GB1161141A - Process for the preparation of Titanium Compounds which are substantially Free from Metallic Impurities - Google Patents
Process for the preparation of Titanium Compounds which are substantially Free from Metallic ImpuritiesInfo
- Publication number
- GB1161141A GB1161141A GB2964/67A GB296467A GB1161141A GB 1161141 A GB1161141 A GB 1161141A GB 2964/67 A GB2964/67 A GB 2964/67A GB 296467 A GB296467 A GB 296467A GB 1161141 A GB1161141 A GB 1161141A
- Authority
- GB
- United Kingdom
- Prior art keywords
- gel
- acid
- hydroxide
- compound
- hpo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/0475—Purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/37—Phosphates of heavy metals
- C01B25/372—Phosphates of heavy metals of titanium, vanadium, zirconium, niobium, hafnium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Abstract
1,161,141. Titanium compounds. MIZUSAWA KAGAKU KOGYO K.K. 19 Jan., 1967 [22 Jan., 1966 (2)], No. 2964/67. Headings C1A and C1N. A titanium oxy-phosphorus compound is produced by mixing a Ti compound with water and a phosphorus oxyacid or derivative thereof to give a liquid mixture which gels, forming granules during or after gelling without filtration, and extracting metal impurities from the granules. The Ti compound may be.-(a) An acid solution of ilmenite, iron sand slag, rutile, high Ti slag (compositions specified), gaseous or liquid TiCl 4 , or titanyl sulphate, e.g. sulphate process waste acid. The acid may be H 2 SO 4 , H 2 SO 3 (added as SO 2 gas), HCl, HClO 3 , HClO 4 , HNO 3 , oxalic, formic, methane sulphonic, or H 2 SO 4 +HNO 3 , and may be used at R.T. to B.pt. to dissolve the compound. If SiO 2 is present it is allowed to gel and is removed. (b) A Ti salt alone, e.g. TiCl 4 . (c) Amorphous Ti hydroxide, obtained by hydrolysis of acid solution (a) above by (i) heating under atmospheric or elevated pressure at 60-140 C., (ii) neutralizing, e.g. with NH 4 HCO 3 , or (iii) diluting with hot water. The gel so produced is filtered and may be heated at 100, 300, 500 or 650 C. The P compound may be H 3 PO 4 (e.g. crude acid), HPO 3 , H 4 P 2 O 7 , (HPO 3 ) 6 , H 5 P 3 O 10 , H 3 PO 3 , H 3 PO 2 ; anhydrides, e.g. P 2 O 5 ; halides or oxyhalides; salts of alkali metals, alkaline earth metals, ammonium, Zn, or Al, e.g. Na 2 HPO 4 .12H 2 O, NaPO 3 , Na 4 P 2 O 7 (NaPO 3 ) 6 , Na 5 P 3 O 10 , Na 2 HPO 3 , (NH4) 2 HPO 4 , Ca 3 (PO 4 ) 2 , and phosphorus ore. Formation of gel.-The P compound may be added at 0-80 C., optionally after the addition e.g. of H 2 SO 4 to the Ti solution, using 0À2-6 atoms P per atom Ti, to give a TiO 2 : P 2 O 5 mole ratio of 7.3 : 1 to 0.8 : 1. The mixture may form (a) a stable sol which is granulated while gelling, or (b) a gel which may be dried and is subsequently granulated. (a) Granulation of sol: it may be (i) poured or sprayed into an immiscible liquid (upwards or downwards), e.g. trichlorobenzene, kerosene alone or with dichloro or trichlorobenzene, or light oil, which may be agitated and maintained at 110 C., to give spheres 2-6 mm.; (ii) poured into a partitioned container, or tube or plate, and dried, e.g. at 100 or 115 C.; or (iii) dropped on to a belt conveyer or rotating drum or disc which may be heated, e.g. to 400 C., to give particles 70-200 Á. (b) Granulation of gel: it may be (i) cut or broken up, e.g. into flakes, (ii) extruded and air-dried; or (iii) thermally shrunk at 100 C. The grains may be 1À5-20 mm. in size. Extraction of impurities may be effected with water; acids, e.g. HC1, H 2 SO 4 , HNO 3 , H 3 PO 4 , H 2 SO 3 , HClO 3 , oxalic, acetic, formic, sulphonic or phosphonic; alkalis, e.g. NaOH, KOH, NH 4 OH, or lime water; organic solvents, e.g. methanol, ethanol, propanol, butanol, or acetone, with or without water or acid, e.g. H 2 SO 4 +methanol; complex formers, e.g. tributyl phosphate or EDTA; ion-exchange resins; or dialysis. A 2-stage treatment may be used, e.g. (a) dilute 0À1-10% acid then concentrated acid, (b) H 2 SO 4 at 60-70 C., then at 95 C., or (c) NaOH followed by H 2 SO 4 containing NaHSO 3 . Treatment with liquid may be effected by passing the liquid continuously through a column containing the gel, or by decantation. When alkali is used, the gel is converted into Ti hydroxide. Subsequent treatment.-The gel may be: (a) dried, broken up, and calcined at above 200 C., preferably at above 700 C.; (b) treated with P oxyacid or salt, e.g. H 3 PO 4 , to vary the TiO 2 : P 2 O 5 ratio, e.g. from 7.3 :1 to 2À2 : 1; (c) converted into Ti hydroxide by treating with NaOH or KOH, dried, crushed, and calcined at at least 500 C. to give TiO 2 ; or (d) treated with a salt of Al, Sn, Zn, Ca, or Zn and neutralized to deposit hydroxide. TiO 2 may be produced by dissolving the Ti hydroxide in HCl or H 2 SO 4 and hydrolysing. TiCl 4 may be produced by incorporating carbon into the starting solution or sol, forming Ti hydroxide from the gel, and treating the product with Cl 2 .
