GB1115627A - Curable interpolymers - Google Patents
Curable interpolymersInfo
- Publication number
- GB1115627A GB1115627A GB2407966A GB2407966A GB1115627A GB 1115627 A GB1115627 A GB 1115627A GB 2407966 A GB2407966 A GB 2407966A GB 2407966 A GB2407966 A GB 2407966A GB 1115627 A GB1115627 A GB 1115627A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bicycloheptadiene
- propylene
- ethylene
- monomers
- interpolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
An interpolymer of at least one monoolefin and a multi-unsaturated hydrocarbon, at least part of said hydrocarbon being bicyclo-[2.2.1]-hepta-2, 5-diene, and which is soluble in hydrocarbons, has an intrinsic viscosity in benzene at 25 DEG C. no higher than 0.4, and sufficient ethylenically unsaturated groups in the polymer molecule to permit substantial curing of films by oxidative mechanism is made by copolymerizing the monomers in the absence of oxygen in the presence of a Ziegler-type catalyst containing a transition metal. The Specification contains long lists of monomers. Exemplified monomers are mixtures of (1) ethylene, propylene, dicyclopentadiene, and bicycloheptadiene, and (2) ethylene, propylene, and bicycloheptadiene. The polymerization and recovery of the copolymers is carried out by conventional "low-pressure" methods. Molecular weight regulators such as hydrogen and dialkyl zinc may be present.ALSO:Substrates made of metals, wood glass, and plastics, are coated with a composition comprising an interpolymer of at least one monoolefin and a multi-unsaturated hydrocarbon of which at least part is bicyclo [2.2.1] hepta-2, 5-diene, and which is soluble in hydrocarbons, has an intrinsic viscosity in benzene at 25 DEG C no higher than 0.4, and is curably by an oxidative mechanism. The compositions may be solutions or dispersions in organic solvents, or water-containing emulsions. The interpolymers may be air-cured at room or elevated temperatures, and the curing may be assisted by metal driers. The substrate may be made of iron, steel, aluminium, copper, nickel, tin, wood, glass, or polyesters. In the examples interpolymers of ethylene, propylene, bicycloheptadiene, and optionally dicyclopentadiene, are coated on phosphatized steel panels and cured.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US46054465A | 1965-06-01 | 1965-06-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1115627A true GB1115627A (en) | 1968-05-29 |
Family
ID=23829143
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2407966A Expired GB1115627A (en) | 1965-06-01 | 1966-05-31 | Curable interpolymers |
Country Status (2)
Country | Link |
---|---|
CH (1) | CH465238A (en) |
GB (1) | GB1115627A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3000726A1 (en) | 1979-01-09 | 1980-07-17 | Exxon Research Engineering Co | LUBRICANTS |
-
1966
- 1966-05-31 GB GB2407966A patent/GB1115627A/en not_active Expired
- 1966-06-01 CH CH798966A patent/CH465238A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3000726A1 (en) | 1979-01-09 | 1980-07-17 | Exxon Research Engineering Co | LUBRICANTS |
Also Published As
Publication number | Publication date |
---|---|
CH465238A (en) | 1968-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2625523A (en) | Polymer composition and process of preparing same | |
KR960014182A (en) | Thermally Polymerized Dicyclopentadiene / Vinyl Aromatic Resins | |
KR900000432A (en) | Multi-component coating compositions composed of anhydride containing polymers, glycidyl components and self-stabilized, dispersed resins and substrates coated therewith | |
JPH02170884A (en) | Ultraviolet-crosslinking composition composed mainly of isoamyl (meth) acrylate copolymer | |
US3175024A (en) | Polymers of acrylic esters of salicyloylbenzoylmethane | |
KR900000434A (en) | Multicomponent Coating Composition | |
US3247012A (en) | Process of coating the exterior surface of articles with a polymerizable coating material subjected to high energy ionizing irradiation | |
US2951831A (en) | Terpolymer of a conjugated diolefin, a styrene, and an allyl alcohol | |
McNeill et al. | Degradation of polymer mixtures. IX. Blends of polystyrene with polybutadiene | |
JPS6231022B2 (en) | ||
GB1115627A (en) | Curable interpolymers | |
GB1527154A (en) | Unsaturated epoxides as coupling agents for carbon fibres and unsaturated matrix resins | |
GB1098677A (en) | Interpolymers | |
Agrawal et al. | Effect of diluents on the curing behavior of vinyl ester resin | |
US3048562A (en) | Process for oxidizing polymeric butadiene drying oil in the presence of steam-cracked petroleum resin, and resulting product | |
GB850894A (en) | Improvements in or relating to the production of diolefin polymers | |
US3159597A (en) | Cross-linked adhesive of a vinyl polymer and a polymethylol bis-phenol | |
US2856309A (en) | Unsaturated hydrocarbon drying oils containing a hardening agent and a process of making them | |
US2513243A (en) | Polymers from the cyclic dimers of diolefines | |
US3582520A (en) | Stabilization of unsaturated interpolymers | |
GB1115628A (en) | Interpolymers | |
JPS54150492A (en) | Production of copolymer resin | |
US3816559A (en) | Solid,curable compositions containing oxoalkyl acrylamides | |
GB1310054A (en) | Method for the manufacture of soluble organic copolymers and their use in reaction lacquers | |
US2549558A (en) | Asphalt resin compositions |