GB1151185A - New Catalytic System and its application for Polymerisation of Unsaturated Compounds - Google Patents
New Catalytic System and its application for Polymerisation of Unsaturated CompoundsInfo
- Publication number
- GB1151185A GB1151185A GB27218/66A GB2721866A GB1151185A GB 1151185 A GB1151185 A GB 1151185A GB 27218/66 A GB27218/66 A GB 27218/66A GB 2721866 A GB2721866 A GB 2721866A GB 1151185 A GB1151185 A GB 1151185A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- bis
- complex
- cyclooctadiene
- cyclopentadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003197 catalytic effect Effects 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 11
- 239000002253 acid Substances 0.000 abstract 5
- 239000000178 monomer Substances 0.000 abstract 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- 125000000896 monocarboxylic acid group Chemical group 0.000 abstract 4
- 239000011651 chromium Substances 0.000 abstract 3
- 239000004912 1,5-cyclooctadiene Substances 0.000 abstract 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 239000002685 polymerization catalyst Substances 0.000 abstract 2
- WGDFZIZPTGYIME-ZWWVTPAXSA-N (1z,5z)-3,7-dimethylcycloocta-1,5-diene Chemical compound CC\1C\C=C/C(C)C\C=C/1 WGDFZIZPTGYIME-ZWWVTPAXSA-N 0.000 abstract 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 abstract 1
- JMMCOSQOQLCDFY-UHFFFAOYSA-N 3-phenylcycloocta-1,5-diene Chemical compound C1C=CCCC=CC1C1=CC=CC=C1 JMMCOSQOQLCDFY-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 abstract 1
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 abstract 1
- NTPRYYNMCIXYPL-UHFFFAOYSA-N benzene cyclohexa-1,3-diene ruthenium Chemical compound [Ru].C1CC=CC=C1.c1ccccc1 NTPRYYNMCIXYPL-UHFFFAOYSA-N 0.000 abstract 1
- OJVAOSDEEFJACC-UHFFFAOYSA-N benzene cyclopenta-1,3-diene Chemical compound C1=CC=CC1.C1=CC=CC=C1 OJVAOSDEEFJACC-UHFFFAOYSA-N 0.000 abstract 1
- HVURSIGIEONDKB-UHFFFAOYSA-N benzene;chromium Chemical compound [Cr].C1=CC=CC=C1.C1=CC=CC=C1 HVURSIGIEONDKB-UHFFFAOYSA-N 0.000 abstract 1
- KXKURNTZDRVLAJ-UHFFFAOYSA-N benzene;molybdenum Chemical compound [Mo].C1=CC=CC=C1.C1=CC=CC=C1 KXKURNTZDRVLAJ-UHFFFAOYSA-N 0.000 abstract 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 abstract 1
- RTJMWZLRYSYOEK-UHFFFAOYSA-N cyclohepta-1,3,5-triene;tris(oxomethylidene)chromium Chemical compound [Cr].[O+]#[C-].[O+]#[C-].[O+]#[C-].C1C=CC=CC=C1 RTJMWZLRYSYOEK-UHFFFAOYSA-N 0.000 abstract 1
- YDMGJZGUOVJKSO-UHFFFAOYSA-N cyclohexa-1,3-diene cyclopenta-1,3-diene Chemical compound C1=CC=CC1.C1=CC=CCC1 YDMGJZGUOVJKSO-UHFFFAOYSA-N 0.000 abstract 1
- KDUIUFJBNGTBMD-VXMYFEMYSA-N cyclooctatetraene Chemical compound C1=C\C=C/C=C\C=C1 KDUIUFJBNGTBMD-VXMYFEMYSA-N 0.000 abstract 1
- -1 dicarbonyl molybdenum Chemical compound 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 1
- PJANXHGTPQOBST-UHFFFAOYSA-N trans-Stilbene Natural products C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- LLUYQIWDEDDNCZ-UHFFFAOYSA-N tris(oxomethylidene)molybdenum Chemical compound [Mo].[O+]#[C-].[O+]#[C-].[O+]#[C-] LLUYQIWDEDDNCZ-UHFFFAOYSA-N 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR21306A FR1478338A (fr) | 1965-06-17 | 1965-06-17 | Nouveau système catalytique et son application à la polymérisation de composés insaturés |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1151185A true GB1151185A (en) | 1969-05-07 |
Family
ID=8582419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB27218/66A Expired GB1151185A (en) | 1965-06-17 | 1966-06-17 | New Catalytic System and its application for Polymerisation of Unsaturated Compounds |
Country Status (7)
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4690912A (en) * | 1968-08-15 | 1987-09-01 | Monsanto Company | Rhodium-containing carbonylation catalysts with halogen-containing promoter |
