GB1132617A - Electrolytic reduction process using anhydrous electrolyte - Google Patents
Electrolytic reduction process using anhydrous electrolyteInfo
- Publication number
- GB1132617A GB1132617A GB52299/66A GB5229966A GB1132617A GB 1132617 A GB1132617 A GB 1132617A GB 52299/66 A GB52299/66 A GB 52299/66A GB 5229966 A GB5229966 A GB 5229966A GB 1132617 A GB1132617 A GB 1132617A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catholyte
- electrolyte
- regd
- anolyte
- cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
1,132,617. Electrolytic reduction of aromatic nitro compounds. MILES LABORATORIES, Inc. Nov.22, 1966 [Dec.28, 1965], No.52299/66. Heading C7B. Aromatic nitro compounds e.g. nitrobenzene, for instance to form p-aminophenol bisulphate, or p-nitrophenol, are electrolytically reduced in the catholyte compartment of a cell having anolyte and catholyte separated by a diaphragm, the electrolyte in both anolyte and catholyte compartments comprising a substantially anhydrous mixture of acetic acid, at least 15% by weight of phosphoric and/or sulphuric acid and at least 1% by weight of sodium, potassium and/or ammonium acetate. The electrolyte preferably contains not more than 0À6% water. Electrolysis may be carried out using a voltage of 12-24 volts, current density of 1-10 Amps /sq.dm. of cathode area and a temperature of 52-80C. The process could be used to reduce 2, 4-dinitrotoluene or 2, 4, 6 trinitrotoluene. Diaphragms used may be of ceramic composition or of fritted Pyrex (regd. trade mark) glass having pore sizes between 0À1 and 1À4 microns, the anode may be carbon, platinum or lead and the cathode is preferably a Monel (regd. trade mark) metal screen. The cell may be heated in a steam bath prior to imposition of electric current.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51706665A | 1965-12-28 | 1965-12-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1132617A true GB1132617A (en) | 1968-11-06 |
Family
ID=24058220
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB52299/66A Expired GB1132617A (en) | 1965-12-28 | 1966-11-22 | Electrolytic reduction process using anhydrous electrolyte |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1132617A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100529190C (en) * | 2006-11-03 | 2009-08-19 | 华东理工大学 | O-nitrophenol electrolyzing reduction process for preparing O-aminophenol |
-
1966
- 1966-11-22 GB GB52299/66A patent/GB1132617A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100529190C (en) * | 2006-11-03 | 2009-08-19 | 华东理工大学 | O-nitrophenol electrolyzing reduction process for preparing O-aminophenol |
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