GB1126204A - New carbamoylthio derivatives and pesticidal compositions containing them - Google Patents

New carbamoylthio derivatives and pesticidal compositions containing them

Info

Publication number
GB1126204A
GB1126204A GB4446565A GB4446565A GB1126204A GB 1126204 A GB1126204 A GB 1126204A GB 4446565 A GB4446565 A GB 4446565A GB 4446565 A GB4446565 A GB 4446565A GB 1126204 A GB1126204 A GB 1126204A
Authority
GB
United Kingdom
Prior art keywords
carbamoylthio
compound
bis
compounds
derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4446565A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takeda Pharmaceutical Co Ltd
Original Assignee
Takeda Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takeda Chemical Industries Ltd filed Critical Takeda Chemical Industries Ltd
Publication of GB1126204A publication Critical patent/GB1126204A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/02—Monothiocarbamic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/14—Dithiocarbamic acids; Derivatives thereof
    • C07C333/18—Esters of dithiocarbamic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

1,126,204. Carbamoyl thio derivatives. TAKEDA CHEMICAL INDUSTRIES. 20 Oct., 1965 [21 Oct., 1964; 6 Nov., 1964], No. 44465/65. Heading C2C. [Also in Division A5] The invention relates to carbamoyl-thio compounds of the general formula and salts thereof, in which R 1 and R 2 are alkyl groups having up to six carbon atoms or R 1 and R 2 together with the nitrogen atom to which they are attached form a heterocyclic ring. Compounds claimed per se are: 1,3-biscarbamoylthio - 2 - dimethylaminopropane; 2,3 - bis - carbamoylthio - 1 - dimethylaminopropane; 1,3 - bis - carbamoylthio - 2 - piperidinopropane; 1,3 - bis - carbamoylthio - 2 - morpholinopropane. The compounds may be prepared by (A) passing excess hydrogen halide into a solution or suspension of lower aliphatic alcohol containing a compound of formulµ (II) or (II)<SP>1</SP>, then, preferably after heating, distilling off the alcohol from the resultant mixture or (B) by passing excess hydrogen halide into an aqueous solution or suspension containing a compound of Formiµ (II) or (II)<SP>1</SP>, or (c) by dropping a compound of Formulµ (II) or (II)<SP>1</SP> into concentrated sulphuric acid containing from 15 to 20% (V/V) of water, then pouring the mixture into cooled water. The compound obtained is a salt, and it may be converted into the free base in known manner.
GB4446565A 1964-10-21 1965-10-20 New carbamoylthio derivatives and pesticidal compositions containing them Expired GB1126204A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP6001864 1964-10-21
JP6296964 1964-11-06

Publications (1)

Publication Number Publication Date
GB1126204A true GB1126204A (en) 1968-09-05

Family

ID=26401090

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4446565A Expired GB1126204A (en) 1964-10-21 1965-10-20 New carbamoylthio derivatives and pesticidal compositions containing them

Country Status (1)

Country Link
GB (1) GB1126204A (en)

Also Published As

Publication number Publication date
DE1693185A1 (en) 1970-07-23

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