| US3709861A (en) * | 1970-12-14 | 1973-01-09 | Shell Oil Co | Process for light-induced curing of epoxy resins in presence of cyclopentadienylmanganese tricarbonyl compounds |
| US3714006A (en) * | 1972-05-15 | 1973-01-30 | W Anderson | Cyclopentadienylmanganese tricarbonyl compounds as a catalyst for the radiation curing of polyepoxides |
| FR2224487B1 (US20100056889A1-20100304-C00004.png) * | 1973-04-05 | 1976-11-12 | Inst Francais Du Petrole | |
| CS175641B1 (en) * | 1973-06-14 | 1977-05-31 | Boris D Babickij | Making method of 2-alkyl-1,3-butadiene's 1,4-transpolymers and/or 2-alkyl-1,3-butadiene's stereoregular 1,4 trans-copolymers with 1,3-butadiene |
| GB1443074A (en) * | 1974-01-14 | 1976-07-21 | Ici Ltd | Olefin polymerisation process |
| US4028271A (en) * | 1975-04-03 | 1977-06-07 | Core-Lube, Inc. | Binding resin for foundry sand and catalyst therefor |
| US4025459A (en) * | 1975-05-14 | 1977-05-24 | Exxon Research And Engineering Company | Noble metal hydrogenation catalysts promoted by fluoride containing acids |
| US4113930A (en) * | 1976-08-02 | 1978-09-12 | Phillips Petroleum Company | Hydrogenated 1,3-cyclohexadiene/1,3-butadiene copolymers |
| US4487847A (en) * | 1983-07-25 | 1984-12-11 | Phillips Petroleum Company | Ethylene dimerization |
| US4681866A (en) * | 1985-04-01 | 1987-07-21 | Phillips Petroleum Company | Polymerization catalyst, method of making and use therefor |
| US4619980A (en) * | 1985-04-01 | 1986-10-28 | Phillips Petroleum Company | Polymerization catalyst, method of making and use therefor |
| US4716205A (en) * | 1985-10-15 | 1987-12-29 | E. I. Du Pont De Nemours And Company | Nickel-catalyzed polymerization of ethylene |
| US5003104A (en) * | 1987-03-03 | 1991-03-26 | Bp Chemicals Limited | Carbonylation process and catalyst |
| US5516739A (en) * | 1990-04-20 | 1996-05-14 | The University Of North Carolina At Chapel Hill | Late transition metal catalysts for the co- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| US5561216A (en) * | 1994-07-01 | 1996-10-01 | University Of North Carolina At Chapel Hill | Late transition metal catalysts for the CO- and terpolymerization of olefin and alkyne monomers with carbon monoxide |
| WO2023140586A1 (ko) * | 2022-01-18 | 2023-07-27 | 주식회사 엘지화학 | 디엔계 고무질 중합체의 제조방법 및 이를 포함하는 그래프트 중합체의 제조방법 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2965627A (en) * | 1956-03-28 | 1960-12-20 | Standard Oil Co | Ethylene polymerization process |
| US3163611A (en) * | 1957-11-07 | 1964-12-29 | Monsanto Co | Method of preparing a modified ziegler polymerization catalyst |
| US3271381A (en) * | 1958-09-15 | 1966-09-06 | Monsanto Co | Polymerization of olefins by use of modified catalysts |
| NL126577C (US20100056889A1-20100304-C00004.png) * | 1963-08-10 | 1900-01-01 | ||
| GB1096347A (en) * | 1964-04-30 | 1967-12-29 | Huels Chemische Werke Ag | Process for the production of mixtures of structurally uniform, high molecular weight 1,4-cis-and 1,4-trans-polybutadienes |
-
1965
- 1965-06-17 FR FR21306A patent/FR1478338A/fr not_active Expired
-
1966
- 1966-06-01 CH CH795166A patent/CH456161A/fr unknown
- 1966-06-15 NL NL6608304A patent/NL6608304A/xx unknown
- 1966-06-16 DE DE19661542231 patent/DE1542231A1/de not_active Withdrawn
- 1966-06-16 BE BE682641D patent/BE682641A/xx unknown
- 1966-06-17 GB GB27218/66A patent/GB1151185A/en not_active Expired
- 1966-06-17 US US558244A patent/US3497488A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NL6608304A (US20100056889A1-20100304-C00004.png) | 1966-12-19 |
| FR1478338A (fr) | 1967-04-28 |
| DE1542231A1 (de) | 1970-04-23 |
| CH456161A (fr) | 1968-05-15 |
| BE682641A (US20100056889A1-20100304-C00004.png) | 1966-12-16 |
| US3497488A (en) | 1970-02-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 416 | Proceeding under section 16 patents act 1949 | ||
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |