPGQEISANPO-UHFFFAOYSA-N butyltin Chemical compound CCCC[Sn] LUZSPGQEISANPO-UHFFFAOYSA-N 0.000 abstract 2
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- VTWKXBJHBHYJBI-SOFGYWHQSA-N (ne)-n-benzylidenehydroxylamine Chemical compound O\N=C\C1=CC=CC=C1 VTWKXBJHBHYJBI-SOFGYWHQSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 abstract 1
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- YMLFYGFCXGNERH-UHFFFAOYSA-K butyltin trichloride Chemical compound CCCC[Sn](Cl)(Cl)Cl YMLFYGFCXGNERH-UHFFFAOYSA-K 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- WCFAIDNLEDEVLH-UHFFFAOYSA-L dibutyl(dichloro)stannane N-propan-2-ylidenehydroxylamine Chemical compound C(CCC)[Sn](CCCC)(Cl)Cl.CC(C)=NO WCFAIDNLEDEVLH-UHFFFAOYSA-L 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000011496 polyurethane foam Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229920002379 silicone rubber Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2224—Compounds having one or more tin-oxygen linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
1,172,239. Organotin compounds. STAUFFER CHEMICAL CO. 23 Dec., 1966 [27 Dec., 1965], No. 57681/66. Heading C2J. [Also in Division C3] Novel organotin compounds have the formula wherein R<SP>11</SP> and R are selected from a C 1-12 aliphatic group, an alicyclic group, aromatic group and the corresponding halo- and cyanosubstituted groups, R<SP>1</SP> is hydrogen or one of the above groups, and n is 1, 2 or 3. These compounds may be used to prepare mixed tin salts, wherein n is 2 and one of the remaining valence bonds is satisfied by a halogen atom, by reaction with R<SP>11</SP> 2 SnX 2 (R<SP>11</SP> is as above and X is halogen). In the examples the following organotin compounds are prepared (1) triacetoximo butyl tin by reaction of the sodium salt of acetoxime with butyl tin trichloride, (2) diacetoximodibutyltin by reaction of (a) the sodium salt of acetoxime with dibutyl tin dichloride, (b) acetone oxime with dibutyltin dichloride, (c) acetoxime with dibutyltinoxide, (3) acetoximotributyltin by reaction of (a) the sodium salt of acetoxime with tributyltin chloride or (b) tributyltinoxide with acetoxime, and (3) dibenzaldoximedibutyltin by reaction of benzaldoxime with dibutyltin oxide. In a further example, triacetoximo butyltin and dibutyltin dichloride are reacted together to give a mixed salt of acetoxime-dibutyl tin chloride. The organotin compounds may be used as catalysts in the curing of silicone rubbers and in the production of flexible polyurethane foams (see Division C3).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51675665A | 1965-12-27 | 1965-12-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1172239A true GB1172239A (en) | 1969-11-26 |
Family
ID=24056964
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB57681/66A Expired GB1172239A (en) | 1965-12-27 | 1966-12-23 | Improvements in or relating to Organotin Compounds |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE691784A (en) |
CH (1) | CH495380A (en) |
DE (1) | DE1593566B2 (en) |
FR (1) | FR1506186A (en) |
GB (1) | GB1172239A (en) |
IL (1) | IL27146A (en) |
NL (1) | NL148349B (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2727917A (en) * | 1950-08-05 | 1955-12-20 | Advance Solvents & Chemical Co | Method of preparing organo-substituted stannane derivatives |
US3275659A (en) * | 1961-04-28 | 1966-09-27 | Monsanto Co | Triorganotin oximes and their preparation |
-
1966
- 1966-12-23 GB GB57681/66A patent/GB1172239A/en not_active Expired
- 1966-12-25 IL IL27146A patent/IL27146A/en unknown
- 1966-12-27 DE DE1593566A patent/DE1593566B2/en active Pending
- 1966-12-27 BE BE691784D patent/BE691784A/xx unknown
- 1966-12-27 FR FR89042A patent/FR1506186A/en not_active Expired
- 1966-12-27 CH CH1859766A patent/CH495380A/en not_active IP Right Cessation
- 1966-12-27 NL NL666618195A patent/NL148349B/en unknown
Also Published As
Publication number | Publication date |
---|---|
DE1593566B2 (en) | 1974-01-31 |
DE1593566A1 (en) | 1969-08-21 |
FR1506186A (en) | 1967-12-15 |
CH495380A (en) | 1970-08-31 |
NL148349B (en) | 1976-01-15 |
IL27146A (en) | 1970-11-30 |
NL6618195A (en) | 1967-06-28 |
BE691784A (en) | 1967-06-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
PLE | Entries relating assignments, transmissions, licences in the register of patents | ||
PCNP | Patent ceased through non-payment of renewal fee |