GB1168822A - Sweetening Hydrocarbon Liquids - Google Patents

Sweetening Hydrocarbon Liquids

Info

Publication number
GB1168822A
GB1168822A GB4531566A GB4531566A GB1168822A GB 1168822 A GB1168822 A GB 1168822A GB 4531566 A GB4531566 A GB 4531566A GB 4531566 A GB4531566 A GB 4531566A GB 1168822 A GB1168822 A GB 1168822A
Authority
GB
United Kingdom
Prior art keywords
glycine
styrene
resin
vinyl
divinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4531566A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Howe Baker Engineers LLC
Original Assignee
Howe Baker Engineers LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Howe Baker Engineers LLC filed Critical Howe Baker Engineers LLC
Publication of GB1168822A publication Critical patent/GB1168822A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C10G25/05—Removal of non-hydrocarbon compounds, e.g. sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1,168,822. Sweetening hydrocarbons. HOWEBAKER ENGS. Inc. 11 Oct., 1966 [11 Oct., 1965; 25 March, 1966], No. 45315/66. Heading C5E. A process for sweetening sour liquid hydrocarbon compositions containing organic mercaptans comprises contacting them with a particulate aluminosilicate ion exchange composition having at least one square metre per gram of surface area available to the hydrocarbon and containing ionically-bound Hg, Ag, Pb, Cu, Co, Fe, Pt or Pd, or a synthetic organic resin ion exchange composition containing ionically-bound Hg, Ag, Pb, Co, Fe, Pt or Pd, whereby the mercaptans are converted at least in part to disulphides, and separating the sweetened hydrocarbon composition. The ion exchanger may be a natural or synthetic zeolite (including molecular sieves), a sulphonated phenol-formaldehyde resin or sulphonated styrene-divinylbenzene copolymer, a resin containing carboxylic groups, a quaternary ammonium type anion exchange resin, a polyamine type resin or a chelate type resin, e.g. chloromethylated styrene-divinyl benzene copolymer reacted with iminodiacetic acid. Preferred resins are cross-linked copolymers of styrene, vinyltoluenes, ethyl styrene, α-methyl styrene, vinyl naphthalene or vinyl acenaphthalene with divinyl benzene, ethylene dimethacrylate, vinyl acrylate, vinyl methacrylate, divinyl oxalate, divinyl ketone or styryl vinyl ketone. The metal/ion-exchanger compound may be complexed with ammonia or an amine (including pyridine), or oxalic, lactic, gluconic, citric, tartaric, salicylic, 5-sulphosalicylic, glutamic, pyrophosphonic, nitroacetic or 8 - hydroxyquinoline - 5 - sulphonic acid, disodium - 1,2 - dihydroxy benzene - 3,5- disulphonate, N-methyl glycine, glycine, N- ethyl glycine, N-propyl glycine, N-butyl glycine, N-isopropylglycine, α-alanine, #-alanine, norvaline, leucine, phenylalanine, tyrosine, serine, threonine, l-ornithine, asparagine, lysine, arginine, proline or glycylglycine.
GB4531566A 1965-10-11 1966-10-11 Sweetening Hydrocarbon Liquids Expired GB1168822A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US49487165A 1965-10-11 1965-10-11
US53728566A 1966-03-25 1966-03-25

Publications (1)

Publication Number Publication Date
GB1168822A true GB1168822A (en) 1969-10-29

Family

ID=27051574

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4531566A Expired GB1168822A (en) 1965-10-11 1966-10-11 Sweetening Hydrocarbon Liquids

Country Status (8)

Country Link
BE (2) BE688096A (en)
BR (1) BR6683531D0 (en)
CH (1) CH481205A (en)
DE (1) DE1545312A1 (en)
ES (1) ES332609A1 (en)
FR (1) FR1500449A (en)
GB (1) GB1168822A (en)
NL (1) NL6614280A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0354316A1 (en) * 1988-07-23 1990-02-14 Hüls Aktiengesellschaft Process for the deep desulphurisation of hydrocarbons
GB2439387A (en) * 2006-06-21 2007-12-27 Oil Plus Ltd Method of screening hydrocarbon compositions for low molecular weight naphthenic acids

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2477569B1 (en) * 1980-03-07 1985-06-28 Uop Inc PROCESS FOR THE CONVERSION OF MERCAPTANS CONTAINED IN AN ACID OIL DISTILLATE
FR2512051A1 (en) * 1981-08-26 1983-03-04 Raffinage Cie Francaise Sulphur cpds. removed from reforming feedstocks, etc. - by contacting with cation exchange resin charged with Gp=IIb metal ions
FR2524818A1 (en) * 1982-04-09 1983-10-14 Raffinage Cie Francaise NOVEL OXIDATION CATALYST OF MERCAPTANS IN DISULFIDE, PROCESS FOR PREPARING THE SAME AND APPLICATION TO SOFTENING PETROLEUM DISTILLATES
FR2902797B1 (en) * 2006-06-21 2008-09-19 Inst Francais Du Petrole PROCESS FOR REMOVING MERCAPTANS FROM LIQUID AND GASEOUS EFFLUENTS

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0354316A1 (en) * 1988-07-23 1990-02-14 Hüls Aktiengesellschaft Process for the deep desulphurisation of hydrocarbons
JPH0273887A (en) * 1988-07-23 1990-03-13 Huels Ag Method for precision desulfurization of hydrocarbon
JP2656981B2 (en) 1988-07-23 1997-09-24 ヒユールス・アクチエンゲゼルシヤフト Precision desulfurization of hydrocarbons
GB2439387A (en) * 2006-06-21 2007-12-27 Oil Plus Ltd Method of screening hydrocarbon compositions for low molecular weight naphthenic acids

Also Published As

Publication number Publication date
NL6614280A (en) 1967-04-12
DE1545312A1 (en) 1970-01-08
BE859473Q (en) 1978-02-01
FR1500449A (en) 1967-11-03
CH481205A (en) 1969-11-15
BR6683531D0 (en) 1973-12-26
ES332609A1 (en) 1967-08-01
BE688096A (en) 1967-04-11

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