GB1125549A - Coordinated ionic hydrocarbon copolymers - Google Patents
Coordinated ionic hydrocarbon copolymersInfo
- Publication number
- GB1125549A GB1125549A GB3530667A GB3530667A GB1125549A GB 1125549 A GB1125549 A GB 1125549A GB 3530667 A GB3530667 A GB 3530667A GB 3530667 A GB3530667 A GB 3530667A GB 1125549 A GB1125549 A GB 1125549A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymers
- ordinated
- ethylene
- metal ions
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0876—Neutralised polymers, i.e. ionomers
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1,125,549. Co-ordinated ionic copolymers. E.I. DU PONT DE NEMOURS & CO. 1 Aug., 1967 [1 Aug., 1966], No. 35306/67. Headings C3P and C3R. Co-ordinated ionic copolymers comprising a random copolymer of ethylene and at least one C 3-8 α,#-ethylenically unsaturated carboxylic acid in which at least some of the carboxyl groups are ionized by metal ions of valence 1 to 4, at least some of which are co-ordinated by electron donor molecules, said copolymer containing at least 50 mole per cent of ethylene and 0À2 to 25 mole per cent of acid, may be prepared by reacting the ionized polymer or a mixture of polymer and metal salt, molten or in solution, with at least one electron donor compound capable of co-ordinating with the metal ions without substantial rupture of the polymer/ metal bonds. Preferred polymers are copolymers of ethylene, methacrylic acid and optionally vinyl acetate or methyl methacrylate. Preferred metal ions are divalent copper, cobalt, nickel, magnesium and zinc. Preferred donor molecules are those containing oxygen, sulphur and nitrogen, many of which are listed including alkyl, alkylene and heterocyclic amines; amino, thiol and hydroxy aromatic compounds, dyes and polyalkylene imines. Alternatively, the co-ordinating molecule may be covalently bonded to the acid copolymer, e.g. by incorporating therein units of acrylonitrile, 2 - hydroxy - 4 - methacryloxybenzophenone or p-vinylphenyl salicylate. The products are said to have good weathering properties. Examples describe the preparation of co-ordinated copolymers from ethylene/methacrylic acid copolymers ionized with zinc, copper, nickel, cobalt, magnesium, manganese and lead, and co-ordinated with diethylene triamine, triethylene tetramine, tetraethylene pentamine, poly - (ethylene imine), poly - (N - t. - butylethylene imine), purpurin, methyl violet, piperazine, salicylic acid and hexamethylene diamine. The copolymers may also be mixed with fillers containing co-ordinatable metal ions, e.g. asbestos and Wollastonite, and conventional antioxidants such as 4,4<SP>1</SP>-thiobis-(6-t.-butyl-mcresol).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56904566A | 1966-08-01 | 1966-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1125549A true GB1125549A (en) | 1968-08-28 |
Family
ID=24273865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3530667A Expired GB1125549A (en) | 1966-08-01 | 1967-08-01 | Coordinated ionic hydrocarbon copolymers |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE701929A (en) |
| DE (1) | DE1745270A1 (en) |
| GB (1) | GB1125549A (en) |
| NL (1) | NL6710639A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0115190A2 (en) * | 1982-12-28 | 1984-08-08 | E.I. Du Pont De Nemours And Company | Ionomers having improved low temperature properties |
| EP0148632A2 (en) * | 1983-12-22 | 1985-07-17 | E.I. Du Pont De Nemours And Company | Ionomers with improved low temperature flex-crack resistance and improved process economics |
| CN111094435A (en) * | 2017-09-14 | 2020-05-01 | 三井—陶氏聚合化学株式会社 | Resin composition for laminated glass interlayer or solar cell sealing material, laminated glass interlayer, laminated glass, solar cell sealing material, and solar cell module |
-
1967
- 1967-07-27 BE BE701929D patent/BE701929A/xx unknown
- 1967-08-01 DE DE19671745270 patent/DE1745270A1/en active Pending
- 1967-08-01 GB GB3530667A patent/GB1125549A/en not_active Expired
- 1967-08-01 NL NL6710639A patent/NL6710639A/xx unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0115190A2 (en) * | 1982-12-28 | 1984-08-08 | E.I. Du Pont De Nemours And Company | Ionomers having improved low temperature properties |
| EP0115190A3 (en) * | 1982-12-28 | 1984-12-27 | E.I. Du Pont De Nemours And Company | Ionomers having improved low temperature properties |
| EP0148632A2 (en) * | 1983-12-22 | 1985-07-17 | E.I. Du Pont De Nemours And Company | Ionomers with improved low temperature flex-crack resistance and improved process economics |
| EP0148632A3 (en) * | 1983-12-22 | 1986-02-12 | E.I. Du Pont De Nemours And Company | Ionomers with improved low temperature flex-crack resistance and improved process economics |
| CN111094435A (en) * | 2017-09-14 | 2020-05-01 | 三井—陶氏聚合化学株式会社 | Resin composition for laminated glass interlayer or solar cell sealing material, laminated glass interlayer, laminated glass, solar cell sealing material, and solar cell module |
| US20200277418A1 (en) * | 2017-09-14 | 2020-09-03 | Dow-Mitsui Polychemicals Co., Ltd. | Resin composition for laminated glass interlayer film or solar cell encapsulant, laminated glass interlayer film, laminated glass, solar cell encapsulant, and solar cell module |
| EP3683266A4 (en) * | 2017-09-14 | 2021-05-26 | Dow-Mitsui Polychemicals Co., Ltd. | Resin composition for laminated glass interlayer film or solar cell encapsulant, laminated glass interlayer film, laminated glass, solar cell encapsulant, and solar cell module |
| US11628651B2 (en) * | 2017-09-14 | 2023-04-18 | Dow-Mitsui Polychemicals Co., Ltd. | Resin composition for laminated glass interlayer film or solar cell encapsulant, laminated glass interlayer film, laminated glass, solar cell encapsulant, and solar cell module |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1745270A1 (en) | 1971-08-12 |
| NL6710639A (en) | 1968-02-02 |
| BE701929A (en) | 1968-01-02 |
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