GB1122090A - Oxidation of paraffins to secondary aliphatic alcohols - Google Patents
Oxidation of paraffins to secondary aliphatic alcoholsInfo
- Publication number
- GB1122090A GB1122090A GB39530/66A GB3953066A GB1122090A GB 1122090 A GB1122090 A GB 1122090A GB 39530/66 A GB39530/66 A GB 39530/66A GB 3953066 A GB3953066 A GB 3953066A GB 1122090 A GB1122090 A GB 1122090A
- Authority
- GB
- United Kingdom
- Prior art keywords
- paraffin
- carbon atoms
- boric acid
- secondary alcohol
- aqueous boric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 aliphatic alcohols Chemical group 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 7
- 239000012188 paraffin wax Substances 0.000 abstract 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 4
- 239000004327 boric acid Substances 0.000 abstract 4
- 150000002148 esters Chemical class 0.000 abstract 3
- 150000003333 secondary alcohols Chemical class 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 229910052796 boron Inorganic materials 0.000 abstract 2
- 239000006227 byproduct Substances 0.000 abstract 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 abstract 2
- 230000007062 hydrolysis Effects 0.000 abstract 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract 2
- 230000003301 hydrolyzing effect Effects 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- LGQXXHMEBUOXRP-UHFFFAOYSA-N tributyl borate Chemical compound CCCCOB(OCCCC)OCCCC LGQXXHMEBUOXRP-UHFFFAOYSA-N 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- BRTALTYTFFNPAC-UHFFFAOYSA-N boroxin Chemical compound B1OBOBO1 BRTALTYTFFNPAC-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000011133 lead Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
- C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US485564A US3375265A (en) | 1965-09-07 | 1965-09-07 | Production of trialkoxyboroxine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1122090A true GB1122090A (en) | 1968-07-31 |
Family
ID=23928642
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB39530/66A Expired GB1122090A (en) | 1965-09-07 | 1966-09-05 | Oxidation of paraffins to secondary aliphatic alcohols |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3375265A (enExample) |
| BE (1) | BE686456A (enExample) |
| DE (1) | DE1593424A1 (enExample) |
| GB (1) | GB1122090A (enExample) |
| NL (1) | NL6612501A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2140252A1 (es) * | 1995-01-11 | 2000-02-16 | Repsol Quimica Sa | Un procedimiento para la obtencion de fibras cortas y largas y sus telas de entrecruzamiento quimico por centrifugacion, estirado o extrusion de soles obtenidos mediante hidrolisis controlada de disoluciones de alcoxidos metalicos. |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3524893A (en) * | 1967-12-22 | 1970-08-18 | Texaco Inc | Secondary alcohol manufacture |
| US3622647A (en) * | 1969-09-11 | 1971-11-23 | Texaco Inc | Manufacture of alkene from alkane via boron esters |
| CN101993451A (zh) * | 2005-06-13 | 2011-03-30 | 巴斯夫欧洲公司 | 合成二烷氧基有机硼烷的方法 |
| US10479748B2 (en) | 2017-11-30 | 2019-11-19 | Cambridge Enterprise Limited | Oxidation of C1-9-alkanes |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB939534A (en) * | 1960-11-09 | 1963-10-16 | Ici Ltd | Improvements in and relating to the preparation of oxidation products of hydrocarbons |
| GB1035624A (en) * | 1961-12-07 | 1966-07-13 | Ici Ltd | Improvements in and relating to the preparation of alcohols |
| NL273572A (enExample) * | 1962-01-15 | |||
| US3232704A (en) * | 1962-03-21 | 1966-02-01 | Exxon Research Engineering Co | Process for recovering boric acid |
-
1965
- 1965-09-07 US US485564A patent/US3375265A/en not_active Expired - Lifetime
-
1966
- 1966-09-05 BE BE686456D patent/BE686456A/xx unknown
- 1966-09-05 GB GB39530/66A patent/GB1122090A/en not_active Expired
- 1966-09-05 DE DE19661593424 patent/DE1593424A1/de active Pending
- 1966-09-06 NL NL6612501A patent/NL6612501A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2140252A1 (es) * | 1995-01-11 | 2000-02-16 | Repsol Quimica Sa | Un procedimiento para la obtencion de fibras cortas y largas y sus telas de entrecruzamiento quimico por centrifugacion, estirado o extrusion de soles obtenidos mediante hidrolisis controlada de disoluciones de alcoxidos metalicos. |
Also Published As
| Publication number | Publication date |
|---|---|
| US3375265A (en) | 1968-03-26 |
| BE686456A (enExample) | 1967-03-06 |
| NL6612501A (enExample) | 1967-03-08 |
| DE1593424A1 (de) | 1970-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1122090A (en) | Oxidation of paraffins to secondary aliphatic alcohols | |
| US2236919A (en) | Process for the production of polyhydric alcohols and derivatives thereof | |
| GB1155022A (en) | Hydroxymethane Carboxylic Acid Esters and process for their manufacture | |
| GB911290A (en) | Process for the production of esters and carboxylates of alkyl boric acids | |
| GB1035624A (en) | Improvements in and relating to the preparation of alcohols | |
| ES316221A1 (es) | Procedimiento para la obtencion de alcoholes alifaticos. | |
| US3194834A (en) | Process of oxidation of organoboranes | |
| GB939534A (en) | Improvements in and relating to the preparation of oxidation products of hydrocarbons | |
| GB1254331A (en) | Paints | |
| GB1530180A (en) | Process for the preparation of triarylborane | |
| GB911522A (en) | Preparation of aluminium trialkoxide compounds | |
| ES486377A1 (es) | Procedimiento para la preparacion de 5-mercapto-1,2,3-tria- zoles | |
| ES8106490A1 (es) | Procedimiento de preparacion de acido percarboxilico | |
| GB910925A (en) | Production of esters | |
| GB821388A (en) | Method of preparing alkali metal hypophosphites | |
| GB1386508A (en) | Process for protolytic reaction of trialkylboranes with acidic hydrogen containing compounds | |
| Skrydstrup et al. | A new and convenient benzyloxyalkylating agent induced by samarium diiodide | |
| GB972656A (en) | Improvements in the production of adipic acid | |
| ES347126A1 (es) | Procedimiento para la preparacion de boratos de alcohol. | |
| GB971060A (en) | Process for n, n-dialkylhydroxylamines | |
| GB997348A (en) | Production of aliphatic dicarboxylic acids | |
| GB576027A (en) | Improvements in and relating to the production of acetals | |
| GB1147693A (en) | Process for the production of mixtures of cycloalkanols and cycloalkanones by oxidation of cycloaliphatic c-to c-hydrocarbons | |
| GB1388694A (en) | Method of manufacturing alkylene oxide adducts of an aliphatic alcohol | |
| GB840866A (en) | Chemical process for the production of esters of carbamic and carbonic acids |