GB1138995A - Improved surface treatment of synthetic polyester or polyamide shaped articles - Google Patents
Improved surface treatment of synthetic polyester or polyamide shaped articlesInfo
- Publication number
- GB1138995A GB1138995A GB617167A GB617167A GB1138995A GB 1138995 A GB1138995 A GB 1138995A GB 617167 A GB617167 A GB 617167A GB 617167 A GB617167 A GB 617167A GB 1138995 A GB1138995 A GB 1138995A
- Authority
- GB
- United Kingdom
- Prior art keywords
- group
- acid
- reactive
- shaped article
- polymeric compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004952 Polyamide Substances 0.000 title abstract 3
- 229920002647 polyamide Polymers 0.000 title abstract 3
- 229920006149 polyester-amide block copolymer Polymers 0.000 title abstract 3
- 238000004381 surface treatment Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000011734 sodium Substances 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 abstract 2
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 abstract 2
- 229910021595 Copper(I) iodide Inorganic materials 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 125000002843 carboxylic acid group Chemical group 0.000 abstract 1
- LSXDOTMGLUJQCM-UHFFFAOYSA-M copper(i) iodide Chemical compound I[Cu] LSXDOTMGLUJQCM-UHFFFAOYSA-M 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 abstract 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract 1
- QFWPJPIVLCBXFJ-UHFFFAOYSA-N glymidine Chemical compound N1=CC(OCCOC)=CN=C1NS(=O)(=O)C1=CC=CC=C1 QFWPJPIVLCBXFJ-UHFFFAOYSA-N 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 abstract 1
- 235000019799 monosodium phosphate Nutrition 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Inorganic materials [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 abstract 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 abstract 1
- 229940116357 potassium thiocyanate Drugs 0.000 abstract 1
- 229920013730 reactive polymer Polymers 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 abstract 1
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Inorganic materials [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000007669 thermal treatment Methods 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
Abstract
1,138,995. Treating polyester and polyamide materials. IMPERIAL CHEMICAL INDUSTRIES Ltd. 31 May, 1967 [9 Feb., 1967], No. 6171/67. Heading DIP. [Also in Division B2] A shaped article in the form of a filament, fibre, fabric or film, made from a synthetic fibre-forming polyester or polyamide is given a durable modified surface by subjecting it to thermal treatment at a temperature below the melting temperature of the material of the shaped article while it is in intimate contact with a reactive linear polymeric compound which has a molecular weight of at least 600, contains at least one reactive group which is an amine group, carboxylic acid group or a salt or ester thereof or an isocyanate group and at least one surface modifying polymeric group, which is a water-solvatable polyoxyalkylene group, a liquid repellent group containing siloxane or fluorocarbon segments or a group containing a plurality of alcoholic hydroxyl radicals, in the presence of an inorganic catalyst so that the reactive linear polymeric compound is attached chemically to the surface of the shaped article substantially without crosslinking. The inorganic catalyst may be K 4 Fe (CN) 6 , K 3 Fe (CN) 6 , FeSO 4 (NH4) 2 SO 4 , Na 4 Fe (CN) 5 NH 2 , Na 2 Fe (No) (CN) 5 , (NH 4 ) 2 SO 4 , Fe 2 (SO 4 ) 3 , FeSO 4 , iodine, sodium, potassium, lithium or cuprous iodide, hydriodic acid, iodic acid, periodic acid, phosphomolybdic acid, sodium dihydrogen phosphate, potassium thiocyanate, selenium dioxide or potassium dichromate. The treatment may be carried out in the presence of antioxidants, e.g. bis (2-hydiroxy-3-α-methylcyclohexyl-5- methyl-pheriyl)-methane, peroxide decomposers, a dye or optical brightener, At least 1% by weight of the catalyst based on the weight of the reactive polymeric compound may be used.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB617167A GB1138995A (en) | 1967-02-09 | 1967-02-09 | Improved surface treatment of synthetic polyester or polyamide shaped articles |
| LU55398D LU55398A1 (en) | 1967-02-09 | 1968-02-02 | |
| BE710550D BE710550A (en) | 1967-02-09 | 1968-02-08 | |
| FR1559877D FR1559877A (en) | 1967-02-09 | 1968-02-09 | |
| DE19681719357 DE1719357A1 (en) | 1967-02-09 | 1968-02-09 | Process for the treatment of molded articles made of synthetic polyesters or polyamides |
| NL6801845A NL6801845A (en) | 1967-02-09 | 1968-02-09 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB617167A GB1138995A (en) | 1967-02-09 | 1967-02-09 | Improved surface treatment of synthetic polyester or polyamide shaped articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1138995A true GB1138995A (en) | 1969-01-01 |
Family
ID=9809707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB617167A Expired GB1138995A (en) | 1967-02-09 | 1967-02-09 | Improved surface treatment of synthetic polyester or polyamide shaped articles |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE710550A (en) |
| DE (1) | DE1719357A1 (en) |
| FR (1) | FR1559877A (en) |
| GB (1) | GB1138995A (en) |
| LU (1) | LU55398A1 (en) |
| NL (1) | NL6801845A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004206A2 (en) * | 1978-03-15 | 1979-09-19 | Toray Industries, Inc. | Material and method for composite woven or knitted fabric |
| WO2017063038A1 (en) * | 2015-10-14 | 2017-04-20 | Heiq Pty Ltd | Process for providing water repellency |
-
1967
- 1967-02-09 GB GB617167A patent/GB1138995A/en not_active Expired
-
1968
- 1968-02-02 LU LU55398D patent/LU55398A1/xx unknown
- 1968-02-08 BE BE710550D patent/BE710550A/xx unknown
- 1968-02-09 DE DE19681719357 patent/DE1719357A1/en active Pending
- 1968-02-09 NL NL6801845A patent/NL6801845A/xx unknown
- 1968-02-09 FR FR1559877D patent/FR1559877A/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0004206A2 (en) * | 1978-03-15 | 1979-09-19 | Toray Industries, Inc. | Material and method for composite woven or knitted fabric |
| EP0004206A3 (en) * | 1978-03-15 | 1979-10-31 | Toray Industries, Inc. | Material, composition and method for composite woven or knitted fabric |
| WO2017063038A1 (en) * | 2015-10-14 | 2017-04-20 | Heiq Pty Ltd | Process for providing water repellency |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6801845A (en) | 1968-08-12 |
| LU55398A1 (en) | 1968-04-11 |
| BE710550A (en) | 1968-08-08 |
| FR1559877A (en) | 1969-03-14 |
| DE1719357A1 (en) | 1971-08-05 |
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