GB1107329A - Olefin terpolymers - Google Patents

Olefin terpolymers

Info

Publication number
GB1107329A
GB1107329A GB3982965A GB3982965A GB1107329A GB 1107329 A GB1107329 A GB 1107329A GB 3982965 A GB3982965 A GB 3982965A GB 3982965 A GB3982965 A GB 3982965A GB 1107329 A GB1107329 A GB 1107329A
Authority
GB
United Kingdom
Prior art keywords
olefin
2alcl
copolymerized
dimer
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3982965A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Montedison SpA
Original Assignee
Montedison SpA
Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montedison SpA, Montecatini Societa Generale per lIndustria Mineraria e Chimica SpA filed Critical Montedison SpA
Publication of GB1107329A publication Critical patent/GB1107329A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Linear amorphous terpolymers of ethylene, an aliphatic alpha-olefin having from 3 to 8 carbon atoms, and methyl-cyclopentadiene dimer are made by copolymerizing a mixture of the monomers in the presence of a halogen-containing catalyst consisting of the reaction product between vanadium compound and an organometallic compound of beryllium or aluminium, at a temperature between + 10 DEG C. and - 80 DEG C., and using as the polymerization medium the mixture of olefinic compounds kept in the liquid state. The methylcyclopentadiene dimer is obtained by conventional processes of cracking petroleum hydrocarbons. The Specification contains a long list of suitable catalyst components. The alpha-olefin may be propylene or butene-1. In Example I, liquid propylene, methylcyclopentadiene dimer, and ethylene were copolymerized at - 10 DEG C. in the presence of (C2H5)2AlCl and VCl4 whilst in Example II, the same monomers were copolymerized in the presence of (C2H5)2AlCl and VoCl3. The copolymers are completely soluble in boiling n-heptane and may be sulphur vulcanized using conventional mixes.
GB3982965A 1964-09-28 1965-09-17 Olefin terpolymers Expired GB1107329A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT2105664 1964-09-28

Publications (1)

Publication Number Publication Date
GB1107329A true GB1107329A (en) 1968-03-27

Family

ID=11176051

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3982965A Expired GB1107329A (en) 1964-09-28 1965-09-17 Olefin terpolymers

Country Status (3)

Country Link
DE (1) DE1620601A1 (en)
GB (1) GB1107329A (en)
NL (1) NL6510532A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1050547A1 (en) * 1999-05-07 2000-11-08 The Goodyear Tire & Rubber Company Polymeric dimethyl-dicyclopentadiene/limonene resin

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1050547A1 (en) * 1999-05-07 2000-11-08 The Goodyear Tire & Rubber Company Polymeric dimethyl-dicyclopentadiene/limonene resin
US6242550B1 (en) 1999-05-07 2001-06-05 The Goodyear Tire & Rubber Company Polymeric dimethyl- dicyclopentadiene/limonene resin
US6281317B1 (en) 1999-05-07 2001-08-28 The Goodyear Tire & Rubber Company Polymeric dimethyl-dicyclopentadiene/limonene resin

Also Published As

Publication number Publication date
DE1620601A1 (en) 1970-02-26
NL6510532A (en) 1966-03-29

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