GB1119630A - Process for the preparation of organotrisiloxanes - Google Patents
Process for the preparation of organotrisiloxanesInfo
- Publication number
- GB1119630A GB1119630A GB29433/67A GB2943367A GB1119630A GB 1119630 A GB1119630 A GB 1119630A GB 29433/67 A GB29433/67 A GB 29433/67A GB 2943367 A GB2943367 A GB 2943367A GB 1119630 A GB1119630 A GB 1119630A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resins
- mixture
- organo
- formula
- mols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 abstract 4
- 229920005989 resin Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- ZPLCXHWYPWVJDL-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)methyl]-1,3-oxazolidin-2-one Chemical compound C1=CC(O)=CC=C1CC1NC(=O)OC1 ZPLCXHWYPWVJDL-UHFFFAOYSA-N 0.000 abstract 1
- 229920000178 Acrylic resin Polymers 0.000 abstract 1
- 239000004925 Acrylic resin Substances 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- -1 hydrocarbons aliphatic ethers Chemical class 0.000 abstract 1
- 229910052752 metalloid Inorganic materials 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 125000002524 organometallic group Chemical group 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 239000005052 trichlorosilane Substances 0.000 abstract 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0874—Reactions involving a bond of the Si-O-Si linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Organotrisiloxanes of the general formula <FORM:1119630/C3/1> where R1, R2 and R3 can be substituted or unsubstituted, saturated or olefinically or aromatically unsaturated hydrocarbon radicals and R represents an alkyl, cycloalkyl, aryl, aralkyl or an alkoxyalkyl radical, are prepared by (a) reacting a mixture, in an inert organic medium, of a diorganodichlorosilane of the formula R2R3SiCl2 and an organotrichlorosilane of the formula R1SiCl3 in a molar ratio of 2:1, with a mixture of water and a compound ROH in a molar ratio of 2 mols. of water and 3-20 mols. of ROH per mol. of the organo-trichlorosilane, (b) neutralizing the product to bromothymol blue with ammonia and (c) isolating the trisiloxane. The optimal concentration of the silane mixture is 40-80% by wt. based on the total weight of mixture. Inert organic medians include the usual aromatic aliphatic and cycloaliphatic hydrocarbons aliphatic ethers. The products may be used to produce mixed organosilicon resins by reaction with polyesters, epoxy resins, melamine-formaldehyde resins, ureaformaldehyde resins, alkyd resins, polyethers, phenol-formadehyde resins, cellulosic resins, polyurethanes or acrylic resins; or cohydrolysed and copolymerized with other organosilicon, organo-metallic and organo-metalloid monomers. The can be rearranged with organocyclopolysiloxanes or organopolysiloxanes in the presence of a suitable catalyst or used as additives in hot-vulcanized elastomers, as plasticizers or modifiers.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR67108A FR1491412A (en) | 1966-06-27 | 1966-06-27 | Process for preparing organotrisiloxanes |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1119630A true GB1119630A (en) | 1968-07-10 |
Family
ID=8611890
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB29433/67A Expired GB1119630A (en) | 1966-06-27 | 1967-06-26 | Process for the preparation of organotrisiloxanes |
Country Status (3)
Country | Link |
---|---|
ES (1) | ES342354A1 (en) |
FR (1) | FR1491412A (en) |
GB (1) | GB1119630A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09132718A (en) * | 1995-11-08 | 1997-05-20 | Toray Dow Corning Silicone Co Ltd | Two-pack type curing liquid silicon composition |
-
1966
- 1966-06-27 FR FR67108A patent/FR1491412A/en not_active Expired
-
1967
- 1967-06-26 GB GB29433/67A patent/GB1119630A/en not_active Expired
- 1967-06-27 ES ES342354A patent/ES342354A1/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
FR1491412A (en) | 1967-08-11 |
ES342354A1 (en) | 1968-07-16 |
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