GB1114455A - Process for the polymerization of ª‡-olefinic hydrocarbon material and catalyst there for - Google Patents

Process for the polymerization of ª‡-olefinic hydrocarbon material and catalyst there for

Info

Publication number
GB1114455A
GB1114455A GB3727065A GB3727065A GB1114455A GB 1114455 A GB1114455 A GB 1114455A GB 3727065 A GB3727065 A GB 3727065A GB 3727065 A GB3727065 A GB 3727065A GB 1114455 A GB1114455 A GB 1114455A
Authority
GB
United Kingdom
Prior art keywords
diphenyl
halide
olefines
tetraphenyl
hydrocarbon containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3727065A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US398051A priority Critical patent/US3340244A/en
Application filed filed Critical
Priority to GB3727065A priority patent/GB1114455A/en
Priority to FR31449A priority patent/FR1446905A/en
Publication of GB1114455A publication Critical patent/GB1114455A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

A polymerization catalyst for alpha-olefines is formed from 91) at elast one organoaluminium halide of the formula RmAIXn or R2 Al2X3 where R represents an alkyl, cycloakyl, phenyl, or tolyl group, X represents Cl or Br and M + n equals 3, (2 a halide, alkoxy halide or alkoxide of a transition metal from Group IVB, VB, or VIB of the Periodic Table, and (3) a monocyclic aliphatic hydrocarbon containing from 7 to 16 carbon atoms and having at least three ethylenic bonds in the ring or a phenyl substituted acyclic straight chain hydrocarbon containing at least three ethylenic bonds, or a polybutadiene having a molecular weight of from 500 to 5,000, e.g. 1,5-9-cycloheptatriene, benzene soluble 1,2- and 1,4-polybutadienes, tetraphenyl-1,2,3-butatriene tetraphenyl-1,2,3,4,5-hexapentaene, 1,6 - diphenyl -1,3,5 - hexatriene, 1,8-diphenyl octatetraene, and 1,16-diphenyl hexadecaoctaene. Exemplified olefines are propylene, 4-methyl-1-pentene, butene-1, vinylcyclohexane and styrene.
GB3727065A 1964-09-21 1965-09-01 Process for the polymerization of ª‡-olefinic hydrocarbon material and catalyst there for Expired GB1114455A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US398051A US3340244A (en) 1964-09-21 1964-09-21 Organo aluminum halide catalysts and polymerization processes employing same
GB3727065A GB1114455A (en) 1965-09-01 1965-09-01 Process for the polymerization of ª‡-olefinic hydrocarbon material and catalyst there for
FR31449A FR1446905A (en) 1965-09-01 1965-09-15 Catalyst containing a halogenated organic derivative of aluminum and process for the polymerization of alpha-ethylenic hydrocarbons using this new catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3727065A GB1114455A (en) 1965-09-01 1965-09-01 Process for the polymerization of ª‡-olefinic hydrocarbon material and catalyst there for

Publications (1)

Publication Number Publication Date
GB1114455A true GB1114455A (en) 1968-05-22

Family

ID=10395104

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3727065A Expired GB1114455A (en) 1964-09-21 1965-09-01 Process for the polymerization of ª‡-olefinic hydrocarbon material and catalyst there for

Country Status (1)

Country Link
GB (1) GB1114455A (en)

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