GB1111413A - Making adiponitrile and like compounds by reductive dimerisation - Google Patents
Making adiponitrile and like compounds by reductive dimerisationInfo
- Publication number
- GB1111413A GB1111413A GB49714/64A GB4971464A GB1111413A GB 1111413 A GB1111413 A GB 1111413A GB 49714/64 A GB49714/64 A GB 49714/64A GB 4971464 A GB4971464 A GB 4971464A GB 1111413 A GB1111413 A GB 1111413A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphate
- anolyte
- mercury
- acrylonitrile
- cationic agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title 1
- 230000002829 reductive effect Effects 0.000 title 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 3
- 125000002091 cationic group Chemical group 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 3
- 229910052753 mercury Inorganic materials 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 3
- 239000010452 phosphate Substances 0.000 abstract 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- 239000002585 base Substances 0.000 abstract 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 2
- QKFFSWPNFCXGIQ-UHFFFAOYSA-M 4-methylbenzenesulfonate;tetraethylazanium Chemical compound CC[N+](CC)(CC)CC.CC1=CC=C(S([O-])(=O)=O)C=C1 QKFFSWPNFCXGIQ-UHFFFAOYSA-M 0.000 abstract 1
- 229910000497 Amalgam Inorganic materials 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001447 alkali salts Chemical class 0.000 abstract 1
- 229910021538 borax Inorganic materials 0.000 abstract 1
- 238000001311 chemical methods and process Methods 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 150000004714 phosphonium salts Chemical class 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 229910000162 sodium phosphate Inorganic materials 0.000 abstract 1
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 1
- 238000000638 solvent extraction Methods 0.000 abstract 1
- -1 sulphonium compound Chemical class 0.000 abstract 1
- UQFSVBXCNGCBBW-UHFFFAOYSA-M tetraethylammonium iodide Chemical compound [I-].CC[N+](CC)(CC)CC UQFSVBXCNGCBBW-UHFFFAOYSA-M 0.000 abstract 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
- C25B3/295—Coupling reactions hydrodimerisation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Hydrogenated Pyridines (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB49714/64A GB1111413A (en) | 1964-12-07 | 1964-12-07 | Making adiponitrile and like compounds by reductive dimerisation |
| NL6515603A NL6515603A (enrdf_load_html_response) | 1964-12-07 | 1965-12-01 | |
| US511210A US3496216A (en) | 1964-12-07 | 1965-12-02 | Reductive dimerization of alpha,beta-unsaturated nitriles by means of amalgam |
| CH1662365A CH456564A (de) | 1964-12-07 | 1965-12-02 | Verfahren zur reduktiven Dimerisierung von a,B-ungesättigten Nitrilen |
| CH1671865A CH475948A (de) | 1964-12-07 | 1965-12-03 | Verfahren zur reduktiven Dimerisierung von in a,B-Stellung olefinisch ungesättigten Amiden |
| NL6515816A NL6515816A (enrdf_load_html_response) | 1964-12-07 | 1965-12-06 | |
| BE673406A BE673406A (enrdf_load_html_response) | 1964-12-07 | 1965-12-07 | |
| FR41204A FR1456388A (fr) | 1964-12-07 | 1965-12-07 | Procédé pour la dimérisation réductrice d'esters et d'amides alpha, bêta-oléfiniques |
| FR41288A FR1456402A (fr) | 1964-12-07 | 1965-12-07 | Procédé de dimérisation réductrice de nitriles non saturés en alpha, bêta |
| DE19651543098 DE1543098A1 (de) | 1964-12-07 | 1965-12-07 | Verfahren zur reduktiven Dimerisation von alpha,beta-olefinischen Verbindungen |
| BE673404A BE673404A (enrdf_load_html_response) | 1964-12-07 | 1965-12-07 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB49714/64A GB1111413A (en) | 1964-12-07 | 1964-12-07 | Making adiponitrile and like compounds by reductive dimerisation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1111413A true GB1111413A (en) | 1968-04-24 |
Family
ID=10453289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB49714/64A Expired GB1111413A (en) | 1964-12-07 | 1964-12-07 | Making adiponitrile and like compounds by reductive dimerisation |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US3496216A (enrdf_load_html_response) |
| BE (1) | BE673404A (enrdf_load_html_response) |
| CH (1) | CH456564A (enrdf_load_html_response) |
| FR (1) | FR1456402A (enrdf_load_html_response) |
| GB (1) | GB1111413A (enrdf_load_html_response) |
| NL (1) | NL6515603A (enrdf_load_html_response) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3193574A (en) * | 1960-05-08 | 1965-07-06 | Katchalsky Aharon | Process for the preparation of adiponitrile by dimerization of acrylonitrile |
| GB1157441A (en) * | 1964-06-02 | 1969-07-09 | Ici Ltd | Reductive Dimerisation of Unsaturated Nitriles |
-
1964
- 1964-12-07 GB GB49714/64A patent/GB1111413A/en not_active Expired
-
1965
- 1965-12-01 NL NL6515603A patent/NL6515603A/xx unknown
- 1965-12-02 CH CH1662365A patent/CH456564A/de unknown
- 1965-12-02 US US511210A patent/US3496216A/en not_active Expired - Lifetime
- 1965-12-07 FR FR41288A patent/FR1456402A/fr not_active Expired
- 1965-12-07 BE BE673404A patent/BE673404A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6515603A (enrdf_load_html_response) | 1966-06-08 |
| US3496216A (en) | 1970-02-17 |
| FR1456402A (fr) | 1966-10-21 |
| BE673404A (enrdf_load_html_response) | 1966-06-07 |
| CH456564A (de) | 1968-07-31 |
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