GB1148852A - Microporous sheet and method for preparing same - Google Patents

Microporous sheet and method for preparing same

Info

Publication number
GB1148852A
GB1148852A GB20615/67A GB2061567A GB1148852A GB 1148852 A GB1148852 A GB 1148852A GB 20615/67 A GB20615/67 A GB 20615/67A GB 2061567 A GB2061567 A GB 2061567A GB 1148852 A GB1148852 A GB 1148852A
Authority
GB
United Kingdom
Prior art keywords
particles
deposited
diameter
small particles
microns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20615/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co
Original Assignee
WR Grace and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WR Grace and Co filed Critical WR Grace and Co
Publication of GB1148852A publication Critical patent/GB1148852A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/24Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by surface fusion and bonding of particles to form voids, e.g. sintering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/429Natural polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/414Synthetic resins, e.g. thermoplastics or thermosetting resins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

1,148,852. Microporous coated sheet material. W. R. GRACE & CO. 3 May, 1967. [3 May, 1966], No. 20615/67. Heading B2E. A micro porous sheet is prepared by forming on a permeable substrate a micro porous layer of thermoplastic polymer by depositing on the substrate relatively large particles of a thermoplastic polymer and thereafter relatively small particles of a thermoplastic polymer, the small particles having a diameter less than two microns and the large particles having a diameter at least seven times the average diameter of the small particles; sintering the polymer particles either in one stage after both the large and the small particles have been deposited, or in two stages, one stage after the large particles have been deposited and one stage after the small particles have been deposited. The small particles may be from 0.01 to two microns diameter. The large particles may have an average diameter at least 40 times the average diameter of the small particles and may have a diameter of from 15 to 70 microns. The large particles may be deposited in two steps, particle 20 to 170 microns in diameter being deposited in the first step and particles 15 to 70 microns in diameter being deposited in the second step. The particles deposited in the first step may be sintered before the second step. The large particles may be deposited by knife coating, air knife coating, falling curtain coating, fog deposition or by electrostatic deposition. The small particles may be hydraulically deposited from a fog of the particles. The small particles may be deposited with the aid of reduced pressure on the side of the substrate opposite the particles. The large or the small particles or both may be composed of polymers or copolymers of vinyl chlorine, vinylidene chloride, acrylonitrile, acrylates, e.g. vinyl chloridevinyl acetate copolymer. The large or the small particles or both may have been prepared by emulsion or suspension polymerization. The substrate may be a glass mat, a mat of synthetic fibres or a cellulosic sheet which may be impregnated with a phenolformaldehyde resin and may have an average pore aperture of 30 to 35 microns. At least 90% of the pore apertures of the micro porous layer may be from 0.5 to 5 microns in diameter. The micro porous layer may be formed on both 'sides of the permeable substrate. The permeable substrate may be removed from the said microporous layer after the latter has been formed. The micro porous sheet may be used to separate electrodes in a battery.
GB20615/67A 1966-05-03 1967-05-03 Microporous sheet and method for preparing same Expired GB1148852A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US54714766A 1966-05-03 1966-05-03

Publications (1)

Publication Number Publication Date
GB1148852A true GB1148852A (en) 1969-04-16

Family

ID=24183516

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20615/67A Expired GB1148852A (en) 1966-05-03 1967-05-03 Microporous sheet and method for preparing same

Country Status (4)

Country Link
BE (1) BE697896A (en)
CH (1) CH451492A (en)
GB (1) GB1148852A (en)
NL (1) NL6706132A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2440085A1 (en) * 1978-10-27 1980-05-23 Comp Generale Electricite Lead accumulator contg. sepg. membrane of chelating resin - esp. for use in confined environments
EP1047145A1 (en) * 1999-04-22 2000-10-25 NBT GmbH Process for making secondary lithium element with heat-sensitive protective element
US9159979B2 (en) 2008-02-20 2015-10-13 Carl Freudenberg Kg Nonwoven fabric having cross-linking material
EP3704749A4 (en) * 2017-10-30 2021-09-08 Arkema Inc. Lithium ion battery separator

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007042554B4 (en) * 2007-09-07 2017-05-11 Carl Freudenberg Kg Nonwoven with particle filling

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2440085A1 (en) * 1978-10-27 1980-05-23 Comp Generale Electricite Lead accumulator contg. sepg. membrane of chelating resin - esp. for use in confined environments
EP1047145A1 (en) * 1999-04-22 2000-10-25 NBT GmbH Process for making secondary lithium element with heat-sensitive protective element
US6511517B1 (en) 1999-04-22 2003-01-28 Nbt Gmbh Method for producing a secondary lithium cell comprising a heat-sensitive protective mechanism
US9159979B2 (en) 2008-02-20 2015-10-13 Carl Freudenberg Kg Nonwoven fabric having cross-linking material
EP3704749A4 (en) * 2017-10-30 2021-09-08 Arkema Inc. Lithium ion battery separator
US11664558B2 (en) 2017-10-30 2023-05-30 Arkema Inc. Lithium ion battery separator

Also Published As

Publication number Publication date
BE697896A (en) 1967-10-16
NL6706132A (en) 1967-11-06
CH451492A (en) 1968-05-15

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