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP332466 | 1966-01-22 | ||
JP332266 | 1966-01-22 | ||
JP332366 | 1966-01-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1161141A true GB1161141A (en) | 1969-08-13 |
Family
ID=27275757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2964/67A Expired GB1161141A (en) | 1966-01-22 | 1967-01-19 | Process for the preparation of Titanium Compounds which are substantially Free from Metallic Impurities |
Country Status (8)
Country | Link |
---|---|
US (1) | US3471252A (en) |
BE (1) | BE693059A (en) |
DE (1) | DE1592459C3 (en) |
FR (1) | FR1510600A (en) |
GB (1) | GB1161141A (en) |
NL (1) | NL147108B (en) |
NO (1) | NO118431B (en) |
SE (1) | SE337267B (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE350469B (en) * | 1968-08-08 | 1972-10-30 | Mizusawa Industrial Chem | |
US3914381A (en) * | 1969-03-18 | 1975-10-21 | Mizusawa Industrial Chem | Process for the preparation of substantially pure phosphorus oxyacid salts of metals of group IV b{41 |
US3936304A (en) * | 1970-12-29 | 1976-02-03 | Tsuneo Kasugai | Article having a whitened polyolefin surface |
JPS516000B2 (en) * | 1972-03-01 | 1976-02-24 | ||
JPH04342419A (en) * | 1990-10-26 | 1992-11-27 | Westinghouse Electric Corp <We> | Method of hydrolyzing group ivb metal chlorides |
US5733519A (en) * | 1996-02-05 | 1998-03-31 | Monsanto Company | Method for producing a dispersible, fine titanium pyrophosphate powder |
AR059689A1 (en) * | 2006-03-01 | 2008-04-23 | Basf Ag | PROCEDURE FOR THE ACID DIGESTION OF METALIFEROUS COMPOUNDS THROUGH LIXIVIATION AND AQUATIVE LIXIVIATOR |
US7704470B2 (en) | 2007-04-24 | 2010-04-27 | Haydock Consulting Services, Lc | Removal of contaminants from by-product acids |
DE102008047533A1 (en) * | 2008-09-16 | 2010-04-15 | Sachtleben Chemie Gmbh | Process for the preparation of titanium-IV-phosphate |
CN109532152B (en) * | 2018-11-01 | 2021-03-02 | 无锡市中舶远航环保科技有限公司 | Acidolysis barrel lining anti-corrosion composite material and construction process thereof |
CN111705226B (en) * | 2020-06-22 | 2022-05-31 | 四川顺应动力电池材料有限公司 | Method for removing impurities from high-titanium slag |
CN114014355B (en) * | 2021-09-16 | 2023-07-25 | 攀枝花学院 | Industrial meta-titanic acid purifying and deironing method |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE558119A (en) * | 1956-06-08 | |||
US3104950A (en) * | 1961-12-11 | 1963-09-24 | Dow Chemical Co | Process for the separation of iron and titanium values by extraction and the subsequent preparation of anhydrous titanium dopxode |
GB1022590A (en) * | 1963-10-04 | 1966-03-16 | British Titan Products | Pigment preparation |
-
1967
- 1967-01-17 US US609918A patent/US3471252A/en not_active Expired - Lifetime
- 1967-01-19 GB GB2964/67A patent/GB1161141A/en not_active Expired
- 1967-01-19 SE SE00801/67A patent/SE337267B/xx unknown
- 1967-01-20 NO NO166514A patent/NO118431B/no unknown
- 1967-01-21 DE DE1592459A patent/DE1592459C3/en not_active Expired
- 1967-01-23 BE BE693059D patent/BE693059A/xx unknown
- 1967-01-23 NL NL676701036A patent/NL147108B/en unknown
- 1967-01-23 FR FR92181A patent/FR1510600A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE1592459B2 (en) | 1977-08-11 |
NL147108B (en) | 1975-09-15 |
DE1592459C3 (en) | 1978-04-06 |
NO118431B (en) | 1969-12-29 |
FR1510600A (en) | 1968-01-19 |
SE337267B (en) | 1971-08-02 |
DE1592459A1 (en) | 1970-12-17 |
NL6701036A (en) | 1967-07-24 |
US3471252A (en) | 1969-10-07 |
BE693059A (en) | 1967-07-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |