GB1150426A - Alkene Oxide Polymerization and Catalyst therefor - Google Patents

Alkene Oxide Polymerization and Catalyst therefor

Info

Publication number
GB1150426A
GB1150426A GB2504066A GB2504066A GB1150426A GB 1150426 A GB1150426 A GB 1150426A GB 2504066 A GB2504066 A GB 2504066A GB 2504066 A GB2504066 A GB 2504066A GB 1150426 A GB1150426 A GB 1150426A
Authority
GB
United Kingdom
Prior art keywords
component
metal
salt
equals
june
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2504066A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US462133A external-priority patent/US3277053A/en
Priority claimed from US462113A external-priority patent/US3396125A/en
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of GB1150426A publication Critical patent/GB1150426A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/22—Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
    • C08G65/24—Epihalohydrins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Polyethers (AREA)

Abstract

1,150,426. Polymerisation catalyst. PHILLIPS PETROLEUM CO. 6 June, 1966 [7 June, 1965], No. 25040/66.' Heading B1E [Also in Division C3] A catalyst composition comprising the product which forms on mixing (a) an organoaluminium compound of the formula R" n AlX m where R" represents a saturated aliphatic, saturated cycloaliphatic or aromatic hydrocarbon radical, each containing up to 20 carbon atoms, or a combination of such radicals, X is hydrogen, fluorine, chlorine, bromine or iodine, n is an integer or 1-3 inclusive, m is 0 or 1 or 2, and n + m equals 3, (b) a salt of a betadiketone being a salt of the formula Me (- O - C (R"') = CH - CO - R'") y where Me is a metal from Group IIA, IIIA, IVA, IB, IIB, IVB, VB, VIB, VIIB, or VIII of the Periodic Table, each R" represents a saturated aliphatic, saturated cycloaliphatic or aromatic radical containing up to 10 carbon atoms, and y equals the valence of the metal Me, and (c) water, the mole ratio of component (c) to component (a) being in the range 0.02:1 to 1.6:1. The metal Me may be Ca, Sr, Ba, Cu, Be, Mg, Zn, Cd, Hg, B, Al, Ga, In, Tl, Ge, Sn, Pb, Ag, V, Or, Mo, W, Mn, Fe, Co, Ni, Zr and Ti. Specific examples of component (a) is tri isobutylaluminium and of component (b) is the acetylacetonate salt of Zn, Cu, Zr, V, Mn, Fe or Co. Other examples are given.
GB2504066A 1965-06-07 1966-06-06 Alkene Oxide Polymerization and Catalyst therefor Expired GB1150426A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US462133A US3277053A (en) 1965-06-07 1965-06-07 Flame and heat resistant polymeric materials containing 2-(bromophenoxy or chlorophenoxy)ethyl and/or propyl acrylates and/or methacrylates
US462113A US3396125A (en) 1965-06-07 1965-06-07 Alkene oxide polymerization

Publications (1)

Publication Number Publication Date
GB1150426A true GB1150426A (en) 1969-04-30

Family

ID=27040236

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2504066A Expired GB1150426A (en) 1965-06-07 1966-06-06 Alkene Oxide Polymerization and Catalyst therefor

Country Status (2)

Country Link
BE (1) BE682131A (en)
GB (1) GB1150426A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000162A (en) * 1977-06-27 1979-01-04 Goodrich Co B F Compositions comprising epihalohydrin co-polymers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2000162A (en) * 1977-06-27 1979-01-04 Goodrich Co B F Compositions comprising epihalohydrin co-polymers
GB2000162B (en) * 1977-06-27 1982-01-27 Goodrich Co B F Compositions comprising epihalohydrin co-polymers

Also Published As

Publication number Publication date
DE1645143B1 (en) 1972-07-13
BE682131A (en) 1966-12-06

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees