GB1159552A - Polymerizable Paint Binder Composition - Google Patents

Polymerizable Paint Binder Composition

Info

Publication number
GB1159552A
GB1159552A GB5426/69A GB542669A GB1159552A GB 1159552 A GB1159552 A GB 1159552A GB 5426/69 A GB5426/69 A GB 5426/69A GB 542669 A GB542669 A GB 542669A GB 1159552 A GB1159552 A GB 1159552A
Authority
GB
United Kingdom
Prior art keywords
molecular weight
ionizing radiation
polymerizable
binder component
paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5426/69A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ford Motor Co Ltd
Original Assignee
Ford Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ford Motor Co Ltd filed Critical Ford Motor Co Ltd
Priority claimed from GB35509/66A external-priority patent/GB1159551A/en
Publication of GB1159552A publication Critical patent/GB1159552A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C08F291/18—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to irradiated or oxidised macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

1,159,552. Polymerizable paint binder compositions. FORD MOTOR CO. Ltd. 9 Aug., 1966 [13 Aug., 1965], No. 5426/69. Divided out of 1,159,551. Headings C3P and C3T. Paint binders polymerizable by means of ionizing radiation comprise a film-forming solution in a flow-inducing solvent of (a) a vinylunsaturated binder component consisting essentially of an addition product of a diisocyanate and a C 5 -C 12 monohydroxy acrylic monomer, the said addition product having a molecular weight below 900, and (b) an organic resin having a molecular weight in excess of 1000 and containing 0À5-3 olefinic unsaturation units per 1000 of molecular weight, the resin (b) and binder component (a) being copolymerizable by ionizing radiation. The film-forming solution may be pigmented, e.g. with TiO 2 . The flow-inducing solvent may be a vinyl monomer or monomers, e.g. methyl methacrylate and/or styrene. In examples the binder component is an adduct of tolylene diisocyanate and 2-hydroxy ethyl methacrylate and the organic resin is (i) a silicone-modified polyester obtained by reacting nepoentyl glycol with a methoxylated partial hydrolysate of monophenyl and phenylmethyl silanes consisting essentially of dimethyltriphenyltrimethoxytrisiloxane and then further reacting with maleic anhydride, tetrahydrophthalic anhydride, dibutyl tin oxide and xylene; (ii) a silicone-modified polyester similar to (i) but wherein the siloxane used is a hydroxyfunctional, cyclic polysiloxane; (iii) a polyester derived from maleic anhydride, tetrahydrophthalic anhydride and neopentyl glycol; (iv) a methyl methacrylate/ethyl acrylate/glycidyl methacrylate copolymer modified by reaction with methacrylic acid. The treatment of the paint binder compositions with ionizing radiation is described in copending application Serial 1,159,551.
GB5426/69A 1965-08-13 1966-08-09 Polymerizable Paint Binder Composition Expired GB1159552A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US47952365A 1965-08-13 1965-08-13
GB35509/66A GB1159551A (en) 1965-08-13 1966-08-09 Painting

Publications (1)

Publication Number Publication Date
GB1159552A true GB1159552A (en) 1969-07-30

Family

ID=26262754

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5426/69A Expired GB1159552A (en) 1965-08-13 1966-08-09 Polymerizable Paint Binder Composition

Country Status (1)

Country Link
GB (1) GB1159552A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2509316A1 (en) * 1981-04-17 1983-01-14 Ceskoslovenska Akademie Ved GRAFT POLYMERIZATION PRODUCTS AND PROCESS FOR THEIR MANUFACTURE
US5128432A (en) * 1990-09-01 1992-07-07 Bayer Aktiengesellschaft Aliphatic polyurethanes containing acryloyl groups and a process for their preparation
US5136008A (en) * 1990-08-25 1992-08-04 Bayer Aktiengesellschaft Polyurethane containing acryloyl or methacryloyl groups, and a process for their production and their use
US5136009A (en) * 1990-09-04 1992-08-04 Bayer Aktiengesellschaft Aliphatic polyurethanes containing acryloyl groups and a process for their preparation
US5247048A (en) * 1991-12-18 1993-09-21 Bayer Aktiengesellschaft Aliphatic polyurethanes containing acryloyl groups and a process for their production
US5300615A (en) * 1992-09-24 1994-04-05 Bayer Aktiengesellschaft Polyurethanes containing acryloyl groups, a process for their preparation and their use as binders for coating compositions
US11518834B2 (en) 2019-01-02 2022-12-06 Polynt Composites USA, Inc. Radically polymerizable compositions
CN117402544A (en) * 2023-11-17 2024-01-16 东莞市瑞盟涂料有限公司 Low-VOC (volatile organic compound) water-based paint and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2509316A1 (en) * 1981-04-17 1983-01-14 Ceskoslovenska Akademie Ved GRAFT POLYMERIZATION PRODUCTS AND PROCESS FOR THEIR MANUFACTURE
US5136008A (en) * 1990-08-25 1992-08-04 Bayer Aktiengesellschaft Polyurethane containing acryloyl or methacryloyl groups, and a process for their production and their use
US5128432A (en) * 1990-09-01 1992-07-07 Bayer Aktiengesellschaft Aliphatic polyurethanes containing acryloyl groups and a process for their preparation
US5136009A (en) * 1990-09-04 1992-08-04 Bayer Aktiengesellschaft Aliphatic polyurethanes containing acryloyl groups and a process for their preparation
US5247048A (en) * 1991-12-18 1993-09-21 Bayer Aktiengesellschaft Aliphatic polyurethanes containing acryloyl groups and a process for their production
US5300615A (en) * 1992-09-24 1994-04-05 Bayer Aktiengesellschaft Polyurethanes containing acryloyl groups, a process for their preparation and their use as binders for coating compositions
US11518834B2 (en) 2019-01-02 2022-12-06 Polynt Composites USA, Inc. Radically polymerizable compositions
US12071498B2 (en) 2019-01-02 2024-08-27 Polynt Composites USA, Inc. Radically polymerizable compositions
CN117402544A (en) * 2023-11-17 2024-01-16 东莞市瑞盟涂料有限公司 Low-VOC (volatile organic compound) water-based paint and preparation method thereof
CN117402544B (en) * 2023-11-17 2024-04-12 东莞市瑞盟涂料有限公司 Low-VOC (volatile organic compound) water-based paint and preparation method thereof

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee