GB1162626A - A process for the Hydrocracking of a Hydrocarbon Oil - Google Patents

A process for the Hydrocracking of a Hydrocarbon Oil

Info

Publication number
GB1162626A
GB1162626A GB2657468A GB2657468A GB1162626A GB 1162626 A GB1162626 A GB 1162626A GB 2657468 A GB2657468 A GB 2657468A GB 2657468 A GB2657468 A GB 2657468A GB 1162626 A GB1162626 A GB 1162626A
Authority
GB
United Kingdom
Prior art keywords
hydrocracking
gasoline
weight
boiling point
fraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2657468A
Inventor
Marius T Hart
Cornelis Jacobus Paul
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB2657468A priority Critical patent/GB1162626A/en
Priority to FR6918046A priority patent/FR2010080A6/en
Priority to NL6908339A priority patent/NL6908339A/xx
Priority to DE19691928016 priority patent/DE1928016A1/en
Publication of GB1162626A publication Critical patent/GB1162626A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/28—Propane and butane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

1,162,626. Hydrocracking petroleum oils. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 4 June, 1968, No. 26574/68. Addition to 1,059,692. Heading C5E. A process for the hydrocracking of a hydrocarbon oil according to Specification 1,059,692 in which a naphthenic kerosene feed having a total ring content of at least 50% by weight and a smoke point of 23 millimetres or less is converted to liquefied petroleum gas components, a light gasoline having a high iso to normal ratio of paraffins with five and/or six carbon atoms in their molecule and a heavy gasoline comprises the following steps: (a) hydrotreating the said naphthenic kerosene feed over a hydro-desulphurization catalyst at a pressure of less than 100 kilograms per square centimetre and a temperature of from 315‹ to 375‹ C., (b) hydrocracking the hydro-treated kerosene feed at a pressure less than 100 kilograms per square centimetre and a temperature of from 270‹ to 390‹ C., over a fluorided hydrocracking catalyst prepared as claimed in British Patent Specification 1,059,692 and comprising 0À1 to 14% by weight of nickel and 0À1 to 5% by weight of tungsten as the active metal components and having a silica-alumina carrier comprising at least 60% by weight of silica, (c) producing a hydrocracking effluent stream from which may be recovered liquid petroleum gas components, a light gasoline or a light gasoline fraction comprising C 5 and/or C 6 paraffins and having a final boiling point in the range of from 65‹ to 120‹ C. and a heavy gasoline or a heavy gasoline fraction with an initial boiling point corresponding with the final boiling point of the said light gasoline or light gasoline fraction, and (d) recycling to the hydrocracking stage of step (b) any residual fraction boiling above the final boiling point of the said heavy gasoline or gasoline fraction. High iso to normal ratio is defined as greater than 6 to 1. The hydrodesulphurization catalyst may comprise one or more oxides or sulphides of molybdenum, tungsten, cobalt or nickel supported on alumina, silica, zirconia, titania, bauxite, bentonite or mixtures thereof. During the hydrocracking step fluorine may be continuously added as hydrogen fluoride, fluorobenzene, fluoro-toluene or difluoroethane.
GB2657468A 1964-09-01 1968-06-04 A process for the Hydrocracking of a Hydrocarbon Oil Expired GB1162626A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB2657468A GB1162626A (en) 1968-06-04 1968-06-04 A process for the Hydrocracking of a Hydrocarbon Oil
FR6918046A FR2010080A6 (en) 1968-06-04 1969-06-02 Process for hydrogenative cracking of naphthenic - hydrocarbon oils
NL6908339A NL6908339A (en) 1964-09-01 1969-06-02
DE19691928016 DE1928016A1 (en) 1968-06-04 1969-06-02 Process for the hydrogenative cracking of a hydrocarbon oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2657468A GB1162626A (en) 1968-06-04 1968-06-04 A process for the Hydrocracking of a Hydrocarbon Oil

Publications (1)

Publication Number Publication Date
GB1162626A true GB1162626A (en) 1969-08-27

Family

ID=10245783

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2657468A Expired GB1162626A (en) 1964-09-01 1968-06-04 A process for the Hydrocracking of a Hydrocarbon Oil

Country Status (3)

Country Link
DE (1) DE1928016A1 (en)
FR (1) FR2010080A6 (en)
GB (1) GB1162626A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021237034A1 (en) * 2020-05-22 2021-11-25 Exxonmobil Research And Engineering .Company High naphthenic content naphtha fuel compositions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021237034A1 (en) * 2020-05-22 2021-11-25 Exxonmobil Research And Engineering .Company High naphthenic content naphtha fuel compositions
US11390820B2 (en) 2020-05-22 2022-07-19 ExxonMobil Technology and Engineering Company High naphthenic content naphtha fuel compositions

Also Published As

Publication number Publication date
FR2010080A6 (en) 1970-02-13
DE1928016A1 (en) 1970-02-19

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Legal Events

Date Code Title Description
PS Patent sealed
PE Patent expired