GB1112563A - Alkali metal aluminium hydrides,methods of making them,reduction methods employing them and polymerization catalysts containing them - Google Patents

Alkali metal aluminium hydrides,methods of making them,reduction methods employing them and polymerization catalysts containing them

Info

Publication number
GB1112563A
GB1112563A GB2606265A GB2606265A GB1112563A GB 1112563 A GB1112563 A GB 1112563A GB 2606265 A GB2606265 A GB 2606265A GB 2606265 A GB2606265 A GB 2606265A GB 1112563 A GB1112563 A GB 1112563A
Authority
GB
United Kingdom
Prior art keywords
alkali metal
butene
methyl
alcohol
mal2h7
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2606265A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US384514A external-priority patent/US3380985A/en
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1112563A publication Critical patent/GB1112563A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
    • C01B6/243—Hydrides containing at least two metals; Addition complexes thereof containing only hydrogen, aluminium and alkali metals, e.g. Li(AlH4)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation
    • C07C37/07—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by conversion of non-aromatic six-membered rings or of such rings formed in situ into aromatic six-membered rings, e.g. by dehydrogenation with simultaneous reduction of C=O group in that ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

a -olefins are polymerized by conventional low pressure techniques in the presence of a catalyst comprising a compound MAl2H7 where M = alkali metal, a halide of a Group IVB, VB or VIB metal with a valency one less than maximum and, optionally as a third component, an alkali metal hydride or a Group II metal oxide. Monomers exemplified are ethylene, propylene, butene-1, heptene-1, decene-1, 3 methyl - 1 - butene, 4 methyl - 1 - butene, styrene, a - methyl - 1 - butene, 4 - methyl - 1 - hexene, 5 - methyl - 1 - hexene, 4,4-dimethyl - 1 - butene, allylcyclohexene allylcyclobutene, allylbenzene; the copolymerization of propylene and butene-1 is described in Examples 14 and 15.ALSO:The invention comprises compounds of the formula MAl2H7 where M is an alkali metal. LiAlH7 and NaAlH7 are exemplified. The compounds of the invention may be prepared by contacting a hydride R2AlH, where R is a hydrocarbon radical free of non-aromatic unsaturation, with an alkali metal hydride MH in molar ratio 2 : 1 to 1 : 2 in an inert solvent at 25-200 DEG C. under N2 and recovering crystalline MAl2H7.ALSO:Alkali metal dialuminium heptahydrides, MAl2H7 (see Division Cl) may be used as reducing agents in hydrocarbon solution at - 80 DEG to 150 DEG C. for the functional groups of ketones, aldehydes, carboxylic acids and esters, nitriles and nitro compounds, usually without reduction of any olefinic double bonds present. Examples of starting materials and products are as follows: .Starting material.Product .Isobutyraldehyde.Isobutyl alcohol .Crotonaldehyde.Crotyl alcohol .Benzaldehyde.Benzyl alcohol .Isobutyl isobutyrate.Isobutyl alcohol .Phthallic anhydride.Phthalyl alcohol .Benzoyl chloride.Benzyl alcohol .Acetone.Isopropyl alcohol .Quinone.Hydroquinone .Cyclohexanone.Cyclohexanol .Nitrobenzene.Azobenzene .Phenylacetonitrile.b -Phenylethylamine
GB2606265A 1964-07-22 1965-06-21 Alkali metal aluminium hydrides,methods of making them,reduction methods employing them and polymerization catalysts containing them Expired GB1112563A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US384514A US3380985A (en) 1964-07-22 1964-07-22 Alkali-metal-containing catalyst and polymerization process employing same
US41609764A 1964-12-04 1964-12-04

Publications (1)

Publication Number Publication Date
GB1112563A true GB1112563A (en) 1968-05-08

Family

ID=27010633

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2606265A Expired GB1112563A (en) 1964-07-22 1965-06-21 Alkali metal aluminium hydrides,methods of making them,reduction methods employing them and polymerization catalysts containing them

Country Status (2)

Country Link
DE (2) DE1259892B (en)
GB (1) GB1112563A (en)

Also Published As

Publication number Publication date
DE1567476A1 (en) 1970-08-06
DE1259892B (en) 1968-02-01

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