GB1134580A - 4,5-diphenylimidazole derivatives and methods of manufacture thereof - Google Patents
4,5-diphenylimidazole derivatives and methods of manufacture thereofInfo
- Publication number
- GB1134580A GB1134580A GB4655867A GB4655867A GB1134580A GB 1134580 A GB1134580 A GB 1134580A GB 4655867 A GB4655867 A GB 4655867A GB 4655867 A GB4655867 A GB 4655867A GB 1134580 A GB1134580 A GB 1134580A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxy
- methylbutane
- chlorohydrin
- diphenylimidazole
- taken
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/64—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms, e.g. histidine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,134,580. 4,5 - Diphenylimidazole derivatives. I. KAWAKAMI. 12 Oct., 1967, No, 46558/67. Heading C2C. Novel compounds having the general formula wherein R 1 =H, CH 3 or C 2 H 5 , R 2 =H, CH 3 or C 2 H 5 , R 3 =H, CH 3 , C 2 H; or CH(CH 3 ) 2 and R 4 =H, CH 3 or C 2 H 5 are prepared by reacting 4,5-diphenylimidazole with an easily soluble oxide and an oxide derivative taken from propylene oxide, 1,2-epoxy-2-methylbutane, 1,2- epoxy - 2 - ethylbutane, 1,2 - epoxy - 3 - methylbutane, 2,3 - epoxy - 3 - methylbutane and 2,3 - epoxy - 2,3 - dimethylbutane, in the presence of a tertiary amine taken from the class consisting of triethylamine, tributylamine, ethyldimethylamine, methyldiethylamine, pyridine, N - methylpiperidine and N - ethylpiperidine. The oxide derivative above may be replaced by a 1-halogeno-2-hydroxy compound taken from 1 -chloro-2-methyl-2-butanol, 1 - chloro - 2,5 - dimethyl - 2 - hexanol, butylene chlorohydrin, isobutylene chlorohydrin and pentylene chlorohydrin, and the reaction takes place in the presence of an alkaline substance.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1967K0063850 DE1695339C3 (en) | 1967-11-09 | 1967-11-09 | 4,5-diphenylimidazole compounds |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1134580A true GB1134580A (en) | 1968-11-27 |
Family
ID=7231322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4655867A Expired GB1134580A (en) | 1967-11-09 | 1967-10-12 | 4,5-diphenylimidazole derivatives and methods of manufacture thereof |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1695339C3 (en) |
GB (1) | GB1134580A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4338453A (en) | 1980-09-17 | 1982-07-06 | The Upjohn Company | Aminoalkyl-1,2,4-triazoles |
-
1967
- 1967-10-12 GB GB4655867A patent/GB1134580A/en not_active Expired
- 1967-11-09 DE DE1967K0063850 patent/DE1695339C3/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4338453A (en) | 1980-09-17 | 1982-07-06 | The Upjohn Company | Aminoalkyl-1,2,4-triazoles |
Also Published As
Publication number | Publication date |
---|---|
DE1695339C3 (en) | 1979-04-12 |
DE1695339A1 (en) | 1971-04-08 |
DE1695339B2 (en) | 1978-08-10 |
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