GB1119949A - Adhesive mixtures based on polyvinyl chloride - Google Patents

Adhesive mixtures based on polyvinyl chloride

Info

Publication number
GB1119949A
GB1119949A GB30494/67A GB3049467A GB1119949A GB 1119949 A GB1119949 A GB 1119949A GB 30494/67 A GB30494/67 A GB 30494/67A GB 3049467 A GB3049467 A GB 3049467A GB 1119949 A GB1119949 A GB 1119949A
Authority
GB
United Kingdom
Prior art keywords
uretdione
pvc
adhesive
polyester
diisocyanate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30494/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1119949A publication Critical patent/GB1119949A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
    • C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J127/04—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09J127/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/798—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

An adhesive comprises polyvinyl chloride, a plasticizer, a polyester capable of reacting with an isocyanate and a polymer of a polyisocyanate having at least one uretdione ring. Dioctyl phthalate is specified as plasticizer; the polyester may be derived from adipic acid and 1,6-hexane diol or butane diol with or without trimethylolpropane, and the uretdione may be obtained from toluylene - 2,4 - diisocyanate, toluene - 2,4,6 - triisocyanate, or diphenyl-methane - 4,41 - diisocyanate. There may also be present a catalyst for the decomposition of the uretdione, e.g. dibutyl tin oxide, stannous octoate, zinc adipate, triethyl phosphine, pyridine, triethylene diamine, or titanium hydroxy chloride. Diphenyl thiourea may be added as a stabilizer. The adhesive is used to bond a fibrous material, e.g. rayon, polyamide or polyester textiles, to PVC. The adhesive is spread on the textile, heated to 120-160 DEG C. to pregelatinize, spread with a PVC paste and gelatinized by heating to 160-190 DEG C. In one example, both sides of a textile are so coated with PVC.ALSO:An adhesive comprises polyvinyl chloride, a plasticiser, a polyester capable of reacting with an isocyanate and a polymer of a polyisocyanate having at least one uretdione ring. Dioctyl phthalate is specified as plasticiser; the polyester may be derived from adipic acid and 1, 6-hexane diol or butane diol with or without trimethylolpropane, and the uretdione may be obtained from toluylene-2, 4-diisocyanate, toluene-2, 4, 6-triisocyanate, or diphenylmethane-4, 4\sv-diisocyanate. There may also be present a catalyst for the decomposition of the uretdione, e.g. dibutyl tin oxide, stannous octoate, zine adipate, triethyl phosphine, pyridine, triethylene diamine, or titanium hydroxy chloride. Diphenyl thiourea may be added as a stabiliser. The adhesive is used to bond a fibrous material e.g., rayon, polyamide or polyester textiles, to PVC. The adhesive is spread on the textile, heated to 120-160 DEG C to pregelatinise, spread with a PVC paste and gelatinised by heating to 160-190 DEG C. In one example both sides of a textile are so coated with PVC.
GB30494/67A 1966-07-02 1967-07-03 Adhesive mixtures based on polyvinyl chloride Expired GB1119949A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0049607 1966-07-02

Publications (1)

Publication Number Publication Date
GB1119949A true GB1119949A (en) 1968-07-17

Family

ID=7103146

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30494/67A Expired GB1119949A (en) 1966-07-02 1967-07-03 Adhesive mixtures based on polyvinyl chloride

Country Status (1)

Country Link
GB (1) GB1119949A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2383212A1 (en) * 1977-03-10 1978-10-06 Lankro Chem Ltd PLASTICIZING COMPOSITION FOR PLASTICIZING SYNTHETIC RESIN POLYMERS, ESPECIALLY POLYVINYL CHORIDE
US5929153A (en) * 1994-12-15 1999-07-27 Tosoh Corporation Vinyl chloride-based polymer-polyurethane composite and method of producing the same
WO2015059509A1 (en) * 2013-10-23 2015-04-30 ZAPATA CUELLAR, Diego Fernando Adhesive mixture, use and adhesive material
FR3063080A1 (en) * 2017-02-23 2018-08-24 Bostik Sa COMPOSITION COMPRISING A POLYESTER AND ACTIVATED ADHESIVE FILM AT LOW TEMPERATURE
CN112300519A (en) * 2020-11-12 2021-02-02 广元瑞峰新材料有限公司 MDI-DINP-based PVC cross-linking agent and PVC cross-linked material thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2383212A1 (en) * 1977-03-10 1978-10-06 Lankro Chem Ltd PLASTICIZING COMPOSITION FOR PLASTICIZING SYNTHETIC RESIN POLYMERS, ESPECIALLY POLYVINYL CHORIDE
US5929153A (en) * 1994-12-15 1999-07-27 Tosoh Corporation Vinyl chloride-based polymer-polyurethane composite and method of producing the same
WO2015059509A1 (en) * 2013-10-23 2015-04-30 ZAPATA CUELLAR, Diego Fernando Adhesive mixture, use and adhesive material
FR3063080A1 (en) * 2017-02-23 2018-08-24 Bostik Sa COMPOSITION COMPRISING A POLYESTER AND ACTIVATED ADHESIVE FILM AT LOW TEMPERATURE
WO2018154246A1 (en) * 2017-02-23 2018-08-30 Bostik Sa Adhesive film activatable at low temperature
US11279860B2 (en) 2017-02-23 2022-03-22 Bostik Sa Adhesive film activatable at low temperature
CN112300519A (en) * 2020-11-12 2021-02-02 广元瑞峰新材料有限公司 MDI-DINP-based PVC cross-linking agent and PVC cross-linked material thereof

Similar Documents

Publication Publication Date Title
GB1060754A (en) Improvements relating to pressure sensitive adhesives
GB1261313A (en) A method for the production of a coating agent
IE36072L (en) Pulverous coating composition
GB981642A (en) Method of making vapor permeable sheet materials
GB1495980A (en) Production of sheet structures comprising polyethylene and polyurethane foam layers
DE59104909D1 (en) SEALING AND ADHESIVE BASED ON POLYURETHANES WITH SPECIAL SOFTENERS.
GB1119949A (en) Adhesive mixtures based on polyvinyl chloride
GB1316893A (en) Adhesive preparations
GB1034701A (en) Process for the production of synthetic plastics from vinyl or vinylidene polymers and polyurethanes
GB1408945A (en) Preparing polyurethanes
US3398014A (en) Process for manufacture of stabilized pressure sensitive adhesive
GB1274925A (en) Flame-resistant textile fabrics
GB1166571A (en) Coating Composition, Coated Article and method for making a Coated Article
GB1376863A (en) Fireretardant polyurethanes and polyureas
GB1494686A (en) Process for the production of polyurethane solutions
GB1530909A (en) Polyurethane foam
GB1091200A (en) Production of shaped articles including sheets
GB703153A (en) Improvements in and relating to articles of clothing impervious to x-rays and beta-rays
GB1142502A (en) Adhesive compositions
US3788882A (en) Synthetic composite and process for preparing
GB1015419A (en) A process for the production of highly elastic fibres and films
GB1409682A (en) Production of microporous film or sheet
GB1118724A (en) A process for the production of a coating composition
GB962186A (en) Polyurethane elastic threads
GB1208544A (en) Improvements in or relating to laminated materials